Mesoporous Cu(Fe)/SBA-15 catalysts were prepared with distinct metal loadings of ca. 2–10 wt.%. A detailed set of characterizations using X-ray diffraction (XRD), electron paramagnetic resonance (EPR), transmission electron microscopy (TEM), scanning electron microscopy coupled to energy dispersive spectroscopy (SEM-EDS), Mössbauer spectroscopy, X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy was performed to correlate the relationship among structure, electronic properties and catalytic performances. All solids were evaluated in the selective catalytic reduction of NO_x in the presence of CO (CO-SCR). The influence of the metal loadings on the overall activity indicated that introducing high amounts of Fe or Cu on the catalysts was beneficial to form either CuO or α-Fe₂O₃ clusters. Cu_x/SBA-15 series exhibited more efficient activity and poison-tolerant ability during CO-SCR reaction, in contrast to Fe_x/SBA-15. In spite of the Fe species introduced on SBA-15 having structural features similar to those of Cu ones, low interactions among Fe nanoparticles, silica and clusters impeded the high performances of Fe₁₀/SBA-15. XPS revealed the Fe species in a more oxidized state, indicating the stability of the solid after the catalytic tests, in agreement with EPR and Raman spectroscopy. Cu₈/SBA-15 worked better, being recyclable due to the interaction of the Cu²⁺ ions with SBA-15, avoiding the deactivation of the catalyst.

We report on the magnetism of amorphous SiO₂–Al₂O₃–CaO–MgO–Fe₂O₃–K₂O–MnO:CA (CA—activated carbon) aluminosilicate glasses prepared by a fusion-quenching method. Fourier transform infrared and Raman spectroscopy show that a Fe²⁺ lattice modifier in the glass structures induces depolymerization, strongly influencing the magnetic transitions. Room temperature magnetization measurements of the CA-glasses show a different magnetic behavior, such as speromagnetism, asperomagnetism, and weak ferromagnetism. Mössbauer spectroscopy analyses at room temperature reveal that iron changes valence from Fe³⁺ → Fe²⁺ with increasing CA content. This Fe³⁺ → Fe²⁺ suggests that asperomagnetism and weak ferromagnetism behavior are triggered by Fe²⁺–O–Fe³⁺ superexchange coupling in short-range structures of aluminosilicate glasses. A model for the aluminosilicate glass structures is proposed to explain the different magnetic regimes.