The pyrolysis of three different biomasses, rice husk (RH), zoita wood sawdust (ZW) and pine wood sawdust (PW), was studied at 500 °C in a multipurpose unit at the bench scale to determine the yields of the different products and the compositions and properties of the liquid products, with particular emphasis given to the alquitranous fractions (tars). It was possible to link the characteristics of the tars with the compositions of the raw biomasses and verify their potential in various applications. The analytical techniques employed in the characterization of biomasses included lignin, celulose and hemicellulose analysis, ultimate and proximate analysis and thermogravimetry–mass spectrometry analysis (TG-MS). Elemental analysis, gas chromatography–mass spectrometry (GC-MS), nuclear magnetic resonance spectroscopy (¹H NMR), Fourier transform infrared spectroscopy (FTIR) and size exclusion chromatography (SEC) were used to characterize the tars. The tar yields were 1.8, 7.4 and 4.0 %wt. in the cases of RH, ZW and PW, respectively. The tars showed higher carbon content, between 60.3 and 62.2 %wt., and lower oxygen content, between 28.8 and 31.6 %wt., than the corresponding raw biomasses. The main components of the tars had aromatic bases, with phenols representing more than 50%. Tar RH included more guaiacols, while Tars ZW and PW included more phenols and alkylated phenols.