Mo-doped SnO2 nanoparticles were prepared via a facile hydrothermal method in this work, demonstrating excellent long-cycling performance as anode material for LIBs.
The booming electric vehicle industry continues to place higher requirements on power batteries related to economic-cost, power density and safety. The positive electrode materials play an important role in the energy storage performance of the battery. The nickel-rich NCM (LiNixCoyMnzO2 with x + y + z = 1) materials have received increasing attention due to their high energy density, which can satisfy the demand of commercial-grade power batteries. Prominently, single-crystal nickel-rich electrodes with s unique micron-scale single-crystal structure possess excellent electrochemical and mechanical performance, even when tested at high rates, high cut-off voltages and high temperatures. In this review, we outline in brief the characteristics, problems faced and countermeasures of nickel-rich NCM materials. Then the distinguishing features and main synthesis methods of single-crystal nickel-rich NCM materials are summarized. Some existing issues and modification methods are also discussed in detail, especially the optimization strategies under harsh conditions. Finally, an outlook on the future development of single-crystal nickel-rich materials is provided. This work is expected to provide some reference for research on single-crystal nickel-rich ternary materials with high energy density, high safety levels, long-life, and their contribution to sustainable development.
With the continuous development of assisted driving technology, the autonomous emergency braking (AEB) system has emerged as a critical innovation in preventing collisions and improving vehicular safety. In this paper, to test the performance of the AEB system efficiently and reliably in real-world driving scenarios, four typical test scenarios for the AEB system were constructed, and five comprehensive performance evaluation indices, including braking parking distance, braking deceleration, collision warning time, speed variation, and accident collision avoidance rate, were proposed for the first time. Subsequently, the Comprehensive Performance Evaluation Index Model (CPEIM) for the AEB system and scoring rules for typical test scenarios were established, which were applied to analyze data obtained from road testing, thereby enabling comprehensive testing and evaluation for AEB system performance. The results showed that the Tesla Model Y and Volvo S90 scored 1.8857 and 2.0433, respectively. Under conditions of dry pavement, across a range of test scenarios, the AEB system of both the Tesla Model Y and Volvo S90 were capable of averting collisions at speeds not exceeding 35 km/h and 45 km/h, respectively.
In the field of active safety technology for intelligent connected vehicles (ICVs), the reliability and safety of the Automatic Emergency Braking (AEB) system is recognized as critical to driving safety. However, existing evaluation methods have been constrained by the inadequacy of static weight assessments in adapting to diverse driving conditions, as well as by the disconnect between conventional evaluation frameworks and experimental validation. To address these limitations, a comprehensive Vehicle-in-the-Loop (VIL) evaluation system based on the dynamic weight analytic hierarchy process (DWAHP) was proposed in this study. A two-tier dynamic weighting architecture was established. At the criterion level, a bivariate variable–weight function, incorporating the vehicle speed and road surface adhesion coefficient, was developed to enable the dynamic coupling modeling of road environment parameters. At the scheme level, a five-dimensional indicator system—integrating braking distance, collision speed, and other key metrics—was constructed to support an adaptive evaluation model under multi-condition scenarios. By establishing a dynamic mapping between weight functions and driving condition parameters, the DWAHP methodology effectively overcame the limitations associated with fixed-weight mechanisms in varying operating conditions. Based on this framework, a dedicated AEB system performance test platform was designed and developed. Validation was conducted using both VIL simulations and real-world road tests, with a Volvo S90L as the test vehicle. The experimental results demonstrated high consistency between VIL and real-world road evaluations across three dimensions: safety (deviation: 0.1833/9.5%), reliability (deviation: 0.2478/13.1%), and riding comfort (deviation: 0.05/2.7%), with an overall comprehensive score deviation of 0.0707 (relative deviation: 0.51%). This study not only verified the technical advantages of the dynamic weight model in adapting to complex driving environments and analyzing multi-parameter coupling effects but also established a systematic methodological framework for evaluating AEB system performance via VIL. The findings provide a robust foundation for the testing and assessment of AEB system, offer a structured approach to advancing the performance evaluation of advanced driver assistance systems (ADASs), facilitate the safe and reliable validation of ICVs’ commercial applications, and ultimately contribute to enhancing road traffic safety.
Proton exchange membrane fuel cells (PEMFCs) have been widely studied as an efficient and environmentally friendly energy conversion technology in recent years. However, the high cost, easy poisoning and complex synthesis methods of noble metal catalysts have hindered their commercialization. Therefore, in this paper, a non-noble metal composite catalyst CuFeCo/C for the oxygen reduction reaction (ORR) was prepared by using a facile liquid-phase reduction method. The ORR kinetic performance of CuFeCo/C was evaluated by cyclic voltammetry (CV), linear sweep voltammetry (LSV) and rotating ring-disk electrode (RRDE) tests. The results show that the oxygen reduction peak of CuFeCo/C appears at about 0.64 V, the half-wave potential is about 0.73 V, the limiting current density is about −16.51 A·m−2, and the Tafel slope is about −0.08. The 10,800 s chronoamperometry test shows that the catalyst has a very good long-term cycle stability. This indicates that the CuFeCo/C composite catalyst has strong stability, good conductivity and ORR catalytic activity under alkaline conditions, which can promote the large-scale commercial application of PEMFCs.