The copper nanoparticles (CuNPs) have attracted much attention due to their application in diverse fields. The applications of CuNPs depend on their physical and chemical properties. This study presents the first report for the use of medicinal fruit extract of Piper retrofractum Vahl as an eco-friendly reagent in the synthesis of CuNPs using copper sulfate as a starting material. Piper retrofractum Vahl extract was employed as a bioreductor as well as a capping agent in the formation of CuNPs. The reaction process was assisted by sonication and stirring. The influences of extract concentration, pH, temperature, and reaction time on the size of CuNPs were studied in detail. The morphology and structure of synthesized CuNPs were characterized by UV-Vis, FT-IR, SEM-EDS, TEM, and XRD. The UV-Vis measurement showed the surface plasmon resonance (SPR) peak at 234-255 nm, whereas FTIR characteristic peaks of metal-oxygen (Cu–O) were confirmed in the range 550-570 cm−1 and Cu–O–H bonds led to bending absorptions in the region 870-880 cm−1. The synthesized CuNPs possess the spherical shapes and high content of copper (70.3%) as confirmed by SEM-EDS. From the TEM micrograph, it can be seen that the particle size distribution of CuNPs has a high uniformity with a size of 2–10 nm under the optimum condition. The crystalline nature of CuNPs as confirmed by XRD showed the crystallinity phase of 26.4%. The synthesized CuNPs have relatively good stability and could inhibit Escherichia coli and Staphylococcus aureus. The results proved that Piper retrofractum Vahl fruit extract could be applied for a greener synthesis of CuNPs with high uniformity of particle sizes.

The isolation of nanocellulose has been extensively investigated due to the growing demand for sustainable green materials. Cellulose nanocrystals (CNCs) and cellulose nanofibers (CNFs), which have the same chemical composition but have different morphology, particle size, crystallinity, and other properties depending on the precursor and the synthesis method used. In comparison, CNC particles have a short rod-like shape and have smaller particle dimensions when compared to CNF particles in the form of fibers. CNC synthesis was carried out chemically (hydrolysis method), and CNF synthesis was carried out mechanically (homogenization, ball milling, and grinding), and both can be modified because they have a large surface area and are rich in hydroxyl groups. Modifications were made to increase the adsorption ability of heavy metal ions. The Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric (TG), and dynamic light scattering (DLS) can reveal the characteristics and morphology of CNCs and CNFs. The success and effectiveness of the heavy metal adsorption process are influenced by a few factors. These factors include adsorbent chemical structure changes, adsorbent surface area, the availability of active sites on the adsorbent’s surface, adsorption constants, heavy metal ionic size differences, pH, temperature, adsorbent dosage, and contact time during the adsorption process. In this review, we will discuss the characteristics of CNCs and CNFs synthesized from various precursors and methods, the modification methods, and the application of CNCs and CNFs as heavy metal ion adsorbents, which includes suitable isotherm and kinetics models and the effect of pH on the selectivity of various types of heavy metal ions.