Information on liquid–liquid phase separation (LLPS) and viscosity (or diffusion) within secondary organic aerosol (SOA) is needed to improve predictions of particle size, mass, reactivity, and cloud nucleating properties in the atmosphere. Here we report on LLPS and viscosities within SOA generated by the photooxidation of diesel fuel vapors. Diesel fuel contains a wide range of volatile organic compounds, and SOA generated by the photooxidation of diesel fuel vapors may be a good proxy for SOA from anthropogenic emissions. In our experiments, LLPS occurred over the relative humidity (RH) range of ∼70 % to ∼100 %, resulting in an organic-rich outer phase and a water-rich inner phase. These results may have implications for predicting the cloud nucleating properties of anthropogenic SOA since the presence of an organic-rich outer phase at high-RH values can lower the supersaturation with respect to water required for cloud droplet formation. At ≤10 % RH, the viscosity was $\ge \mathrm{1}\times {\mathrm{10}}^{\mathrm{8}}$ Pa s, which corresponds to roughly the viscosity of tar pitch. At 38 %–50 % RH, the viscosity was in the range of 1×10⁸ to 3×10⁵ Pa s. These measured viscosities are consistent with predictions based on oxygen to carbon elemental ratio (O:C) and molar mass as well as predictions based on the number of carbon, hydrogen, and oxygen atoms. Based on the measured viscosities and the Stokes–Einstein relation, at ≤10 % RH diffusion coefficients of organics within diesel fuel SOA is $\le \mathrm{5.4}\times {\mathrm{10}}^{-\mathrm{17}}$ cm² s⁻¹ and the mixing time of organics within 200 nm diesel fuel SOA particles (τ_mixing) is 50 h. These small diffusion coefficients and large mixing times may be important in laboratory experiments, where SOA is often generated and studied using low-RH conditions and on timescales of minutes to hours. At 38 %–50 % RH, the calculated organic diffusion coefficients are in the range of $\mathrm{5.4}\times {\mathrm{10}}^{-\mathrm{17}}$ to $\mathrm{1.8}\times {\mathrm{10}}^{-\mathrm{13}}$ cm² s⁻¹ and calculated τ_mixing values are in the range of ∼0.01 h to ∼50 h. These values provide important constraints for the physicochemical properties of anthropogenic SOA.

Secondary organic aerosol (SOA) constitutes a large fraction of atmospheric aerosol. To assess its impacts on climate and air pollution, knowledge of the number of phases in internal mixtures of different SOA types is required. Atmospheric models often assume that different SOA types form a single phase when mixed. Here, we present visual observations of the number of phases formed after mixing different anthropogenic and biogenic SOA types. Mixing SOA types generated in environmental chambers with oxygen-to-carbon (O/C) ratios between 0.34 and 1.05, we found 6 out of 15 mixtures of two SOA types to result in two phase particles. We demonstrate that the number of phases depends on the difference in the average O/C ratio between the two SOA types (Δ(O/C)). Using a threshold Δ(O/C) of 0.47, we can predict the phase behavior of over 90 % of our mixtures, with one- and two-phase particles predicted for Δ(O/C)<0.47 and Δ(O/C)≥0.47, respectively. This threshold ΔO/C value provides a simple parameter to predict whether mixtures of fresh and aged SOA form one- or two-phase particles in the atmosphere. In addition, we show that phase-separated SOA particles form when mixtures of volatile organic compounds emitted from real trees are oxidized.

Molecular composition, viscosity, and liquid–liquid phase separation (LLPS) were investigated for secondary organic aerosol (SOA) derived from synthetic mixtures of volatile organic compounds (VOCs) representing emission profiles for Scots pine trees under healthy and aphid-herbivory stress conditions. Model “healthy plant SOA” and “stressed plant SOA” were generated in a 5 m³ environmental smog chamber by photooxidation of the mixtures at 50% relative humidity (RH). SOA from photooxidation of α-pinene was also prepared for comparison. Molecular composition was determined with high resolution mass spectrometry, viscosity was determined with the poke-flow technique, and liquid–liquid phase separation was investigated with optical microscopy. The stressed plant SOA had increased abundance of higher molecular weight species, reflecting a greater fraction of sesquiterpenes in the stressed VOC mixture compared to the healthy plant VOC mixture. LLPS occurred in both the healthy and stressed plant SOA; however, stressed plant SOA exhibited phase separation over a broader humidity range than healthy plant SOA, with LLPS persisting down to 23 ± 11% RH. At RH ≤25%, both stressed and healthy plant SOA viscosity exceeded 10⁸ Pa s, a value similar to that of tar pitch. At 40% and 50% RH, stressed plant SOA had the highest viscosity, followed by healthy plant SOA and then α-pinene SOA in descending order. The observed peak abundances in the mass spectra were also used to estimate the SOA viscosity as a function of RH and volatility. The predicted viscosity of the healthy plant SOA was lower than that of the stressed plant SOA driven by both the higher glass transition temperatures and lower hygroscopicity of the organic molecules making up stressed plant SOA. These findings suggest that plant stress influences the physicochemical properties of biogenic SOA. Furthermore, a complex mixture of VOCs resulted in a higher SOA viscosity compared to SOA generated from α-pinene alone at ≥25% RH, highlighting the importance of studying properties of SOA generated from more realistic multi-component VOC mixtures.

Rotor tip clearance height and the associated tip leakage flow have a significant effect on the performance and stability of compressors. Existing studies considering tip clearance effects on stability have been primarily limited to low-speed compressors, and many of these evaluated single-stage machines, which may not adequately represent stall trends for engine-scale compressors. Furthermore, test campaigns for engine-scale compressors cannot provide instrumentation accessibility required for detailed stage performance and stall investigations. Using results collected from a three-stage intermediate-speed axial compressor with appreciable density rise, this study addresses these needs. In this paper, three rotor tip clearances are tested, ranging from 1.5 to 4% span (1 to 3% chord). Previous studies have primarily shown a transition from short-length-scale spikes to long-length-scale modes as the clearance is increased, whereas the present study shows the opposite: a transition from modes to spikes with increased tip clearance. As a result, these data emphasize that a definitive trend does not exist between the stall inception mechanism and increasing tip clearance. Instead, the clearance effects alter stage matching with speed and change the stall inception mechanism. These results also elicit future research by preliminarily suggesting that stall inception mechanisms may be predictable from steady performance measurements collected in the stalling stage.

The unsteady flow field generated by the rotor provides unsteady aerodynamic excitations to the downstream stator, which can result in vibrations such as forced response. In this paper, measurements of the rotor wake and rotor tip leakage flow from an embedded rotor in a multistage axial compressor are presented. A unique feature of this work is the pitchwise traverse of the flow field used to highlight the changes in the rotor exit flow field with respect to the position of the surrounding vane rows. Results acquired at midspan focus on characterizing an average rotor wake, including the effects on the frequency spectrum, from a forced response perspective. While many analyses use an average rotor wake to characterize the aerodynamic forcing function to the downstream stator, this study explores the factors that influence changes in the rotor wake shape and the resulting impact on the spectrum. Additionally, this paper investigates the flow near the endwall where the tip leakage vortex is an important contributor to the aerodynamic excitations for the downstream vane. For the first time, experimental data are presented at the rotor exit, which show the modulation in size and radial penetration of the tip leakage vortex as the rotor passes through the upstream vane wake. As computational models become more advanced, the ability to incorporate these aerodynamic excitation effects should be considered to provide better predictions for vane vibratory response.