Sylvain Caillol

Dr. Sylvain Caillol

Institut Charles Gerhardt, Montpellier, Occitanie, France
orcid
Senior Research Director CNRS

Research Focus & Metrics

Academic Career Length

24Years (2003-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

View All Publications
14 October 2013 in Chemical Reviews
Verified
Journal Article
Closed access
RARémi Auvergne
Rémi Auvergne
Sylvain CaillolSylvain Caillol
Sylvain Caillol
GDGhislain David
Ghislain David
BBBernard Boutevin
Bernard Boutevin
JPJean-Pierre Pascault
Jean-Pierre Pascault

15 December 2015 in ACS Sustainable Chemistry & Engineering
Verified
Journal Article
Closed access
MFMaxence Fache
Maxence Fache
BBBernard Boutevin
Bernard Boutevin
Sylvain CaillolSylvain Caillol
Sylvain Caillol

3 November 2016 in Chemical Reviews
Verified
Journal Article
Closed access
VFVincent Froidevaux
Vincent Froidevaux
CNClaire Negrell
Claire Negrell
Sylvain CaillolSylvain Caillol
Sylvain Caillol
JPJean-Pierre Pascault
Jean-Pierre Pascault
BBBernard Boutevin
Bernard Boutevin

1 February 2017 in European Polymer Journal
Verified
Journal Article
Closed access
ACAdrien Cornille
Adrien Cornille
RARémi Auvergne
Rémi Auvergne
OFOleg Figovsky
Oleg Figovsky
BBBernard Boutevin
Bernard Boutevin
Sylvain CaillolSylvain Caillol
Sylvain Caillol

18 February 2014 in Green Chemistry
Verified
Journal Article
Closed access
PDF file
MFMaxence Fache
Maxence Fache
EDEmilie Darroman
Emilie Darroman
VBVincent Besse
Vincent Besse
RARémi Auvergne
Rémi Auvergne
Sylvain CaillolSylvain Caillol
Sylvain Caillol
BBBernard Boutevin
Bernard Boutevin
Vanillin was used as a renewable building-block to develop a platform of 22 biobased compounds for polymer chemistry. Vanillin-derived biobased monomers bearing epoxy, cyclic carbonates, allyl, amine, alcohol and carboxylic acid moieties were synthesized. They can be used, among many others, in epoxy, polyester, polyurethanes, and Non-Isocyanate PolyUrethanes (NIPU) polymer synthesis. The epoxy-functionalized compounds were synthesized under solvent-free conditions and are original biobased aromatic epoxy monomers. Cyclic carbonates were prepared through a catalytic reaction between epoxy compounds and CO2. Thiol–ene reactions allowed the functionalization of allylated compounds with amines, acids and alcohols. The amine-functionalized compounds are, to our knowledge, the first non-aliphatic biobased amine hardeners, usable either in epoxy or NIPU materials.

9 January 2012 in Polymer Reviews
Verified
Journal Article
Closed access
MDMyriam Desroches
Myriam Desroches
MEMaxime Escouvois
Maxime Escouvois
RARemi Auvergne
Remi Auvergne
Sylvain CaillolSylvain Caillol
Sylvain Caillol
BBBernard Boutevin
Bernard Boutevin
Most of biobased polyols for polyurethanes are synthesized from vegetable oils. In the first part, the present review goes into details of these different synthetic routes to obtain polyols. First, olefinic functionalities of triglycerides could easily be epoxidized, leading to reactive epoxide groups. Second, triglycerides double bonds could undergo a wide ranges of reactions to yield polyols. Finally, the carbonyl group could also be used as a reactive group to yield various polyols. In the second part, the present review is dedicated to the commercial biobased polyols, and, based on the patent literature focuses on the industrial synthetic routes.