The application of semiconductor photocatalysts with narrow band gaps is hindered by the rapid recombination of electron–hole pairs and limitation of multiple reactive oxygen species (ROS) synchronous generation. A n–n-type direct Z-scheme heterostructured photocatalyst was constructed based on the staggered band alignment of bismuth tungstate (Bi₂WO₆) and indium zinc sulfide (ZnIn₂S₄) to reveal the synergistic effect of charge separation and multiple ROS synchronous generation on boosting photocatalytic performance. Under irradiation, electrons in the conduction band (CB) of Bi₂WO₆ and holes in the valence band (VB) of ZnIn₂S₄ recombined at interface to prolong the lifetime of electrons in the CB of ZnIn₂S₄ and holes in the VB of Bi₂WO₆. Meanwhile, the multiple ROS synchronously generated to oxidize pollutant due to the strong redox ability of electrons of ZnIn₂S₄ and holes of Bi₂WO₆, which was determined by the CB potential of ZnIn₂S₄ and VB potential of Bi₂WO₆. The results provided valuable insights for the application of photocatalysts with a narrow band gap in the field of water pollution control.

Using photodeposition and plasma, Pt-N co-modified TiO₂ nanotube electrodes were created. Several techniques, such as SEM, XRD, UV-VIS-DRS, XPS, and PL, were used to analyze the electrode shape, crystalline structure, light absorption range, elemental composition, and photogenerated carrier recombination efficiency. Using the electrochemical workstation, EIS and I-t were utilized to examine the electrochemical characteristics. The results indicated that the diameter of the TiO₂ nanotube tubes was around 90 nm, and that the photodeposition duration affected the amount of Pt particles deposited. The deposited Pt particles efficiently reduced the photogenerated carrier complexation rate of the N-TiO₂ nanotube electrode, contributing to the separation of electron-hole pairs and light utilization. Electrochemical studies indicated that Pt-N co-modified TiO₂ increased the electrode’s oxidation and electrical conductivity, as well as its photoelectrocatalytic capacity. Oxytetracycline degradation in simulated wastewater by a Pt-N co-modified TiO₂ nanotube electrode revealed the exceptional PEC activity, and the oxytetracycline degradation processes followed primary kinetics. •O₂⁻ and •OH played a significant role in the photoelectrocatalytic degradation of oxytetracycline, resulting in a novel method for oxytetracycline degradation.

Water-scarce cities have fewer surface water (SW) resources available for ecological use, causing landscape water to deteriorate due to water shortage and fail to perform their intended landscape functions. As a result, many cities use reclaimed water (RW) to replenish them. However, this could cause concern among the people, as RW usually has higher nutrient concentrations, which may stimulate algae growth and deteriorate the aesthetic senses of the receiving water bodies. In order to assess the feasibility of using RW for this purpose, this study used Xingqing Lake in Northwest China as insight into the effect of RW replenishment on the visual landscape quality of urban landscape water. Water transparency (measured by SD) is used as an intuitive indicator to reflect the comprehensive influence of suspended solids and algae growth on the water’s aesthetic quality. Scenario analyses were carried out after calibrating and validating one-year data in MIKE 3 software with both SD and algae growth calculations, and the results showed that the low concentration of suspended matter in RW could compensate for the decrease in SD due to algal blooms caused by high concentrations of nitrogen and phosphorus, and the effect on SD is especially pronounced under conditions that are not conducive to algal growth, such as good flow conditions and low temperature. In addition, to meet a SD ≥ 70 mm, the total water inflow required can be significantly reduced with the optimal application of RW. It is also indicated that partial or complete utilization of RW to replace SW for replenishing the landscape water could be feasible from the viewpoint of landscape quality, at least for the landscape water investigated in this study. This can provide a method for the improvement to urban water management practices by using RW for replenishment in water-scarce cities.

A microtubule ultrafiltration reactor (MUFR), with an organophosphorus system containing a sewage section with buffer liquid acetic acid and an enrichment section with aqua fortis liquid and organophosphorus dissolved in fuel oil, has been studied for praseodymium(III) migration. Many factors of praseodymium(III) migration using MUFR need to be explored, including hydrogen ion molarity (or pH), cinit of praseodymium(III), the different ionic strengths of rare-earth mine sewage, the volume ratio of organophosphorus fuel oil and aqua fortis liquid (O/A), aqua fortis’ molarity, organophosphorus’ molarity, and the effects of different acid liquids in the enrichment section on praseodymium(III) migration with MUFR. The virtues of MUFR compared to conventional migration were explored. The effects of the hydrodynamic properties (stability and flow velocity) and UF system parameters (internal diameter of the microtubule, tubule shell thickness, void ratio), etc., on the mass migration performance of the MUFR process for praseodymium(III) migration were also studied. The experimental results show that the best migration prerequisites of praseodymium(III) were obtained as follows: an aqua fortis molarity of 4.00 mol/L, an organophosphorus molarity of 0.200 mol/L, an O/A of 0.6 in the enrichment section, and a pH value of 4.80 in the sewage section. The ionic strength of rare-earth mine sewage had no obvious effect on praseodymium(III) migration. When the cinit of praseodymium(III) molarity was 1.58 × 10⁻⁴ mol/L, the migration percentage of praseodymium(III) reached 95.2% in 160 min.