Photocatalyst is the core of photocatalysis and directly determines photocatalytic performance. However, low quantum efficiency and low utilization of solar energy are important technical problems in the application of photocatalysis. In this work, a series of polyoxometalates (POMs) [H₃PW₁₂O₄₀] (PW₁₂)-doped titanium dioxide (TiO₂) nanofibers modified with various amount of silver (Ag) nanoparticles (NPs) were prepared by utilizing electrospinning/photoreduction strategy, and were labelled as x wt% Ag/PW₁₂/TiO₂ (abbr. x% Ag/PT, x = 5, 10, and 15, respectively). The as-prepared materials were characterized with a series of techniques and exhibited remarkable catalytic activities for visible-light degradation tetracycline (TC), enrofloxacin (ENR), and methyl orange (MO). Particularly, the 10% Ag/PT catalyst with a specific surface area of 155.09 m²/g and an average aperture of 4.61 nm possessed the optimal photodegradation performance, with efficiencies reaching 78.19% for TC, 93.65% for ENR, and 99.29% for MO, which were significantly higher than those of PW₁₂-free Ag/TiO₂ and PT nanofibers. Additionally, various parameters (the pH of the solution, catalyst usage, and TC concentration) influencing the degradation process were investigated in detail. The optimal conditions are as follows: catalyst usage: 20 mg; TC: 20 mL of 20 ppm; pH = 7. Furthermore, the photodegradation intermediates and pathways were demonstrated by HPLC-MS measurement. We also investigated the toxicity of products generated during TC removal by employing quantitative structure-activity relationship (QSAR) prediction through a toxicity estimation software tool (T.E.S.T. Version 5.1.2.). The mechanism study showed that the doping of PW₁₂ and the modification of Ag NPs on TiO₂ broadened the visible-light absorption, accelerating the effective separation of photogenerated carriers, therefore resulting in an enhanced photocatalytic performance. The research provided some new thoughts for exploiting efficient and durable photocatalysts for environmental remediation.

A bimetallic organic gel (MOG-Fe/Al) was synthesized through the solvothermal method. The gel state of the product obtained under optimized gel formation conditions is sufficient to carry 2 g of weight for a long time. Scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, Brunauer–Emmett–Teller (BET) technique, and X-ray photoelectron spectroscopy (XPS) analysis confirmed the structures and morphologies of the synthesized materials. MOG-Fe/Al, with good stability, excellent durability, and wide applicability, exhibited efficient MO adsorption capacity as high as 335.88 mg/g at 25 °C. Adsorption-influencing factors including solution pH, contact time, and temperature were investigated. The adsorption performance of the bimetallic organic gel was better than that of the monometallic organic gels (MOG-Fe and MOG-Al), and its adsorption processes were in accordance with the pseudo-second-order kinetic and Langmuir isothermal models. The excellent adsorption capacity of the MOG-Fe/Al is due to its surface structure, pore volume, π-π interactions, hydrogen bonds, and electrostatic interactions.

Electrochromic supercapacitors (ECSCs) have recently received growing attention for potential smart energy storage components in intelligent electronics. However, in the development of ECSCs, the design and assembly of high-performance electrode materials remain ongoing challenges. In this study, Ti₃C₂T_x MXene and polyoxotungstate (P₂W₁₈) were deposited on TiO₂ nanowires to construct a unique three-dimensional (3D) porous hybrid film, NW@MXene/P₂W₁₈, via a convenient layer-by-layer self-assembly approach. The 3D porous structure of the nanocomposite reduced the aggregation and stacking of Ti₃C₂T_x MXene nanosheets during self-assembly, leading to the formation of unobstructed ion diffusion channels and interfacial charge transfer between adjacent layers, resulting in a good electrochemical performance. Compared to the tightly packed structure, the porous hybrid film demonstrated an enhanced electrochromic energy storage performance with a higher areal capacitance (i.e., 19.0 mF cm⁻² at a current density of 0.6 mA cm⁻²), in addition to a high cycling stability (i.e., 90.7% retention rate after 2000 cycles), and an excellent color rendering efficiency. Subsequently, an asymmetric ECSC was fabricated using an NW@MXene/P₂W₁₈ film as the cathode and a TiO₂ nanowire film as the anode. This ECSC exhibited a high areal capacitance of 4.0 mF cm⁻² at a current density of 0.1 mA cm⁻² with a wide operating window of 4.5 V, whilst also achieving high-speed color switching between olive green and dark blue during the charge/discharge processes, ultimately offering new avenues for the development of electrochromic energy storage electrode materials and the design of novel devices.

A bifunctional electrochromic-energy storage film with enhanced performance is designed and fabricated by hybridizing TiO₂nanowires with POMs.

An electrochromic film with a high coloration efficiency is designed and fabricated by electrochemically depositing polyoxometalates on vertically aligned TiO₂ nanowires.