For the detection of deep-sea natural gas hydrates, it is very important to accurately detect the ¹³CO₂/¹²CO₂ isotope ratio of dissolved gas in seawater. In this paper, a ¹³CO₂/¹²CO₂ isotope ratio sensor is investigated, which uses a tunable diode laser absorption spectroscopy (TDLAS) technique at 4.3 μm. The proposed sensor consists of a mid-infrared interband cascade laser (ICL) operating in continuous wave mode, a long optical path multi-pass gas cell (MPGC) of 24 m, and a mid-infrared mercury cadmium telluride (MCT) detector. Aiming at the problem of the strong absorption intensity of the two absorption lines of ¹³CO₂ and ¹²CO₂ being affected by temperature, a high-precision temperature control system for the MPGC was fabricated. Five different concentrations of CO₂ gas were configured to calibrate the sensor, and the response linearity could reach 0.9992 for ¹²CO₂ and 0.9996 for ¹³CO₂. The data show that the carbon isotope measurement precision was assessed to be 0.0139‰ when the integration time was 92 s and the optical path length was 24 m. The sensor is combined with a gas–liquid separator to detect the ¹³CO₂/¹²CO₂ isotope ratio of CO₂ gas extracted from water. Results validate the reported sensor system’s potential application in deep-sea natural gas hydrate exploration.

The remotely operated vehicle (ROV), a vital deep-sea platform, offers key advantages, including operational duration via continuous umbilical power, high task adaptability, and zero human risk. It has become indispensable for deep-sea scientific research and marine engineering. To enhance surveys of cobalt-rich crusts (CRCs) on complex seamount terrains, the 4500-m-class Haima ROV integrates advanced payloads, such as underwater positioning systems, multi-angle cameras, multi-functional manipulators, subsea shallow drilling systems, sediment samplers, and acoustic crust thickness gauges. Coordinated control between deck monitoring and subsea units enables stable multi-task execution within single dives, significantly improving operational efficiency. Survey results from Caiwei Guyot reveal the following: (1) ROV-collected data were highly reliable, with high-definition video mapping CRCs distribution across varied terrains. Captured crust-bearing rocks weighed up to 78 kg, drilled cores reached 110 cm, and acoustic thickness measurements had a 1–2 cm margin of error compared to in situ cores; (2) Video and cores analysis showed summit platforms (3–5° slopes) dominated by tabular crusts with gravel-type counterparts, summit margins (5–10° slopes) hosting gravel crusts partially covered by sediment, and steep slopes (12–15° slopes) exhibiting mixed crust types under sediment coverage. Thicker crusts clustered at summit margins (14 and 15 cm, respectively) compared to thinner crusts on platforms and slopes (10 and 7 cm, respectively). The Haima ROV successfully investigated CRC resources in complex terrains, laying the groundwork for seamount crust resource evaluations. Future advancements will focus on high-precision navigation and control, high-resolution crust thickness measurement, optical imaging optimization, and AI-enhanced image recognition.

As crucial transportation hubs and economic nodes, the underwater security and infrastructure maintenance of harbors are of paramount importance. Harbors are characterized by high vessel traffic and complex underwater environments, where traditional underwater inspection methods, such as diver operations, face challenges of low efficiency, high risk, and limited operational range. This paper introduces a collaborative survey and disposal system that integrates a deformable unmanned surface vehicle (USV) with a lightweight remotely operated vehicle (ROV). The USV is equipped with a side-scan sonar (SSS) and a multibeam echo sounder (MBES), enabling rapid, large-area searches and seabed topographic mapping. The ROV, equipped with an optical camera system, forward-looking sonar (FLS), and a manipulator, is tasked with conducting close-range, detailed observations to confirm and dispose of abnormal objects identified by the USV. Field trials were conducted at an island harbor in the South China Sea, where simulated underwater objects, including an iron drum, a plastic drum, and a rubber tire, were deployed. The results demonstrate that the USV-ROV collaborative system effectively meets the demands for underwater environmental measurement, object localization, identification, and disposal in complex harbor environments. The USV acquired high-resolution (0.5 m × 0.5 m) three-dimensional topographic data of the harbor, effectively revealing its topographical features. The SSS accurately localized and preliminarily identified all deployed simulated objects, revealing their acoustic characteristics. Repeated surveys revealed a maximum positioning deviation of 2.2 m. The lightweight ROV confirmed the status and location of the simulated objects using an optical camera and an underwater positioning system, with a maximum deviation of 3.2 m when compared to the SSS locations. The study highlights the limitations of using either vehicle alone. The USV survey could not precisely confirm the attributes of the objects, whereas a full-area search of 0.36 km² by the ROV alone would take approximately 20 h. In contrast, the USV-ROV collaborative model reduced the total time to detect all objects to 9 h, improving efficiency by 55%. This research offers an efficient, reliable, and economical practical solution for applications such as underwater security, topographic mapping, infrastructure inspection, and channel dredging in harbor environments.

Recently, shallow gas fields and hydrate-bearing sand in the deepwater area of the northern South China Sea have been successively discovered, and the accurate prediction of shallow sands is an important foundation. However, most of the current prediction methods are mainly for deep oil and gas reservoirs. Compared with those reservoirs with high degree of consolidation, shallow sandy reservoirs are loose and unconsolidated, whose geophysical characteristics are not well understood. This paper analyzes the logging data of shallow sandy reservoirs recovered in the South China Sea recently, which show that the sand content has a significant influence on Young’s modulus and Poisson’s ratio of the sediments. Therefore, this paper firstly constructs a new petrophysical model of unconsolidated strata targeting sandy content and qualitatively links the mineral composition and the elastic parameters of the shallow marine sediments and defines a new indicator for sandy content: the modified brittleness index (MBI). The effectiveness of MBI in predicting sandy content is then verified by measured well data. Based on pre-stack seismic inversion, the MBI is then inverted, which will identify the sandy deposits. The method proposed provides technical support for the subsequent shallow gas and hydrate exploration in the South China Sea.

The search and discovery of underwater shipwreck sites represent the most arduous and critical phases of underwater archaeology. Wooden shipwrecks, in particular, are characterized by low acoustic impedance contrast and weak magnetic anomalies, coupled with their limited physical dimensions. Consequently, they predominantly exist as shallow-buried, discontinuous small targets scattered within confined areas, making their detection exceptionally challenging. Furthermore, the complexity of the submarine environment—including rugged topography, turbid water columns, and strong currents—poses formidable obstacles to the effective detection of these archaeological remains. Single geophysical methods are often limited by insufficient imaging resolution, interpretation ambiguity, and geological noise, making precise localization and characterization difficult. Focusing on the Nan’ao I Ming Dynasty shipwreck located in waters approximately 24 m deep off the coast of Nan’ao, Guangdong Province, China, this study proposes and validates an “acoustic-magnetic” multi-source data integration detection method. This approach systematically integrates high-resolution multibeam echo sounding (MBES), side-scan sonar (SSS), sub-bottom profiling (SBP), and marine magnetic data to establish a comprehensive framework for identification and integration analysis. The results indicate that the MBES bathymetric data reveal a regular, elongated structure oriented north–south (approximately 34 m × 12 m), closely matching the main hull and deck configuration. The SSS imagery exhibited high backscatter intensity and parallel linear textures, effectively delineating the hard shipwreck structure and the associated rigid protective frame employed for in situ preservation. SBP data confirmed the semi-buried state of the shipwreck (burial depth of approximately 0.6 m). Spatial variations in sediment thickness around the site suggested ongoing modification by strong hydrodynamic processes. Marine magnetic surveys identified localized negative anomalies (−210 nT relative to the ambient magnetic field), contrasting sharply with the positive anomalies of the surrounding natural reefs, thereby indicating an artificial ferromagnetic source. The spatial registration and feature superposition of multi-source data facilitated the characterization of the shipwreck, demonstrating its potential to mitigate environmental interference and enhance detection reliability in this complex environment. Using the Nan’ao I shipwreck site as a case study, this study provides a detailed characterization of the site’s 3D morphology, burial state, and physical properties. The proposed methodology offers a practical and robust technical solution for underwater shipwreck archaeology in complex nearshore environments, providing significant implications for proactive discovery, efficient investigation, and protection of underwater cultural heritage (UCH).