Many biological organisms with exceptional freezing tolerance can resist the damages to cells from extra-/intracellular ice crystals and thus maintain their mechanical stability at subzero temperatures. Inspired by the freezing tolerance mechanisms found in nature, here we report a strategy of combining hydrophilic/oleophilic heteronetworks to produce self-adaptive, freeze-tolerant and mechanically stable organohydrogels. The organohydrogels can simultaneously use water and oil as a dispersion medium, and quickly switch between hydrogel- and organogel-like behaviours in response to the nature of the surrounding phase. Accordingly, their surfaces display unusual adaptive dual superlyophobic in oil/water system (that is, they are superhydrophobic under oil and superoleophobic under water). Moreover, the organogel component can inhibit the ice crystallization of the hydrogel component, thus enhancing the mechanical stability of organohydrogel over a wide temperature range (−78 to 80 °C). The organohydrogels may have promising applications in complex and harsh environments.

Morphology control in laboratory and industry setting remains as a major challenge for organic solar cells (OSCs) due to the difference in film-drying kinetics between spin coating and the printing process. A two-step sequential deposition method is developed to control the active layer morphology. A conjugated polymer that self-assembles into a well-defined fibril structure is used as the first layer, and then a non-fullerene acceptor is introduced into the fibril mesh as the second layer to form an optimal morphology. A benefit of the combined fibril network morphology and non-fullerene acceptor properties was that a high efficiency of 16.5% (certified as 16.1%) was achieved. The preformed fibril network layer and the sequentially deposited non-fullerene acceptor form a robust morphology that is insensitive to the polymer batches, solving a notorious issue in OSCs. Such progress demonstrates that the utilization of polymer fibril networks in a sequential deposition process is a promising approach towards the fabrication of high-efficiency OSCs.

The lightweight and high-strength functional nanocomposites are important in many practical applications. Natural biomaterials with excellent mechanical properties provide inspiration for improving the performance of composite materials. Previous studies have usually focused on the bionic design of the material’s microstructure, sometimes overlooking the importance of the interphase in the nanocomposite system. In this Perspective, we will focus on the construction and control of the interphase in confined space and the connection between the interphase and the macroscopic properties of the materials. We shall survey the current understanding of the critical size of the interphase and discuss the general rules of interphase formation. We hope to raise awareness of the interphase concept and encourage more experimental and simulation studies on this subject, with the aim of an optimal design and controllable preparation of polymer nanocomposite materials.