The aim of this study was to investigate the effects of the Ti element addition on the microstructure and properties of CoCrFeNiMn high entropy alloys. The Ti element modified CoCrFeNiMnTi_x high entropy alloys were prepared by vacuum arc melting processing. The Ti rich body-centered cubic structure phase was observed in CoCrFeNiMnTi_0.25 and CoCrFeNiMnTi_0.55 instead of a simple face-centered cubic structure in CoCrFeNiMn. The amount of the Ti-rich phase depicted an increasing trend with increasing Ti content. Simultaneously, the mechanical properties of CoCrFeNiMnTi_x were obviously improved. When the Ti content is 0, 0.25 and 0.55, the microhardness is 175 HV, 253 HV and 646 HV, which has an obvious increasing trend, while the ductility decreased. The tensile properties show a trend of first strengthening and then decreasing, changing from 461 MPa to 631 MPa and then to 287 MPa. When x was 0.55, the solid–liquid transition temperature of the alloy decreased, and the melting temperature range increased.

Friction stir spot welding (FSSW) of Al to Ti alloys has broad applications in the aerospace and automobile industries, while its narrow joining area limits the improvement of mechanical properties of the joint. In the current study, an Al-coating was prepared on Ti6Al4V alloy by hot-dipping prior to joining, then a Zn interlayer was used during friction stir joining of as-coated Ti alloy to the 2014-Al alloy in a lap configuration to introduce a brazing zone out of the stir zone to increase the joining area. The microstructure of the joint was investigated, and the joint strength was compared with the traditional FSSW joint to confirm the advantages of this new process. Because of the increase of the joining area, the maximum fracture load of such joint is 110% higher than that of the traditional FSSW joint under the same welding parameters. The fracture load of these joints depends on the joining width, including the width of solid-state bonding region in stir zone and brazing region out of stir zone.

To protect magnesium alloy surfaces from wear and corrosion, an Fe-based amorphous coating was prepared on WE43 through the Ni60 interlayer by high-velocity oxygen-fuel (HVOF) spraying. The porosity was ~1%, and the amorphous content exceeded 90%. The wear and corrosion resistance of the composite coating with WC particles wrapped in a Ni layer as the reinforcing phase were compared with that of the completely amorphous coating. The friction coefficient (COF) of the composite coating was 0.3, which is only half of that of the WE43 substrate, and the composite coating exhibited a more stable wear behavior than the completely amorphous coating. The corrosion tendency of the composite coating is lower than that of stainless steel, with a corrosion potential of −0.331 V, and the addition of WC particles did not deteriorate the corrosion resistance considerably. The bonding mechanism of the bonding interface between the amorphous structure and the particles of the reinforcing phase was investigated by transmission electron microscopy (TEM). Reinforcing particles were confirmed to form metallurgical bonding with the coating. It was found that the Ni layer showed excellent bonding performance in the form of a mixture that is amorphous and nanocrystalline. Therefore, the Fe-based amorphous composite coating on a magnesium alloy surface shows a potential protective effect.

5A06 aluminum alloy bar was brazed by temperature gradient transient liquid phase diffusion welding (TG-TLP). The effects of brazing temperature on the microstructure and the tensile strength of the brazing joints were investigated. Three typical brazing filler alloys (1^# Al-20Cu-6Si-2Ni, 2^# Al-10Cu-10Si-3Mg-1Ga, and 3^# Al-6Cu-10Si-2Mg-10Zn) were prepared by smelting, and TG-TLP diffusion bonding was carried out at different brazing temperatures (550 °C~590 °C). The results show that with the increase in brazing temperature, the oxide films at the brazing junction are easier to be broken and dispersed, but the oxidation extent will also increase. The oxidation products enriched were mainly Al₂O₃ and SiO₂ at the brazing junction. There are different optimal brazing temperatures corresponding to the different filler alloys. For 1^#, the optimal temperature is 570 °C; for 2^# is 580 °C; for 3^# is 580 °C. For 1^# brazing joints, the maximum tensile strength was 113 MPa, and for 2^# was 122.4 MPa. Under the experimental conditions of this study, the maximum tensile strength of the TG-TLP joint is 147.4 MPa of 3^# brazing sample (at 580 °C), which has increased by 30% and 20% compared to 1^# and 2^# respectively. The nickel-rich phase at the interface (of 1^# brazing filler) could form a brittle fracture, which was unfavorable for interface bonding. For TG-TLP brazing of 5A06, the filler alloy with high Al:Cu ratio (12:1 wt.%) needs a sufficient temperature gradient to exert the film-breaking effect, while the filler alloy with low Al:Cu ratio (3.6:1 wt.%) needs to accurately control its brazing temperature to avoid excessive oxidation. There are many research gaps in the influence of brazing material composition and brazing temperature on the microstructure and mechanical properties of 5A06 aluminum alloy TG-TLP joints. The research results can provide a theoretical basis for formulating the TG-TLP brazing specification of 5A06 aluminum alloy.