This study aimed to prepare antifouling and highly mechanical strengthening membranes for brackish and underground water desalination. It was designed from cellulose acetate (CA) loaded anatase. Anatase was prepared from tetra-iso-propylorthotitanate and carboxymethyl cellulose. Different concentrations of anatase (0.2, 0.3, 0.5, 0.6, 0.7, and 0.8)% were loaded onto CA during the inversion phase preparation of the membranes. The prepared membranes were characterized using Fourier Transform Infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy (SEM & EDX), mechanical properties, swelling ratio, porosity determination, and ion release. The analysis confirmed the formation of anatase on the surface and inside the macro-voids of the membrane. Furthermore, anatase loading improved the CA membrane’s mechanical properties and decreased its swelling and porosity rate. Also, CA-loaded anatase membranes displayed a significant antibacterial potential against Gram-positive and Gram-negative bacteria. The results showed that the salt rejection of the CA/anatase films as-prepared varies considerably with the addition of nanomaterial, rising from 46%:92% with the prepared membranes under the 10-bar operation condition and 5 g/L NaCl input concentration. It can be concluded that the prepared CA-loaded anatase membranes have high mechanical properties that are safe, economical, available, and can stop membrane biofouling.
Egypt faces significant challenges in managing its sewage sludge generated in large quantities from wastewater treatment plants. This study investigates the feasibility of utilizing sewage sludge as a renewable resource for hydrogen production through anaerobic digestion at the 100 L bioreactor level. Hydrogen is considered a promising alternative energy source due to its high energy content and environmental benefits. To optimize the microbial degradation process and maximize hydrogen production from sewage sludge, a specialized pretreatment is necessary. Various pretreatment methods have been applied to the sewage sludge, individually and in combination, to study the bio-hydrogen production from sewage sludge. The four methods of treatment were studied in batch assays as a pilot scale. Thermal pretreatment of sewage sludge significantly increases bio-hydrogen production yield compared to other sewage sludge pretreatment methods, producing the highest H2 yield (6.48 LH2/g VS). In general, the hydrogen yield of any type of pretreated inoculum was significantly higher than the untreated inoculum. At the same time, alkaline pretreatment improved the hydrogen yield (1.04 LH2/g VS) more than acid pretreatment (0.74 LH2/g VS), while the hydrogen yield for the combination of pretreatments (shock alkali pretreatment) was higher than both (1.73 LH2/g VS), On the other hand, untreated sewage sludge (control) had almost no hydrogen yield (0.03 LH2/g VS). The self-fermented anaerobic bioreactor improved sewage sludge utilization, increased bioenergy yields, and seems to be promising for treating complex wastes at this scale.
In an attempt to improve the quality of the agricultural drain in Egypt for its reuse again in the irrigation, low-cost solution such as sand filter along with/without other filtration media has been used in this research. As a result of that, pilot plant of sand filter mixed with other filtration media was tested for its ability to improve the sand performance in removing the suspended solids and organic matters from agricultural drain water of the Belbeis drain (in Sharkia governorate in Egypt). Sand only, sand mixed with sponge, sand mixed with activated carbon and sand mixed with ceramic cylinders have been tested to find the best media combination and optimum mixing sand/ medium ratio and optimum infiltration rate. The work has been done on four runs. It was found that sand mixed with ceramic cylinders gave the best removal efficiency with respect to total chemical oxygen demand and chemical oxygen demand for solution which were 77, 74%, respectively, whereas sand mixed with sponge had the best removal efficiency with respect to total suspended solids which was 89%. Also, all tested media combination had effluent quality that complied with Egyptian law 48 for the year 1982 regarding the disposal of wastewater into agricultural drains (chemical oxygen demand ≤ 80 mg/l, total suspended solids ≤ 50 mg/l).
Selecting the appropriate desalination and renewable energy technologies is crucial for the success of desalination projects, as each technology offers distinct advantages and disadvantages tailored to specific project requirements. This research investigates the application of both the analytic hierarchy process and fuzzy logic techniques to develop four decision-making models: two for selecting the optimal desalination technology and two for selecting the optimal renewable energy technology in coastal communities. For desalination technology selection, the analytic hierarchy process model is structured into four hierarchical levels: the main goal, criteria, sub-criteria, and alternatives. The criteria level encompasses four groups, while the sub-criteria level comprises 26 factors. The alternatives considered are reverse osmosis, electrodialysis, and multi-stage flash. In parallel, the analytic hierarchy process model for renewable energy technology selection is similarly structured, with four criteria groups and 24 sub-criteria factors. The alternatives evaluated include photovoltaic, concentrated solar power, and wind energy. Additionally, fuzzy logic models are developed for both desalination and renewable energy technology selection. These models enhance the decision-making framework by incorporating the uncertainty and vagueness that are inherent in real-world scenarios. The integration of analytic hierarchy process and fuzzy logic methodologies provide a robust approach to identifying optimal technologies, thereby supporting sustainable development in Egypt’s water–energy nexus. The research outcomes highlight the effectiveness of integrating analytic hierarchy process and fuzzy logic in decision-making processes, offering decision-makers systematic and reliable approaches for selecting the most suitable technologies to achieve sustainability in water–energy nexus projects. The results of the research indicate that the best alternative for desalination was reverse osmosis, and for renewable energy was photovoltaics.
Desalination of sea water projects are critical for addressing water scarcity in regions like Egypt, but they face numerous risks that can hinder their success. This study identifies and analyzes 53 risk factors affecting renewable energy desalination projects through expert interviews, literature review, and a questionnaire survey completed by 47 experts. Statistical methods, including descriptive statistics (mean, mode, standard error, and standard deviation), Pearson correlation, and Cronbach's alpha, were employed to validate the reliability and significance of these factors. The overall questionnaire showed excellent reliability (α = 0.815 for probability of occurrence; α = 0.921 for degree of impact). The results indicate a strong consensus among industry experts. Inflation and price fluctuations was ranked as the highest-probability risk (mean = 4.32/5), while faulty design of plant components (intake, outfall, mechanical systems) was ranked as the highest-impact risk (mean = 4.51/5). Conversely, environmental disasters (earthquakes, floods) showed the lowest probability of occurrence (mean = 1.91/5), and social pressures from entities not directly invested in the project’s success showed the lowest degree of impact (mean = 2.70/5). These statistically validated findings provide project stakeholders with critical insights into the most significant threats to desalination initiatives in Egypt's unique operational context. These findings provide a robust basis for understanding and managing risks in desalination projects, contributing to grow the knowledge on desalination project sustainability and offers actionable insights for stakeholders in Egypt and similar arid regions.
In an attempt to improve the quality of the agricultural drain in Egypt for its reuse again in the irrigation, low cost solution such as sand filter along with/ without other filtration media have been used in this research, As a result of that, pilot plant of sand filter mixed with other filtration media was tested for its ability to improve the sand performance in removing the suspended solids and organic matters from agricultural drain water of the Belbeis drain (in Sharkia governorate in Egypt). Only sand compared with sand with sponge and sand with Liyan Nanfang activated carbon (L.N.A.C) have been tested to find the optimum mixing sand/ medium ratio &optimum infiltration rate. The work has been done on four runs. It was found that sand mixed with sponge gave the best removal efficiency compared to that of the sand only and the sand mixed with L.N.A.C. The results presented that the concentration of CODt, CODsol and TSS was reduced from 125, 47 and 162 mg/l to 44, 34 and 28 mg/l respectively at optimum infiltration rate of 2 m3/m2/d for sand mixed with sponge.