Compared to conventional allothermal gasification of solid fuels (e.g., biomass, charcoal, lignite, etc.), plasma-assisted gasification offers an efficient method for applying energy to the gasification process to increase the flexibility of operation conditions and to increase the reaction kinetics. In particular, non-thermal plasmas (NTP) are promising, in which thermal equilibrium is not reached and electrons have a substantially higher mean energy than gas molecules. Thus, it is generally assumed that in NTP the supplied energy is utilized more efficiently for generating free radicals initiating gasification reactions than thermal plasma processes. In order to investigate this hypothesis, we compared purely thermal to non-thermal plasma-assisted gasification of biomass in steam in a drop tube reactor at atmospheric pressure. The NTP was provided by means of gliding arcs between two electrodes aligned in the inlet steam flow with an electric power of about 1 kW. Reaction yields and rates were evaluated using measured gas temperatures by the optical technique. The first experimental results show that the non-thermal plasma not only promotes the carbon conversion of the fuel particles, but also accelerates the reaction kinetics. The carbon conversion is increased by nearly 10% using wood powder as the fuel. With charcoal powder, more than 3% are converted into syngas.

1-methylnaphthalene (1-MN) is a widely used laser-induced fluorescence (LIF) tracer for planar imaging of mixture formation and temperature distributions in internal combustion (IC) engines. As the LIF measurement results can be biased by partial tracer oxidation, the conversion of 1-MN and the base fuel isooctane is analyzed in a calibration cell. First, measurements using supercontinuum laser absorption spectroscopy (SCLAS) are presented in order to quantify the conversion by detection of the produced H₂O mole fraction. A single mode fiber (SMF) coupled setup is presented, with the fiber core acting as entrance slit of a Czerny-Turner spectrometer. Dependencies on residence time and global air-fuel ratio are presented at pressures up to 1.5 MPa and temperatures up to 900 K, at which distinct tracer and fuel consumption is observed. Signal loss due to intense beam steering was partially compensated using a self-stabilizing double-pass setup with a retroreflector.

A novel supercontinuum laser absorption spectroscopy (SCLAS) approach combining a planar external Herriott multi-pass cell (HMPC) with fully single-mode fiber (SMF) coupling is presented for broadband multi-scalar combustion measurements in a rapid compression expansion machine (RCEM). For the HMPC, 1-dimensional refractive index gradients occurring in the RCEM combustion chamber are analyzed via ray-tracing with respect to axial and vertical beam steering. The impact of beam steering on the SCLAS signal is compared with the ray-tracing analysis and high-speed flame luminosity images. SCLAS based measurements are presented during compression, auto-ignition and combustion in the RCEM for n-heptane/methane mixtures at varied AFR (air-fuel ratio) and n-heptane/EGR (exhaust gas recirculation) mixtures at temperatures exceeding 1800 K and pressures up to 80 bar. Simultaneous temperature and mole fraction courses of H₂O, CH₄, and CO₂ are inferred from NIR (near-infrared) broadband absorbance spectra detected by a Czerny Turner spectrometer (CTS) in a spectral range of 1374 nm to 1669 nm. The multi-pass approach with SMF coupling, which avoids multi-mode fiber induced noise, allows for high-speed multi-species SCLAS measurements with low standard deviations; for temperature this amounts to about 5 K and partially below at a temporal resolution of 25 µs.

Compared to conventional allothermal gasification of solid fuels (e.g. biomass, charcoal, lignite etc.), plasma-assisted gasification offers an efficient method to apply energy into the gasification process to increase the flexibility of operation conditions and to increase the reaction kinetics. In particular, non-thermal plasmas (NTP) are promising, in which thermal equilibrium is not reached and electrons have substantially higher mean energy than gas molecules. Thus it is generally assumed that in NTP the supplied energy is utilized more efficiently for generating free radicals initiating gasification reactions than thermal plasma processes. In order to investigate this hypothesis, we compared purely thermal to non-thermal plasma assisted gasification of biomass in steam in a drop tube reactor at atmospheric pressure. The NTP was provided by means of gliding arcs between two electrodes aligned in the inlet steam flow. Electric power of about 1 kW was supplied using a high voltage generator operating at frequencies between 70 and 150 kHz and voltage amplitudes up to 10 kV. A laser-assisted optical method (Raman spectroscopy) was applied for measuring the gas temperature both in the conventionally heated steam and flow-down of the visible plasma filaments of the gliding arcs. Reaction yields and rates were evaluated using these measured gas temperatures. The first experimental results have shown that the non-thermal plasma not only promotes the carbon conversion of the fuel particles, but also accelerates the reaction kinetics. The carbon conversion is increased by nearly 10% using wood powder as the fuel. With charcoal powder more than 3% are converted into syngas.