[NiCl₂(C₁₄H₁₂N₂)(H₂O)] complex has been synthesized from nickel chloride hexahydrate (NiCl₂·6H₂O) and 2,9-dimethyl-1,10-phenanthroline (dmphen) as N,N-bidentate ligand. The synthesized complex was characterized by elemental analysis, infrared (IR) spectroscopy, ultraviolet-visible (UV-vis) spectroscopy and differential thermal/thermogravimetric analysis (TG/DTA). The complex was further confirmed by single crystal X-ray diffraction (XRD) as triclinic with space group P-1. The desired complex, subjected to thermal decomposition at low temperature of 400 °C in an open atmosphere, revealed a novel and facile synthesis of pure NiO nanoparticles with uniform spherical particle; the structure of the NiO nanoparticles product was elucidated on the basis of Fourier transform infrared (FT-IR), UV-vis spectroscopy, TG/DTA, XRD, scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDXS) and transmission electron microscopy (TEM).

Inorganic metal-halide perovskites hold a lot of promise for solar cells, light-emitting diodes, and lasers. A thorough investigation of their optoelectronic properties is ongoing. In this study, the accurate modified Becke Johnson generalized gradient approximation (mBJ-GGA) method without/with spin orbital coupling (SOC) implemented in the WIEN2k code was used to investigate the effect of mixed I/Br and Br/Cl on the electronic and optical properties of orthorhombic CsPb(I_1–xBr_x)₃ and CsPb(Br_1–xCl_x)₃ perovskites, while the Perdew–Burke–Ernzerhof generalized gradient approximation (PBE-GGA) method was used to investigate their structural properties. The calculated band gap (E_g) using the mBJ-GGA method was in good agreement with the experimental values reported, and it increased clearly from 1.983 eV for CsPbI₃ to 2.420 and 3.325 eV for CsPbBr₃ and CsPbCl₃, respectively. The corrected mBJ + SOC E_g value is 1.850 eV for CsPbI₃, which increased to 2.480 and 3.130 eV for CsPbBr₃ and CsPbCl₃, respectively. The calculated photoabsorption coefficients show a blue shift in absorption, indicating that these perovskites are suitable for optical and optoelectronic devices.

The effect of halide composition on the structural, electronic, and optical properties of CsPb(Br_1−xCl_x)₃ perovskite was investigated in this study. When the chloride (Cl) content of x was increased, the unit cell volume decreased with a linear function. Theoretical X-ray diffraction analyses showed that the peak (at 2θ = 30.4°) shifts to a larger angle (at 2θ = 31.9°) when the average fraction of the incorporated Cl increased. The energy bandgap (E_g) was observed to increase with the increase in Cl concentration. For x = 0.00, 0.25, 0.33, 0.50, 0.66, 0.75, and 1.00, the E_g values calculated using the Perdew–Burke–Ernzerhof potential were between 1.53 and 1.93 eV, while those calculated using the modified Becke−Johnson generalized gradient approximation (mBJ–GGA) potential were between 2.23 and 2.90 eV. The E_g calculated using the mBJ–GGA method best matched the experimental values reported. The effective masses decreased with a concentration increase of Cl to 0.33 and then increased with a further increase in the concentration of Cl. Calculated photoabsorption coefficients show a blue shift of absorption at higher Cl content. The calculations indicate that CsPb(Br_1−xCl_x)₃ perovskite could be used in optical and optoelectronic devices by partly replacing bromide with chloride.

The growth of nanocrystals (NCs) from metal oxide-based substrates with exposed high-energy facets is of particular importance for many important applications, such as solar cells as photoanodes due to the high reactivity of these facets. The hydrothermal method remains a current trend for the synthesis of metal oxide nanostructures in general and titanium dioxide (TiO₂) in particular since the calcination of the resulting powder after the completion of the hydrothermal method no longer requires a high temperature. This work aims to use a rapid hydrothermal method to synthesize numerous TiO₂-NCs, namely, TiO₂ nanosheets (TiO₂-NSs), TiO₂ nanorods (TiO₂-NRs), and nanoparticles (TiO₂-NPs). In these ideas, a simple non-aqueous one-pot solvothermal method was employed to prepare TiO₂-NSs using tetrabutyl titanate Ti(OBu)₄ as a precursor and hydrofluoric acid (HF) as a morphology control agent. Ti(OBu)₄ alone was subjected to alcoholysis in ethanol, yielding only pure nanoparticles (TiO₂-NPs). Subsequently, in this work, the hazardous chemical HF was replaced by sodium fluoride (NaF) as a means of controlling morphology to produce TiO₂-NRs. The latter method was required for the growth of high purity brookite TiO₂ NRs structure, the most difficult TiO₂ polymorph to synthesize. The fabricated components are then morphologically evaluated using equipment, such as transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), electron diffraction (SAED), and X-ray diffraction (XRD). In the results, the TEM image of the developed NCs shows the presence of TiO₂-NSs with an average side length of about 20–30 nm and a thickness of 5–7 nm. In addition, the image TEM shows TiO₂-NRs with diameters between 10 and 20 nm and lengths between 80 and 100 nm, together with crystals of smaller size. The phase of the crystals is good, confirmed by XRD. The anatase structure, typical of TiO₂-NS and TiO₂-NPs, and the high-purity brookite-TiO₂-NRs structure, were evident in the produced nanocrystals, according to XRD. SAED patterns confirm that the synthesis of high quality single crystalline TiO₂-NSs and TiO₂-NRs with the exposed {001} facets are the exposed facets, which have the upper and lower dominant facets, high reactivity, high surface energy, and high surface area. TiO₂-NSs and TiO₂-NRs could be grown, corresponding to about 80% and 85% of the {001} outer surface area in the nanocrystal, respectively.

Photonic devices based on perovskite materials are considered promising alternatives for a wide range of these devices in the future because of their broad bandgaps and ability to contribute to light amplification. The current study investigates the possibility of improving the light amplification characteristics of CsPbBr₃ perovskite quantum dot (PQD) films using the surface encapsulation technique. To further amplify emission within a perovskite layer, CsPbBr₃ PQD films were sandwiched between two transparent layers of poly(methyl methacrylate) (PMMA) to create a highly flexible PMMA/PQD/PMMA waveguide film configuration. The prepared perovskite film, primed with a polymer layer coating, shows a marked improvement in both emission efficiency and amplified spontaneous emission (ASE)/laser threshold compared with bare perovskite films on glass substrates. Additionally, significantly improved photoluminescence (PL) and long decay lifetime were observed. Consequently, under pulse pumping in a picosecond duration, ASE with a reduction in ASE threshold of ~1.2 and 1.4 times the optical pumping threshold was observed for PQDs of films whose upper face was encapsulated and embedded within a cavity comprising two PMMA reflectors, respectively. Moreover, the exposure stability under laser pumping was greatly improved after adding the polymer coating to the top face of the perovskite film. Finally, this process improved the emission and PL in addition to enhancements in exposure stability. These results were ascribed in part to the passivation of defects in the perovskite top surface, accounting for the higher PL intensity, the slower PL relaxation, and for about 14 % of the ASE threshold decrease.

Brookite TiO₂ is the most difficult TiO₂ polymorph to synthesize. The available methods in the literature to produce brookite nanostructures mostly use water-based techniques for the preparation of water-soluble Ti complexes first, followed by a hydrothermal growth of the brookite nanostructures. Besides its multi-step nature, achieving a single brookite phase and optimizing the aqueous growth environment are all issues to be hardly controlled. In this work, pure brookite TiO₂ nanorods are synthesized using tetrabutyl titanate Ti(OBu)₄ and Sodium Fluoride (NaF) as precursor materials in a simple non-aqueous one-pot solvothermal process. Alcoholysis of only Ti(OBu)₄ in ethanol resulted in pure anatase nanoparticles, while the addition of NaF was essential to promote the growth of highly pure brookite nanorods. The phase purity is confirmed by X-Ray Diffraction, Raman Spectroscopy, and High-Resolution Transmission Electron Microscopy. The growth mechanism is explained according to the Ostwald’s step rule, where Na⁺ ions are anticipated to have a potential role in driving the growth process towards the brookite phase.