This paper describes the crystal interphase impact of ZnFe₂O₄-Ag in the photodegradation of Rhodamine B. Prepared ZnFe₂O₄ nanoparticles (NPs) were deposited with Ag NPs to offer ZnFe₂O₄-Ag (0-2.5%). An X-ray diffraction peak corresponding to the Ag NPs was detected if the particle content reached about 2.0%, observing multiple crystalline interphases in HR-TEM. Magnetic saturation (Ms) was increased ∼160% times for ZnFe₂O₄-Ag (7.25 to 18.71 emu/g) and ZnFe₂O₄ (9.62 to 25.09 emu/g) if the temperature is lowered from 298 to 5.0 K; while for Fe₃O₄ (91.09 to 96.19 emu/g), the Ms increment was just about 5.6%. After analyzing the DFT-Density of State, a decrease of bandgap energy for ZnFe₂O₄-Ag₆ from the influence of the size of Ag cluster was seen. Quantum yield (Φ) was 0.60 for ZnFe₂O₄, 0.25 for ZnFe₂O₄-Ag (1.0%), 0.70 for ZnFe₂O₄-Ag (1.5%), 0.66 for ZnFe₂O₄-Ag (2.0%), and 0.66 for ZnFe₂O₄-Ag (2.5%), showing that the disposition of Ag NPs (1.5-2.5%) increases the Φ to >0.60. The samples were used to photo-oxidize RhB under visible light assisted by photopowered Langmuir adsorption. The degradation follows first-order kinetics (k = 5.5 × 10^-3 min^-1), resulting in a greater k = 2.0 × 10^-3 min^-1 for ZnFe₂O₄-Ag than for ZnFe₂O₄ (or Fe₃O₄, k = 1.1 × 10^-3 min^-1). DFT-total energy was used to analyze the intermediates formed from the RhB oxidation. Finally, the ZnFe₂O₄-Ag exhibits good antibacterial behavior because of the presence of Zn and the Ag components.

We developed a technique that detects Al3+ in milk/bio-samples, and reversibly applied to recognize tetracycline (TC) in milk, enhancing the fluorescence intensity without interference from other cations (Cd2+, Ni2+, Co2+, Sr2+, Mg2+, Fe3+, K+, Sm3+, Ag+, Na+, Ba2+, Cr3+, Zn2+ and Mn2+); the limit of detection (LOD) is found to be 0.00022 mM with r2 = 0.9439. The detection of Al3+ is tested in milk as well as in living cells (Saccharomyces cerevisiae and Debaryomyces spp.) by TC or by its quantum dots. This is consistent with the molecular orbital, revealing that the lowering of the energy of HOMO (Highly Occupied Molecular Orbital) discourages the electron transfer from HOMO of fluorophore to HOMO of excited states of Al-complex that increases the fluorescent intensity. Interestingly, carbon dots (CDs) generated from TC also recognize Al3+ as its LOD is as low as to 0.00050 mM with r2 of 0.9404.