This paper describes the crystal interphase impact of ZnFe₂O₄-Ag in the photodegradation of Rhodamine B. Prepared ZnFe₂O₄ nanoparticles (NPs) were deposited with Ag NPs to offer ZnFe₂O₄-Ag (0-2.5%). An X-ray diffraction peak corresponding to the Ag NPs was detected if the particle content reached about 2.0%, observing multiple crystalline interphases in HR-TEM. Magnetic saturation (Ms) was increased ∼160% times for ZnFe₂O₄-Ag (7.25 to 18.71 emu/g) and ZnFe₂O₄ (9.62 to 25.09 emu/g) if the temperature is lowered from 298 to 5.0 K; while for Fe₃O₄ (91.09 to 96.19 emu/g), the Ms increment was just about 5.6%. After analyzing the DFT-Density of State, a decrease of bandgap energy for ZnFe₂O₄-Ag₆ from the influence of the size of Ag cluster was seen. Quantum yield (Φ) was 0.60 for ZnFe₂O₄, 0.25 for ZnFe₂O₄-Ag (1.0%), 0.70 for ZnFe₂O₄-Ag (1.5%), 0.66 for ZnFe₂O₄-Ag (2.0%), and 0.66 for ZnFe₂O₄-Ag (2.5%), showing that the disposition of Ag NPs (1.5-2.5%) increases the Φ to >0.60. The samples were used to photo-oxidize RhB under visible light assisted by photopowered Langmuir adsorption. The degradation follows first-order kinetics (k = 5.5 × 10^-3 min^-1), resulting in a greater k = 2.0 × 10^-3 min^-1 for ZnFe₂O₄-Ag than for ZnFe₂O₄ (or Fe₃O₄, k = 1.1 × 10^-3 min^-1). DFT-total energy was used to analyze the intermediates formed from the RhB oxidation. Finally, the ZnFe₂O₄-Ag exhibits good antibacterial behavior because of the presence of Zn and the Ag components.

Biomolecules like cysteine and cytosine play a significant role in many physiological processes, and their unusual level in biological systems can lead to many diseases including cancer. Indeed, the need for selective detection of these moieties by a fluorescence probe is imperative. Thus, thiophene based Schiff N,N′-bis(thiophene-2-ylmethylene)thiophenemethane (BMTM) was synthesized and then characterized using several analytical techniques before converting it into organic nanoparticles (ONPs). Then, fluorescent organic inorganic nanohybrids (FONs) were obtained after decorating ONPs with AuNPs to yield BMTM-Au-ONPs (FONPs). The morphology of the particles, analyzed using a Transmission Electron Microscope (TEM), shows that AuNPs were embedded with low density organic matter (ONPs). FONPs were employed to recognize cysteine and cytosine simultaneously. No interference was observed from other moieties such as guanine, uracyl, NADH, NAD, ATP, and adenine during the detection. It means that the intensity of the fluorescence signal was significantly changed (enhanced for cytosine and quenched for cysteine). So, FONPs were used to detect cysteine and cytosine in real samples, like Saccharomyces cerevisiae cells. As expected, no considerable fluorescence signal for cysteine was observed, while for cytosine, strong fluorescence signals were detected in the cells. DFT was used to explain the interaction of FONPs with cysteine or cytosine.