Asuncion Fernandez

Dr. Asuncion Fernandez

Materials Science Institute of Seville (ICMS), CSIC and Univ. Seville, Avda. Américo Vespucio 49, 41092-Sevilla, Spain
orcid

Research Focus & Metrics

Academic Career Length

43Years (1984-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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20 August 2004 in Physical Review Letters
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Journal Article
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PCP. Crespo
P. Crespo
RLRocio Litrán
Rocio Litrán
TRTeresa Cristina de Rojas
Teresa Cristina de Rojas
MMMarta María Multigner
Marta María Multigner
Jesus M De La FuenteJesus M De La Fuente
Jesus M De La Fuente
Asuncion FernandezAsuncion Fernandez
Asuncion Fernandez
We report on the experimental observation of magnetic hysteresis up to room temperature in thiol-capped Au nanoparticles with 1.4 nm size. The coercive field ranges from 860 Oe at 5 K to 250 Oe at 300 K. It is estimated that the Au atoms exhibit a magnetic moment of μ=0.036μB. However, Au nanoparticles with similar size but stabilized by means of a surfactant, i.e., weak interaction between protective molecules and Au surface atoms, are diamagnetic, as bulk Au samples are. The apparent ferromagnetism is consequently associated with 5d localized holes generated through Au-S bonds. These holes give rise to localized magnetic moments that are frozen in due to the combination of the high spin-orbit coupling (1.5 eV) of gold and the symmetry reduction associated with two types of bonding: Au-Au and Au-S.

1 December 1995 in Applied Catalysis B: Environment and Energy
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Journal Article
Closed access
Asuncion FernandezAsuncion Fernandez
Asuncion Fernandez
GLG. Lassaletta
G. Lassaletta
VJV.M. Jiménez
V.M. Jiménez
AJA. Justo
A. Justo
AGAgustín R. González-Elipe
Agustín R. González-Elipe
YAY. Ait-Ichou
Y. Ait-Ichou

14 November 1997 in Applied Catalysis B: Environment and Energy
Verified
Journal Article
Closed access
JHJ Herrmann
J Herrmann
HTH Tahiri
H Tahiri
YAY Aitichou
Y Aitichou
GLG Lassaletta
G Lassaletta
AGAgustín R. González-Elipe
Agustín R. González-Elipe
Asuncion FernandezAsuncion Fernandez
Asuncion Fernandez

13 June 2001 in Angewandte Chemie International Edition
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Journal Article
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Jesus M De La FuenteJesus M De La Fuente
Jesus M De La Fuente
ABAfrica G. Barrientos
Africa G. Barrientos
TRTeresa Cristina de Rojas
Teresa Cristina de Rojas
Javier RojoJavier Rojo
Javier Rojo
JCJavier Cañada
Javier Cañada
SPSoledad Penadés
Soledad Penadés

1 February 1995 in Journal of Electron Spectroscopy and Related Phenomena
Verified
Journal Article
Closed access
VJV.M. Jiménez
V.M. Jiménez
Asuncion FernandezAsuncion Fernandez
Asuncion Fernandez
JEJ.P. Espinós
J.P. Espinós
AGAgustín R. González-Elipe
Agustín R. González-Elipe

9 April 2003 in Chemistry – A European Journal
Verified
Journal Article
Closed access
PDF file
ÁBÁfrica G Barrientos
África G Barrientos
Jesus M De La FuenteJesus M De La Fuente
Jesus M De La Fuente
TRTeresa Cristina de Rojas
Teresa Cristina de Rojas
Asuncion FernandezAsuncion Fernandez
Asuncion Fernandez
SPSoledad Penadés
Soledad Penadés