In this work, the poly(D-lactic acid)–polyethylene glycol–poly(D-lactic acid) (PDLA–PEG–PDLA) triblock copolymer as a novel modification agent was incorporated into poly(L-lactic acid) (PLLA) to improve the thermal and mechanical properties of PLLA. The influences of molecular weight of PEG in the triblock copolymer on the structure, crystallization behaviors, heat resistance and tensile properties of PDLA–PEG–PDLA/PLLA blends were investigated by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), differential scanning calorimetry (DSC), polarized optical microscopy (POM), thermogravimetric analysis (TGA) and tensile testing. The results from FTIR, XRD and DSC confirm the formation of a polylactide stereocomplex in the PLLA blends. The structure and properties of the stereocomplex crystals are different from those of pure PLLA. The melting temperature (T_m) of the stereocrystal is near 200 °C, which is significantly higher than that of the homogeneous crystal of PLLA. The effect of molecular weight of PEG on the crystal morphology of PLLA blends is also obvious. The improvement of tensile properties for PLLA blends is attributed to the crystal morphological features, which will potentially enhance the utility of the PLLA based polymer.

Lignin, a natural amorphous three-dimensional aromatic polymer, is investigated as an appropriate filler for biocomposites. The chemical modification of firsthand lignin is an effective pathway to accomplish acetoacetate functional groups replacing polar hydroxyl (–OH) groups, which capacitates lignin to possess better miscibility with poly(lactic acid) (PLA), compared with acidified lignin (Ac-lignin) and butyric lignin (By-lignin), for the sake of blending with poly(lactic acid) (PLA) to constitute a new biopolymer based composites. Generally speaking, the characterization of all PLA composites has been performed taking advantage of Fourier transform infrared (FTIR), scanning electron microscopy (SEM), dynamic Mechanical analysis (DMA), differential scanning calorimeter (DSC), thermogravimetric analysis (TGA), rheological analysis, and tensile test. Visibly, it is significant to highlight that the existence of acetoacetate functional groups enhances the miscibility, interfacial compatibility, and interface interaction between acetoacetate lignin (At-lignin) and PLA. Identical conclusions were obtained in this study where PLA/At-lignin biocomposites furthest maintain the tensile strength of pure PLA.

This paper presents an integrated multi-attribute decision-making (MADM) approach to aid selection of commercially available materials in the context of sustainable design. The MADM couples grey relational analysis (GRA) with an analytic hierarchy process (AHP) to rank alternative materials in terms of their economic, environmental, and social performance. AHP is used to determine the corresponding weighting values for the selected indicators. In addition, a case example is used to verify the proposed MADM method and demonstrate its practical application. Three alternative polymer materials, i.e., poly(vinyl chloride) (PVC), polypropylene (PP), and polyethylene (PE), are examined to determine their sustainability for plastic pipe design. The associated MADM result and the limitations of the approach are discussed to lay the foundation for further improvement.

An efficient and simple approach for the preparation of organic–inorganic intumescent interfacial flame retardants, aiming at enhancing the flame-retardant efficiency and interfacial adhesion between matrix and flame retardants was presented.