Polyether block amide (PEBA) nanocomposite membranes, including Graphene (GA)/PEBA membranes are considered to be a promising emerging technology for removing CO₂ from natural gas and biogas. However, poor dispersion of GA in the produced membranes at industrial scale still forms the main barrier to commercialize. Within this frame, this research aims to develop a new industrial approach to produce GA/PEBA granules that could be used as a feedstock material for mass production of GA/PEBA membranes. The developed approach consists of three sequential phases. The first stage was concentrated on production of GA/PEBA granules using extrusion process (at 170–210 °C, depending on GA concentration) in the presence of Paraffin Liquid (PL) as an adhesive layer (between GA and PEBA) and assisted melting of PEBA. The second phase was devoted to production of GA/PEBA membranes using a solution casting method. The last phase was focused on evaluation of CO₂/CH₄ selectivity of the fabricated membranes at low and high temperatures (25 and 55 °C) at a constant feeding pressure (2 bar) using a test rig built especially for that purpose. The granules and membranes were prepared with different concentrations of GA in the range 0.05 to 0.5 wt.% and constant amount of PL (2 wt.%). Also, the morphology, physical, chemical, thermal, and mechanical behaviors of the synthesized membranes were analyzed with the help of SEM, TEM, XRD, FTIR, TGA-DTG, and universal testing machine. The results showed that incorporation of GA with PEBA using the developed approach resulted in significant improvements in dispersion, thermal, and mechanical properties (higher elasticity increased by ~10%). Also, ideal CO₂/CH₄ selectivity was improved by 29% at 25 °C and 32% at 55 °C.

Asymmetric polyphenylsulfone (PPSU) membranes were fabricated by a non-solvent induced phase inversion method. Glycerin and silica nanoparticles were added into the polymer solution to investigate their effects on the material properties and gas separation performance of prepared membranes. The morphology and structure of PPSU membranes were analyzed by scanning electron microscopy (SEM), the surface roughness of the selective layer was analyzed by atomic force microscopy (AFM), and the surface free energy was calculated based on the contact angle measurements by using various solvents. The gas separation performance of PPSU membranes was estimated by measuring the permeability of CO₂ and CH₄. The addition of glycerin as a nonsolvent into the polymer solution changed the cross-section structure from finger-like structure into sponge-like structure due to the delayed liquid-liquid demixing process, which was confirmed by SEM analysis. The incorporation of silica nanoparticles into PPSU membranes slightly increased the hydrophilicity, which was confirmed by water contact angle results. PPSU membrane fabricated from the polymer solution containing 10 wt.% glycerin showed the best CO₂/CH₄ selectivity of 3.86 and the CO₂ permeability of 1044.01 Barrer. Mixed matrix PPSU membrane containing 0.1 wt.% silica nanoparticles showed the CO₂/CH₄ selectivity of 3.16 and the CO₂ permeability of 1202.77 Barrer.

The transition from fossil fuels to renewable energy sources often requires shifting toward biomass fuels such as agriculture residues and waste, which tend to emit higher emission rates during combustion, and one of them is sulfur compounds. The main objective of this study is to clarify the regularities of the formation of sulfur compounds depending on the technological factors when burning sulfur-containing biomass. The experiments were conducted on two experimental stands—models of 20 kW and 25 kW capacities of industrial boilers equipped with reciprocating grates—by burning sunflower husk pellets and meat bone meal. The influence of incomplete combustion (indicator CO concentration), flue gas recirculation, and combined effects of both factors on concentrations of SO₂, SO₃, and H₂S were investigated during experiments. In addition, 20–90% of the sulfur in the fuel is converted to SO₂, contingent upon the combustion conditions. These findings have practical implications for the design and operation of biomass combustion systems. The highest SO₂ emissions were observed when primary air was mixed with flue gas recirculation and at the highest content of CO. The correlation of SO₂ and SO₃ and SO₂ and H₂S concentrations in flue gases of boilers was investigated. The conversion ratio of SO₂ to SO₃ was determined under different combustion modes and showed that this ratio can reach up to 5%. The sulfur content in ash deposits in different areas of the actual industrial boiler was analyzed. The highest percent of sulfur (S = 20%) in ash was found on the first boiler pass.

In the present paper, molecular dynamics simulations were performed to study the influence of two temperature control strategies on water flow behaviour inside planar nanochannel. In the simulations, the flow was induced by the force acting on each water molecule in the channel. Two temperature control strategies were considered: (a) frozen wall simulations, in which the dynamics of confining wall atoms was not solved and the thermostat was applied to the water, and (b) dynamic wall simulations, in which the dynamics of confining wall atoms was solved, and the thermostat was applied to walls while water was simulated in the microcanonical ensemble. The simulation results show that the considered temperature control strategies has no effect on the shape of the water flow profile, and flow behaviour in the channel is well described by the Navier–Stokes equation solution with added slip velocity. Meanwhile, the slip velocity occurring at the boundaries of the channel is linearly dependent on the magnitude of the flow inducing force in both frozen wall and dynamic wall simulations. However, the slip velocity is considerably greater in simulations when the wall dynamics are solved in contrast to the frozen wall simulations.

A numerical investigation of flow topology in open-type cavities with length-to-depth ratio L/h₁ = 4 was performed in the Reynolds number range of 10–1000. Cavities with differently rounded corners were chosen for simulation. Three-dimensional numerical simulations were performed to analyse flow topology in different planes. A series of experiments was performed to ensure the validity of numerical simulations. Both numerical simulations and physical experiments were conducted with water as the working fluid. Since the results agreed acceptably, further simulations were performed. The main goal of this study was to investigate and highlight the influence of rounded cavity corners on the topology and stability of flow. Analysis revealed that fully rounded upper cavity corners decrease pressure loss compared to other investigated cases; therefore, the velocity of the main flow is increased. Additionally, fully rounded upper corners form a notably smaller recirculation zone compared to other investigated cases. Flow stability analysis showed that fully rounded cavity bottom corners negatively impact flow stability by increasing the intensity of turbulence.

Flow stabilization and velocity uniformity in a Göttingen-type closed-circuit subsonic aerodynamic wind tunnel with an expanded test section are investigated in this study. Both experimental and numerical approaches were employed. The experiments were performed by using Laser Doppler Anemometry, Pitot tubes, and thermal anemometry. For numerical simulations, Reynolds-averaged Navier–Stokes simulations with a standard k-ε turbulence model were employed to evaluate flow characteristics in the velocity range of 0.05–20 m/s. The study shows that a properly contoured contraction nozzle suppresses inlet turbulence and ensures stable Reynolds-independent core flow. The contraction nozzle significantly accelerates and redistributes the flow, allowing rapid hydrodynamic stabilization and ensuring velocity measurements with high repeatability. These characteristics are inherent in a benchmark facility. Additionally, the study shows that the outlet-to-inlet diameter has the most prominent role in longitudinal velocity distribution in the test section. An optimal ratio of 1.10 was identified, stabilizing the pressure distribution and providing the most uniform longitudinal velocity profile. These findings offer geometry-dependent design guidelines for achieving high-quality measurements in Göttingen-type wind tunnels with expanded test sections and support accurate velocity measurement instrument calibration and aerodynamic testing.