High performance low temperature co-fired ceramic (LTCC) dielectrics is highly desired for next generation information technology. The rational design is a key issue for the development of new LTCC materials. In comparison to the design of conventional electroceramics, more attention should be paid on the formation process of the material structure for that of LTCC, in addition to the physical properties, due to the special requirement in fabrication processing. In this paper, sintering mechanism of three types of LTCC materials, i.e., glass-ceramics, glass ceramic composite, and glass bonded ceramics, as well as important factors of their dielectric properties are discussed and summarized, and the design strategies for LTCC dielectrics, based on new matrix materials with much lower sintering temperature or higher quality, are proposed. As an example for rational design, oxyfluoride glass-ceramic based dielectrics, a new class of LTCC materials with low ɛ_r, is analyzed.

It is possible to improve the machinability of aluminum nitride-hexagonal boron nitride (AlN-h-BN) ceramics while maintaining high strength and high thermal conductivity. The composite ceramics with 0–30 wt% BN as secondary phase were prepared by hot pressed sintering, using yttrium oxide (Y₂O₃) as sintering aid. The phase composition, density, microstructure, mechanical properties, thermal conductivity, and dielectric properties were investigated. The sintering additives were favorable to purify the grain boundaries and improve densification, reacting with oxide impurities on the surface of raw material powder particles. The optimum BN content improved the flexural strength and fracture toughness of composite ceramics with 475 MPa and 4.86 MPa·m^1/2, respectively. With increasing the amount of BN, the thermal conductivity and hardness of composites gradually decreased, but the minimum value of thermal conductivity was still 85.6 W·m⁻¹·K⁻¹. The relative dielectric constant and dielectric loss tangent of the samples ranged from 6.8 to 8.3 and from 2.4 × 10⁻³ to 6.4 × 10⁻³, respectively, in 22–26 GHz.

BiFeO₃/Reduced Graphene Oxide (BFO/RGO) composites have been fabricated by a simple hydrothermal method. The X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman, and X-ray photoelectron spectroscopy (XPS) analysis reveal that graphene oxide was reduced in hydrothermal process and BFO/RGO composites were successfully synthesized. UV-visible absorption and photoluminescence properties show that the introduction of RGO can effectively reduce the recombination of photogenerated electron and hole pairs. Compared to the pristine BFO, the photocatalytic performance of BiFeO₃ Graphene Oxide (BGO) composites is enhanced for the degradation of Methylene blue (MB) solution under visible light irradiation, and the result shows that the optimal amount of Graphene Oxide (GO) in the composites is 60 mg (BGO60). The excellent photocatalytic performance is mainly ascribed to improved light absorption, increased reactive sites, and the low recombination rate of electron-hole pairs. This work can provide more insights into designing advanced photocatalysts for wastewater treatment and environmental protection.

Dielectric metamaterials based on ceramics have attracted considerable interest in the past few years owing to their low dielectric loss, simple structure, excellent multifield tunability, and good environmental adaptability. They are considered to be promising alternative to metal‐based metamaterials and can lead to a new strategy for the development of passive devices. In this review, the recent progress of ceramic‐based dielectric metamaterials in electromagnetic applications, energy applications, non‐Hermitian systems, and natural materials with near‐zero or negative refraction are summarized. The design principle and mechanism, as well as manufacturing technologies, are also introduced, and the current development trend of ceramic‐based dielectric metamaterials are proposed.