BiFeO3/Reduced Graphene Oxide (BFO/RGO) composites have been fabricated by a simple hydrothermal method. The X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman, and X-ray photoelectron spectroscopy (XPS) analysis reveal that graphene oxide was reduced in hydrothermal process and BFO/RGO composites were successfully synthesized. UV-visible absorption and photoluminescence properties show that the introduction of RGO can effectively reduce the recombination of photogenerated electron and hole pairs. Compared to the pristine BFO, the photocatalytic performance of BiFeO3 Graphene Oxide (BGO) composites is enhanced for the degradation of Methylene blue (MB) solution under visible light irradiation, and the result shows that the optimal amount of Graphene Oxide (GO) in the composites is 60 mg (BGO60). The excellent photocatalytic performance is mainly ascribed to improved light absorption, increased reactive sites, and the low recombination rate of electron-hole pairs. This work can provide more insights into designing advanced photocatalysts for wastewater treatment and environmental protection.
In this study, MOF/BiFeO3 composite (MOF, metal-organic framework) has been synthesized successfully through a one-pot hydrothermal method. The MOF/BiFeO3 composite samples, pure MOF samples and BiFeO3 samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and by UV–vis spectrophotometry. The results and analysis reveal that MOF/BiFeO3 composite has better photocatalytic behavior for methylene blue (MB) compared to pure MOF and pure BiFeO3. The enhancement of photocatalytic performance should be due to the introduction of MOF change the surface morphology of BiFeO3, which will increase the contact area with MB. This composing strategy of MOF/BiFeO3 composite may bring new insight into the designing of highly efficient photocatalysts.
In this work, a novel metal-organic framework (MOF) and BiVO4 (BVO) composite photocatalyst was successfully synthesized by an in-situ growth method. The characterization of obtained samples was done by X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, N2 adsorption, and photoluminescence spectroscopy. The photocatalytic performance of ZIF-8@BiVO4 composite was evaluated by the degradation of methylene blue (MB) under simulated visible light irradiation. Compared with the mixture of BVO and ZIF-8, the composite photocatalyst exhibited superior photodegradation efficiency, which could be attributed to the synergistic effect between BVO and ZIF-8. The reduced recombination of photogenerated electrons and holes was considered to be an important reason for the enhancement of photocatalytic performance. This design demonstrates a rational method to improve the photocatalytic performance by combining photocatalysts with MOFs.