The re-processing of mine tailings to obtain critical raw materials (CRMs) could reduce the mining of new deposits as well as ensure the profitable use of the waste materials. Though, it requires large scale industrial installations and the development of specialized technologies to obtain CRMs. New investment in mining activities is an operation, engaging for considerable financial resources involved. The scale of such an endeavor makes a new mining activity a high-risk operation due to several uncertainties present. Therefore, there is an acute need to use new tools to assess the risk associated with the planning and development of new mining activities. This study introduces a framework to evaluate the economic risk related to the re-processing of mine tailings to obtain CRMs. The framework, based on real options analysis (ROA), and sensitivity and uncertainty analysis, was applied to analyze the profitability of using mine tailings as a source of CRMs in the Chilean mining industry. The novelty of this approach consists in enabling the investment decision making including the uncertainties related to a novel investment mining project. RESULTS: show that tailing storage facilities in Chile have some stocks of CRMs, like scandium, whose extraction could be profitable. For the data used, the results of uncertainty and sensitivity analyses show that capital expenditure has a more significant influence than the other variables. Therefore, for the case of mine tailings re-processing, it is essential to develop processes and technologies that enable lower capital expenses.
The recycling of active materials from Li-ion batteries (LIBs) via froth flotation has gained interest recently. To date, recycled graphite has not been pure enough for direct reuse in LIB manufacturing. The present work studied the effect of particle sizes on the grade of recycled graphite. Furthermore, selective flocculation is proposed as a novel approach to control particle sizes and thus improve graphite grade by preventing the entrainment of cathode components. Zeta potential and particle size measurements were performed to find an optimal pH for electrically selective flocculation and to study the interaction of flocculants, respectively. Batch flotation experiments were performed to investigate the effect of particle size on the purity of the recovered graphite. Results suggested that, in the absence of ultrafine fine particles, battery-grade graphite of 99.4% purity could be recovered. In the presence of ultrafine particles, a grade of 98.2% was observed. Flocculating the ultrafine feed increased the grade to 98.4%, although a drop in recovery was observed. By applying a dispersant in addition to a flocculant, the recovery could be increased while maintaining a 98.4% grade. Branched flocculants provided improved selectivity over linear flocculants. The results suggest that particle size needs to be controlled for battery-grade graphite to be recovered.
7 June 2018 in Industrial & Engineering Chemistry Research
Minerals and metals are essential to the economic and social development of our society, and they are critical to modern life. The continuous exploitation of mineral resources has led to a large amount of waste, which has a large impact on the environment. One of the main streams of wastes in mining is mine tailings, which are produced in mineral processing plants. The mining industry must enhance its contribution to achieving sustainable development by incorporating the sustainable development goals into its operations. The objective of this article is to define targets and indicators for mine tailings management to achieve the sustainable development goals, defined in the 2030 Agenda for Sustainable Development by the United Nations. The result of this study is a collection of indicators proposed to measure the progress of mine tailings management towards sustainable development.
This research aims to analyze the behavior of bubble size distribution in the HydroFloat® with seawater and tap water. The study characterized bubble size in a two-phase gas–water system in a fluidized-bed flotation cell. The impact of seawater was compared to tap water using two frothers, MIBC and polyglycol F507. The experimental design was used to investigate the influence of various parameters such as superficial air velocity, superficial liquid velocity, frother concentration, and seawater concentration on bubble size. The results indicate that the critical coalescence concentration followed the order of MIBC > F507. Bubble size decreases with increasing superficial liquid velocity, while the superficial gas velocity and frother/seawater concentration have the opposite effect. ANOVA results reveal that all linear factors are significant, the quadratic terms of the frother and seawater concentrations are significant, and the interaction term for the superficial air velocity–superficial liquid velocity is nonsignificant for bubble size. Global sensitivity analysis demonstrates that the variables significantly affecting bubble size are frother concentration and seawater concentration, followed by superficial water velocity. The superficial gas velocity has minimal impact on bubble size under the conditions studied.