Electrochemical techniques are among the most commonly techniques used for the evaluation and study of corrosion in reinforced concrete, including electrochemical impedance spectroscopy (EIS). Electrochemical impedance spectroscopy (EIS) is a powerful technique for characterizing a wide variety of electrochemical systems and for determining the contribution of electrode or electrolytic processes in these systems. The analysis of EIS results on samples of concrete is highly complex due to overlapping arcs from simultaneous phenomena and noise measurement, of course, associated with the heterogeneity of the samples and that complicate the analysis considerably. Thus, this paper proposes a new form of analysis based on the characteristic relaxation angular frequency, w, of each phenomenon and associating the typical capacitances and frequencies.