Biochar as a stable carbon-rich material shows incredible potential to handle water/wastewater contaminants. Its application is gaining increasing interest due to the availability of feedstock, the simplicity of the preparation methods, and their enhanced physico-chemical properties. The efficacy of biochar to remove organic and inorganic pollutants depends on its surface area, pore size distribution, surface functional groups, and the size of the molecules to be removed, while the physical architecture and surface properties of biochar depend on the nature of feedstock and the preparation method/conditions. For instance, pyrolysis at high temperatures generally produces hydrophobic biochars with higher surface area and micropore volume, allowing it to be more suitable for organic contaminants sorption, whereas biochars produced at low temperatures own smaller pore size, lower surface area, and higher oxygen-containing functional groups and are more suitable to remove inorganic contaminants. In the field of water/wastewater treatment, biochar can have extensive application prospects. Biochar have been widely used as an additive/support media during anaerobic digestion and as filter media for the removal of suspended matter, heavy metals and pathogens. Biochar was also tested for its efficiency as a support-based catalyst for the degradation of dyes and recalcitrant contaminants. The current review discusses on the different methods for biochar production and provides an overview of current applications of biochar in wastewater treatment.
26 February 2024 in Environmental Science and Pollution Research
Olive oil extraction has recently experienced a continuous increase due to its related beneficial properties. Consequently, large amounts of olive mill wastes (OMWs) derived from the trituration process are annually produced, causing serious environmental problems. The limited financial capabilities of olive mills make them usually unable to bear the high costs required for the disposal of their wastes. Alternatively, the valorization of OMWs within the framework of the so-called waste-to-resource concept and their recycling can represent a successful strategy for the implementation of circular economy model in the olive industry, which could have significant socioeconomic impacts on low-income Mediterranean countries. There is, however, no unique solution for OMWs valorization, due to the wide variety of the wastes’ composition and their seasonal production. In this review, the potential of OMWs for being reused and the recent technological advances in the field of OMWs valorization are assessed. Special focus is given to the analysis of the advantages and limitations of each technology and to reporting the most significant issues that still limiting its industrial scale-up. The information collected in this review shows that OMW could be effectively exploited in several sectors, including energy production and agriculture. OMWs potential seems, however, undervalued, and the implementation of sustainable valorization strategies in large-scale remains challenging. More efforts and policy actions, through collective actions, encouraging subsidies, and establishing public–private collaborations, are still needed to reconcile research progress with industrial practices and encourage the large-scale implementation of the waste-to-resource concept in the olive sector.
Agricultural activities face several challenges due to the intensive increase in population growth and environmental issues. It has been established that biochar can be assigned a useful role in agriculture. Its agronomic application has therefore received increasing attention recently. The literature shows different applications, e.g., biochar serves as a soil ameliorant to optimize soil structure and composition, and it increases the availability of nutrients and the water retention capacity in the soil. If the biochar is buried in the soil, it decomposes very slowly and thus serves as a long-term store of carbon. Limiting the availability of pesticides and heavy metals increases soil health. Biochar addition also affects soil microbiology and enzyme activity and contributes to the improvement of plant growth and crop production. Biochar can be used as a compost additive and animal feed and simultaneously provides a contribution to minimizing greenhouse gas emissions. Several parameters, including biochar origin, pyrolysis temperature, soil type when biochar is used as soil amendment, and application rate, control biochar’s efficiency in different agricultural applications. Thus, special care should be given when using a specific biochar for a specific application to prevent any negative effects on the agricultural environment.
2 January 2020 in Environmental Science and Pollution Research
In the present study a new combined process, comprising filtration of raw olive mill wastewater (OMWW) on two successive olive stone (OS) filters followed by a coagulation–flocculation, was developed in order to perform an efficient pretreatment of OMWW. The results show that the use of OS filter leads to a higher removal of total suspended solids (TSS) and fatty matter (FM) from the raw OMWW (about 82.5% and 73.8%, respectively) and a depletion of total phenolic compounds (TP) and chemical oxygen demand (COD) (11.3% and 23.2%, respectively). The coagulation–flocculation was then applied to improve the removal of TP and COD from the filtered OMWW. For this purpose, a full-factorial design was used to study the effect of different factors involved in coagulation–flocculation. The studied variables were: pH (5–8), coagulant type (ferric chloride; FC and aluminum sulfate; AS), coagulant concentration (250–1000 mg/L) and flocculant (Anionique polyelectrolyte Superfloc A120 PWG) concentration (1–5 mg/L). The results reveal that the use of 250 mg/L FC and 5 mg/L flocculant at an acid pH (around 5) allows for, respectively, a removal of TP and COD of about 10.8% and 31.3%.
12 November 2019 in Journal of Chemical Technology & Biotechnology