Composites can be divided into three groups based on their matrix materials, namely polymer, metal and ceramic. Composite materials fail due to micro cracks. Repairing is complex and almost impossible if cracks appear on the surface and interior, which minimizes reliability and material life. In order to save the material from failure and prolong its lifetime without compromising mechanical properties, self-healing is one of the emerging and best techniques. The studies to address the advantages and challenges of self-healing properties of different matrix materials are very limited; however, this review addresses all three different groups of composites. Self-healing composites are fabricated to heal cracks, prevent any obstructed failure, and improve the lifetime of structures. They can self-diagnose their structure after being affected by external forces and repair damages and cracks to a certain degree. This review aims to provide information on the recent developments and prospects of self-healing composites and their applications in various fields such as aerospace, automobiles etc. Fabrication and characterization techniques as well as intrinsic and extrinsic self-healing techniques are discussed based on the latest achievements, including microcapsule embedment, fibers embedment, and vascular networks self-healing.
In general, aerospace structures manufactured using fiber reinforced polymer composites are exposed to fluctuating temperatures and subjected to cyclic loading during their service life. Therefore, studying the temperature-frequency dependent properties of composites for different fiber orientations is essential. However, such experiments are expensive, time-consuming and labor-intensive while theoretical models minimize these issues, but temperature-frequency-dependent viscoelastic models for predicting the full-range of the storage and loss moduli curves of composites are limited. In this study, the dynamic mechanical properties of a neat epoxy resin, unidirectional ([0°]6, [45°]6 and [90°]6), symmetric angle-ply [+45°/−45°/+45°]s and quasi-isotropic [±45°/0°/90°]s carbon/epoxy and glass/epoxy composite panels were investigated. Experiments were performed from room temperature (approximately 35 °C) to 160 °C at five different frequencies (1, 10, 20, 33 and 50 Hz). Two parameter viscoelastic models as function of temperature and frequency were used, and their applicability in predicting the storage and loss moduli for the entire region of the temperature curve is shown. The storage modulus values were compared and validated against the static flexural modulus values coupled with scanning electron microscopy analysis. The flexural and storage moduli values were found to be higher for [0°]6 carbon/epoxy composites, while the activation energy values were found to be higher in the case of [+45°/−45°/+45°]s carbon/epoxy composites compared with epoxy resin and other laminates in different orientations. The predicted results were in reasonably good agreement with the experiments. Both experimental and modeling approaches used in this study are highly valuable for designing aerospace composites for harsh in-service loading conditions.
In recent times, thermoplastic waste materials are being extensively used as fine and coarse aggregates in the concrete mix as an environmentally friendly construction material. This study aims at utilizing polypropylene (PP) as a partial substitute for the conventional coarse aggregates in M30 grade concrete. The different replacement levels of coarse aggregates such as 0%, 20%, 40%, and 60% by weight were used in concrete. Sieve analysis, specific gravity, and water absorption tests were performed in all replacement levels of aggregates. The mechanical (compressive and split tensile tests) tests were conducted after 3, 14, and 28 days. The change in mechanical properties of concrete with the addition of different weight proportions of plastics was studied experimentally. Further, experimental values were predicted using the two-parameter Weibull distribution and artificial neural network (ANN)-based statistical approaches. The Levenberg–Marquardt algorithm was used in predicting the mechanical properties using the ANN. A good correlation was obtained between the experimental and predicted values with an error (%) of less than 10. The decrease in mechanical properties with the increase in replacement levels of coarse aggregates in concrete was observed in both experimental and predicted approaches. This can be attributed to poor bonding between concrete and PP aggregate owing to the development of agglomerations and the hydrophobic nature of PP. However, the strength values of 20% PP-embedded concrete specimens are closer to 0% PP-embedded concrete specimens. Therefore, 20% PP-embedded concrete specimens can be used for primary load-bearing applications to utilize plastic waste and reduce the cost of the component.
Thermomechanical modeling of epoxy/graphene oxide under quasi-static and dynamic loading requires thermo-mechanical properties such as Young’s modulus, Poisson’s ratio, thermal conductivity, and frequency-temperature dependent viscoelastic properties. In this study, the effects of different graphene oxide (GO) concentrations (0.05, 0.1, and 0.2 wt%) within an epoxy matrix on several mechanical and thermal properties were investigated. The distribution of GO fillers in the epoxy was investigated using transmission electron microscopy (TEM). The digital image correlation (DIC) technique was employed during the tensile testing to determine Young’s modulus and Poisson’s ratio. Analytical models were used to predict Young’s modulus and thermal conductivity, with an error of less than 13% and 9%, respectively. Frequency–temperature dependent phenomenological models were proposed to predict the storage moduli and loss tangent, with a reasonable agreement with experimental data. A relatively high storage modulus, heat-resistance index (THRI), and thermal conductivity were observed in 0.2 wt% nanocomposite samples compared with pure epoxy and other lower concentration GO nanocomposites. A high THRI and derivative of thermogravimetric analysis peak temperatures (Tm1 and Tm2) were exhibited by adding nano-fillers in the epoxy, which confirms higher thermal stability of nanocomposites than that of pristine epoxy.