Unoccupied aircraft systems (UAS) are developing into fundamental tools for tackling the grand challenges in volcanology; here, we review the systems used and their diverse applications. UAS can typically provide image and topographic data at two orders of magnitude better spatial resolution than space-based remote sensing, and close-range observations at temporal resolutions down to those of video frame rates. Responsive deployments facilitate dense time-series measurements, unique opportunities for geophysical surveys, sample collection from hostile environments such as volcanic plumes and crater lakes, and emergency deployment of ground-based sensors (and robots) into hazardous regions. UAS have already been used to support hazard management and decision-makers during eruptive crises. As technologies advance, increasing system capabilities, autonomy and availability, supported by more diverse and lighter-weight sensors, will offer unparalleled potential for hazard monitoring. UAS will provide opportunities for pivotal advances in our understanding of complex physical and chemical volcanic processes.

Volcanic emissions are a critical pathway in Earth’s carbon cycle. Here, we show that aerial measurements of volcanic gases using unoccupied aerial systems (UAS) transform our ability to measure and monitor plumes remotely and to constrain global volatile fluxes from volcanoes. Combining multi-scale measurements from ground-based remote sensing, long-range aerial sampling, and satellites, we present comprehensive gas fluxes—3760 ± [600, 310] tons day⁻¹ CO₂ and 5150 ± [730, 340] tons day⁻¹ SO₂—for a strong yet previously uncharacterized volcanic emitter: Manam, Papua New Guinea. The CO₂/S_T ratio of 1.07 ± 0.06 suggests a modest slab sediment contribution to the sub-arc mantle. We find that aerial strategies reduce uncertainties associated with ground-based remote sensing of SO₂ flux and enable near–real-time measurements of plume chemistry and carbon isotope composition. Our data emphasize the need to account for time averaging of temporal variability in volcanic gas emissions in global flux estimates.

Volcanic gas emissions are intimately linked to the dynamics of magma ascent and outgassing and, on geological time scales, constitute an important source of volatiles to the Earth's atmosphere. Measurements of gas composition and flux are therefore critical to both volcano monitoring and to determining the contribution of volcanoes to global geochemical cycles. However, significant gaps remain in our global inventories of volcanic emissions, (particularly for CO₂, which requires proximal sampling of a concentrated plume) for those volcanoes where the near‐vent region is hazardous or inaccessible. Unmanned Aerial Systems (UAS) provide a robust and effective solution to proximal sampling of dense volcanic plumes in extreme volcanic environments. Here we present gas compositional data acquired using a gas sensor payload aboard a UAS flown at Volcán Villarrica, Chile. We compare UAS‐derived gas time series to simultaneous crater rim multi‐GAS data and UV camera imagery to investigate early plume evolution. SO₂ concentrations measured in the young proximal plume exhibit periodic variations that are well correlated with the concentrations of other species. By combining molar gas ratios (CO₂/SO₂ = 1.48–1.68, H₂O/SO₂ = 67–75, and H₂O/CO₂ = 45–51) with the SO₂ flux (142 ± 17 t/day) from UV camera images, we derive CO₂ and H₂O fluxes of ~150 t/day and ~2,850 t/day, respectively. We observe good agreement between time‐averaged molar gas ratios obtained from simultaneous UAS‐ and ground‐based multi‐GAS acquisitions. However, the UAS measurements made in the young, less diluted plume reveal additional short‐term periodic structure that reflects active degassing through discrete, audible gas exhalations.

A multi-rotor drone has been adapted for studies of volcanic gas plumes. This adaptation includes improved capacity for high-altitude and long-range, real-time SO₂ concentration monitoring, long-range manual control, remotely activated bag sampling and plume speed measurement capability. The drone is capable of acting as a stable platform for various instrument configurations, including multi-component gas analysis system (MultiGAS) instruments for in situ measurements of SO₂, H₂S, and CO₂ concentrations in the gas plume and portable differential optical absorption spectrometer (MobileDOAS) instruments for spectroscopic measurement of total SO₂ emission rate, remotely controlled gas sampling in bags and sampling with gas denuders for posterior analysis on the ground of isotopic composition and halogens. The platform we present was field-tested during three campaigns in Papua New Guinea: in 2016 at Tavurvur, Bagana and Ulawun volcanoes, in 2018 at Tavurvur and Langila volcanoes and in 2019 at Tavurvur and Manam volcanoes, as well as in Mt. Etna in Italy in 2017. This paper describes the drone platform and the multiple payloads, the various measurement strategies and an algorithm to correct for different response times of MultiGAS sensors. Specifically, we emphasize the need for an adaptive flight path, together with live data transmission of a plume tracer (such as SO₂ concentration) to the ground station, to ensure optimal plume interception when operating beyond the visual line of sight. We present results from a comprehensive plume characterization obtained during a field deployment at Manam volcano in May 2019. The Papua New Guinea region, and particularly Manam volcano, has not been extensively studied for volcanic gases due to its remote location, inaccessible summit region and high level of volcanic activity. We demonstrate that the combination of a multi-rotor drone with modular payloads is a versatile solution to obtain the flux and composition of volcanic plumes, even for the case of a highly active volcano with a high-altitude plume such as Manam. Drone-based measurements offer a valuable solution to volcano research and monitoring applications and provide an alternative and complementary method to ground-based and direct sampling of volcanic gases.

This paper describes a series of proof‐of‐concept Beyond Visual Line Of Sight unmanned aerial vehicle flights which reached a range of up to 9 km and an altitude of 4,410 m Above Mean Sea Level over Volcán de Fuego in Guatemala, interacting with the volcanic plume on multiple occasions across a range of different conditions. Volcán de Fuego is an active volcano which emits gas and ash regularly, causing disruption to airlines operating from the international airport 50 km away and impacting the lives of the local population. Collection of data from within the plume develops scientists’ understanding of the composition of the volcano's output and is of use to scientists, aviation, and hazard management groups alike. This paper presents preliminary results of multiple plume interceptions with multiple aircraft, carrying a variety of sensors. A plume‐detection metric is introduced, which uses a combination of flight data and atmospheric sensor data to identify flight through a volcanic plume. Future work will develop the automation of plume tracking such that reliable scientific data sets can be gathered in a robust manner.

Volcanoes with multiple summit vents present a methodological challenge for determining vent-specific gas emissions. Here, using a novel approach combining multiple ultraviolet cameras with synchronous aerial measurements, we calculate vent-specific gas compositions and fluxes for Stromboli volcano. Emissions from vent areas are spatially heterogeneous in composition and emission rate, with the central vent area dominating passive emissions, despite exhibiting the least explosive behaviour. Vents exhibiting Strombolian explosions emit low to negligible passive fluxes and are CO₂-dominated, even during passive degassing. We propose a model for the conduit system based on contrasting rheological properties between vent areas. Our methodology has advantages for resolving contrasting outgassing dynamics given that measured bulk plume compositions are often intermediate between those of the distinct vent areas. We therefore emphasise the need for a vent-specific approach at multi-vent volcanoes and suggest that our approach could provide a transformative advance in volcano monitoring applications.