The continuous decline of traditional fossil energy has cast the shadow of an energy crisis on human society. Hydrogen generated from renewable energy sources is considered as a promising energy carrier, which can effectively promote the energy transformation of traditional high-carbon fossil energy to low-carbon clean energy. Hydrogen storage technology plays a key role in realizing the application of hydrogen energy and liquid organic hydrogen carrier technology, with many advantages such as storing hydrogen efficiently and reversibly. High-performance and low-cost catalysts are the key to the large-scale application of liquid organic hydrogen carrier technology. In the past few decades, the catalyst field of organic liquid hydrogen carriers has continued to develop and has achieved some breakthroughs. In this review, we summarized recent significant progress in this field and discussed the optimization strategies of catalyst performance, including the properties of support and active metals, metal–support interaction and the combination and proportion of multi-metals. Moreover, the catalytic mechanism and future development direction were also discussed.

Aluminum hydride (AlH₃) has attracted wide attention due to its high gravimetric and volumetric hydrogen capacity. AlH₃ can easily release hydrogen when heated at relatively low temperature. Such high hydrogen density and low dehydrogenation temperature make it one of the most promising high-energy fuels for solid propellants. In particular, AlH₃ as a component of solid propellants may greatly increase the specific impulse of rocket engines. However, AlH₃ exhibits low chemical and thermal stability in an ambient atmosphere. In this paper, the research progress about the synthesis, dehydrogenation thermodynamics, and kinetics, the stabilization of AlH₃ over the past decades are reviewed, with the aim of exploring more a economical synthesis and suitable stabilization methods for large-scale use in solid propellants. Finally, some suggestions regarding future research directions in this filed are proposed.

Metal hydrides are regarded as promising hydrogen-supplying fuel for energetic materials while CL-20 (Hexanitrohexaazaisowurtzitane) and FOX-7 (1,1-Diamino-2,2-dinitroethylene) are typical principal components commonly used in energetic materials. Hence, it is interesting to explore the interactions between them for development of new energetic systems. In this paper, the adsorption and decomposition of CL-20 or FOX-7 molecules on the MgH₂ (110) crystal surface were investigated by employing the First-Principles. In total, 18 adsorption configurations for CL-20/MgH₂ (110) and 12 adsorption configurations for FOX-7/MgH₂ (110) were considered. The geometric parameters for the configurations, adsorption energies, charge transfer, density of states, and decomposition mechanism were obtained and analyzed. In most of the configurations, chemical adsorption will occur. Moreover, the orientation of the nitro-group in CL-20 or FOX-7 with regard to the MgH₂ (110) surface plays an important role on whether and how the energetic molecule decomposes. The adsorption and decomposition of CL-20 or FOX-7 on MgH₂ could be attributed to the strong charge transfer between Mg atoms in the first layer of MgH₂ (110) surface and oxygen as well as nitrogen atoms in the nitro-group of CL-20 or FOX-7 molecules.

Accurate and efficient simulation on the fluid flow and deformation in porous media is of increasing importance in a diverse range of engineering fields. At present, there are only several methods can be used to simulate the deformation of fractured porous media. It is very important to know their application scopes, advantages, and disadvantages for solving the practical problems correctly. Therefore, in this paper, we compared two numerical simulation methods for flow-induced fracture deformation in porous media. One is the Extended Finite Element Method (XFEM), which is based on the classical finite element method and can simulate strong or weak discontinuous problems. The other is developed within the finite-volume framework, termed Extended Finite Volume Method (XFVM). We designed three test cases, including single fracture, cross fractures and eight discrete fractures, to investigate the accuracy and efficiency of XFEM and XFVM. The reference solutions were provided by the commercial software, COMSOL, where the standard finite element method is implemented. The research findings showed that the accuracy of the XFEM was slightly higher than that of the XFVM, but the latter was more efficient. These results are likely to be useful in decision making regarding choice of solving methods for the multi-field coupling problem in fractured porous media.