Lithium-ion batteries (LIBs) are gaining importance in the automotive sector because of the potential of electric vehicles (EVs) to reduce greenhouse gas emissions and air pollution. However, there are serious hazards resulting from failing battery cells leading to exothermic chemical reactions inside the cell, called thermal runaway (TR). Literature of quantifying the failing behavior of modern automotive high capacity cells is rare and focusing on single hazard categories such as heat generation. Thus, the aim of this study is to quantify several hazard relevant parameters of a failing currently used battery cell extracted from a modern mass-produced EV: the temperature response of the cell, the maximum reached cell surface temperature, the amount of produced vent gas, the gas venting rate, the composition of the produced gases including electrolyte vapor and the size and composition of the produced particles at TR. For this purpose, overtemperature experiments with fresh 41 Ah automotive lithium NMC/LMO—graphite pouch cells at different state-of-charge (SOC) 100%, 30% and 0% are performed. The results are valuable for firefighters, battery pack designers, cell recyclers, cell transportation and all who deal with batteries.

Nowadays "microplastics" (MPs) is an already well-known term and results of micro-sized particles found in consumer products or environments are regularly reported. However, studies of native MPs smaller than 1 μm, often referred to as nanoplastics (NPs), in analytically challenging environments are rare. In this study, a correlative approach between scanning electron microscopy and Raman microscopy is tested to meet the challenges of finding and identifying NPs in the 100 nm range in various environments, ranging from ideal (distilled water) to challenging (sea salt, human amniotic fluid). To test the viability of this approach in principle, standardized polystyrene beads (Ø 200 nm) are mixed into the various environments in different concentrations. Promising detection limits of 2 10-3 μg/L (distilled water), 20 μg/L (sea salt) and 200 μg/L (human amniotic fluid) are found. To test the approach in practices both sea salt and amniotic fluid are analysed for native NPs as well. Interestingly a nylon-NP was found in the amniotic fluid, maybe originating from the sampling device. However, the practical test reveals limitations, especially with regard to the reliable identification of unknown NPs by Raman microscopy, due to strong background signals from the environments. We conclude from this in combination with the excellent performance in distilled water that a combination of this approach with an advanced sample preparation technique would yield a powerful tool for the analysis of NPs in various environments.

Significance: Lithium–air batteries are promising next-generation energy storage devices and operate by electrodepositing insulating lithium peroxide (Li ₂ O ₂ ). Understanding how large amounts of Li ₂ O ₂ form, corresponding to large capacities, and what limits the amount is therefore paramount and requires following its structural evolution from atomic to micron scales. We demonstrate that in situ small- and wide-angle X-ray scattering together with sophisticated data evaluation provides access to these scales. This allows distinguishing the two reported competing reaction mechanisms, which are thought to be responsible for large and small capacities, respectively. We find that, surprisingly, only one pathway predominates at all conditions. On a wider perspective, we introduce a powerful tool to characterize transformations in complex multiphase materials.

Efficient capture of barium (Ba) from solution is a serious task in environmental protection and remediation. Herein, the capacity and the mechanism of Ba adsorption by natural and iron(III) oxide (FeO) modified allophane (ALO), beidellite (BEI) and zeolite (ZEO) were investigated by considering the effects of contact time, temperature, pH, Ba²⁺ concentration, adsorbent dosage, the presence of competitive ions and adsorption–desorption cycles (regenerability). Physicochemical and mineralogical properties of the adsorbents were characterized by XRD, FTIR, SEM with EDX and N₂ physisorption techniques. The Ba²⁺ adsorption fitted to a pseudo-first-order reaction kinetics, where equilibrium conditions were reached within K⁺ > Ca²⁺ >> Mg²⁺ for all adsorbents; however, BEI and FeO-BEI showed the highest selectivity for Ba²⁺ among all materials tested. Barium removal from solution was governed by physical adsorption besides ion exchange, intercalation, surface complexation and precipitation, depending mainly on the absorbent type and operational conditions. BEI and FeO-BEI showed a high regenerability (>70–80% desorption efficiency after 5 cycles) and could be considered as efficient sorbent materials for wastewater clean-up.

Biobased and biodegradable polymers (BBDs) such as poly(3-hydroxy-butyrate), PHB, and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) are considered attractive alternatives to fossil-based plastic materials since they are more environmentally friendly. One major problem with these compounds is their high crystallinity and brittleness. In order to generate softer materials without using fossil-based plasticizers, the suitability of natural rubber (NR) as an impact modifier was investigated in PHBV blends. Mixtures with varying proportions of NR and PHBV were generated, and samples were prepared by mechanical mixing (roll mixer and/or internal mixer) and cured by radical C–C crosslinking. The obtained specimens were investigated with respect to their chemical and physical characteristics, applying a variety of different methods such as size exclusion chromatography, Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), thermal analysis, XRD, and mechanical testing. Our results clearly indicate that NR–PHBV blends exhibit excellent material characteristics including high elasticity and durability. Additionally, biodegradability was tested by applying heterologously produced and purified depolymerases. pH shift assays and morphology analyses of the surface of depolymerase-treated NR–PHBV through electron scanning microscopy confirmed the enzymatic degradation of PHBV. Altogether, we prove that NR is highly suitable to substitute fossil-based plasticizers; NR–PHBV blends are biodegradable and, hence, should be considered as interesting materials for a great number of applications.

Fine-grained sedimentary deposits can bear an increased risk for building settlements due to their moderate stiffness and strength properties, as well as high groundwater tables. However, some buildings, e.g., situated on shallow foundations in Alpine basins, show only relatively small settlements because the formation of carbonate cement can create bridging bonds between the detrital soil particles, leading to increased stiffness. These weak bonds can be damaged through dynamic loads and high static loads, causing a weakening of the soil’s microstructure and resulting in large settlements in several cases. However, the environmental controls and mechanistic processes underlying the formation versus damaging of microstructure in fine-grained, postglacial sediments are, to date, poorly understood. In the present study, fine-grained sediments are artificially cemented by calcium carbonates (CaCO₃) to investigate (i) the influence of a mild and sustainable cementation process on the stress–strain behavior of silicate- and carbonate-rich soils and (ii) the possibilities and limitations of artificial microstructure development for soil stabilization. Incremental load oedometer testing (IL), bender element testing (BE), X-ray diffraction (XRD), scanning electron microscopy (SEM) and Brunauer–Emmett–Teller (BET) specific surface area (SSA) measurements are used to characterize the development of cementation and to elucidate the improvements in the soil mechanical properties. It is shown that cementation induced by CaCO₃ mineralization (by 5–15% replacement) leads to an increased stiffness (factor ≈ 5–7) and shear wave velocity (factor ≈ 1.1), caused by the formation of nanocrystalline, particle-binding CaCO₃ cements. The improvement of soil stiffness is dependent on the CaCO₃ replacement level, reaction time and primary soil mineralogical composition.