This article proposes a multiobjective hybrid energy management system that minimizes both the electricity expenses and the household greenhouse gas emissions released due to consumption, considering the entire life cycle of the generation assets used to provide energy. The global warming potential indicator is used to decide if it is more sustainable to purchase electricity from the grid or use the household's flexible generation sources like photovoltaic panels and the energy storage system. Results prove that it is possible to reduce greenhouse gas emissions without incurring expensive electricity bill costs thanks to the hybrid-based home energy management system approach. This method gives the end-users a more influential role in the climate change solution, allowing them to give more or less importance to the economic or environmental component, according to their preferences.

A comprehensive electric vehicle model is developed to characterize the behavior of the Smart e.d. (2013) while driving, charging and providing vehicle-to-grid services. To facilitate vehicle-to-grid strategy development, the EV model is completed with the measurement of the on-board charger efficiency and the charging control behavior upon external set-point request via IEC 61851-1. The battery model is an electro-thermal model with a dual polarization equivalent circuit electrical model coupled with a lumped thermal model with active liquid cooling. The aging trend of the EV’s 50 Ah large format pouch cell with NMC chemistry is evaluated via accelerated aging tests in the laboratory. Performance of the model is validated using laboratory pack tests, charging and driving field data. The RMSE of the cell voltage was between $18.49$ $\mathrm{m}$$\mathrm{V}$ and $67.17$ $\mathrm{m}$$\mathrm{V}$ per cell for the validation profiles. Cells stored at 100% SOC and 40 °C reached end-of-life (80% of initial capacity) after 431–589 days. The end-of-life for a cell cycled with 80% DOD around an SOC of 50% is reached after 3634 equivalent full cycles which equates to a driving distance of over 420,000 $\mathrm{k}$$\mathrm{m}$. The full parameter set of the model is provided to serve as a resource for vehicle-to-grid strategy development.

The emergence of electric vehicles offers the opportunity to decarbonize the transportation and mobility sector. With smart charging strategies and the use of electricity generated from renewable sources, electric vehicle owners can reduce their electricity bill as well as reduce their carbon footprint. We investigated smart charging strategies for electric vehicle charging at household and workplace sites with photovoltaic systems. Furthermore, we investigated the participation of an electric vehicle in the provision of positive automatic frequency restoration reserve (aFRR) in Germany from 30 October 2018 to 31 July 2019. We find that the provision of positive aFRR in Germany returns a positive net return. The positive net return is, however, not sufficient to cover the current investment cost for a necessary control unit. For home charging, we find that self-sufficiency rates of up to 48.1% and an electricity cost reduction of 17.6% for one year can be reached with unidirectional smart charging strategies. With bidirectional strategies, self-sufficiency rates of up to 56.7% for home charging and electricity cost reductions of up to 26.1% are reached. We also find that electric vehicle (EV) owners who can charge at their workplace can reduce their electricity cost further. The impact of smart charging strategies on battery aging is also discussed.