In the last four decades, Campi Flegrei caldera has been the world’s most active caldera characterized by intense unrest episodes involving huge ground deformation and seismicity, but, at the time of writing, has not culminated in an eruption. We present a careful review, with new analyses and interpretation, of all the data and recent research results. We deal with three main problems: the tentative reconstruction of the substructure; the modelling of unrest episodes to shed light on possible pre-eruptive scenarios; and the probabilistic estimation of the hazards from explosive pyroclastic products. The results show, for the first time at a volcano, that a very peculiar mechanism is generating episodes of unrest, involving mainly activation of the geothermal system from deeper magma reservoirs. The character and evolution of unrest episodes is strongly controlled by structural features, like the ring-fault system at the borders of the caldera collapse. The use of detailed volcanological, mathematical and statistical procedures also make it possible to obtain a detailed picture of eruptive hazards in the whole Neapolitan area. The complex behaviour of this caldera, involving interaction between magmatic and geothermal phenomena, sheds light on the dynamics of the most dangerous types of volcanoes in the world.

The Campi Flegrei caldera is considered the most dangerous volcano in Europe and is currently in a new phase of unrest (started in 2000 and still ongoing) that has persisted intermittently for several decades (main crisis occurred from 1950 to 1952, 1970–1972, and 1982–1984). Here, by combining the petrological and geochemical data collected in recent decades with numerical simulations, we place new constraints on the source(s) of the current dynamics of the volcano. In particular, we show that the measured (N₂‐He‐CO₂) geochemical changes at the fumaroles of Solfatara hydrothermal site are the result of massive (about 3 km³) magma degassing in the deep portion (≥200 MPa, 8 km of depth) of the plumbing system. This degassing mechanism would be able to flood the overlying hydrothermal system with hot gas, thus heating and fracturing the upper crust inducing shallow seismicity and deformation. This implies that the deep magma transfer process (≥8 km) has been decoupled from the source of deformation and seismicity, localized in the first kilometers (0–4 km) of caldera‐filling rocks. This information on magma transfer depth can have important implications for defining the best monitoring strategies and for forecasting a future eruption. Finally, this study highlights how petrological and geochemical data allow us to explore the dynamics of the deep portion of the plumbing system and thus trace the occurrence of recharge episodes, in a portion of the ductile lower crust where magma transfer occurs in the absence of earthquakes.

The eruptions of Campi Flegrei (Southern Italy), one of the most studied and dangerous active volcanic areas of the world, are fed by mildly potassic alkaline magmas, from shoshonite to trachyte and phonotrachyte. Petrological investigations carried out in past decades on Campi Flegrei rocks provide crucial information for understanding differentiation processes in its magmatic system. However, the compositional features of rocks are a palimpsest of many processes acting over timescales of 10⁰–10⁴ years, including crystal entrapment from multiple reservoirs with different magmatic histories. In this work, olivine, clinopyroxene and feldspar crystals from volcanic rocks related to the entire period of Campi Flegrei’s volcanic activity are checked for equilibrium with combined and possibly more rigorous tests than those commonly used in previous works (e.g., Fe–Mg exchange between either olivine or clinopyroxene and melt), with the aim of obtaining more robust geothermobarometric estimations for the magmas these products represent. We applied several combinations of equilibrium tests and geothermometric and geobarometric methods to a suite of rocks and related minerals spanning the period from ~59 ka to 1538 A.D. and compared the obtained results with the inferred magma storage conditions estimated in previous works through different methods. This mineral-chemistry investigation suggests that two prevalent sets of T–P (temperature–pressure) conditions, here referred to as “magmatic environments”, characterized the magma storage over the entire period of Campi Flegrei activity investigated here. These magmatic environments are ascribable to either mafic or differentiated magmas, stationing in deep and shallow reservoirs, respectively, which interacted frequently, mostly during the last 12 ka of activity. In fact, open-system magmatic processes (mixing/mingling, crustal contamination, CO₂ flushing) hypothesized to have occurred before several Campi Flegrei eruptions could have removed earlier-grown crystals from their equilibrium melts. Moreover, our new results indicate that, in the case of complex systems such as Campi Flegrei’s, in which different pre-eruptive processes can modify the equilibrium composition of the crystals, one single geothermobarometric method offers little chance to constrain the magma storage conditions. Conversely, combined methods yield more robust results in agreement with estimates obtained in previous independent studies based on both petrological and geophysical methods.