Oily wastewater from shipping waste and marine accidents have seriously polluted the marine environment and brought great harm to human production and health. With the increasing awareness of environmental protection, the treatment of marine oily wastewater has attracted extensive attention from the international community. Marine oily wastewater has various forms and complex components, so its treatment technology faces great challenges. Sources, types, supervision, and treatment of marine oily wastewater are introduced in this paper. The research progress of marine and ship’s oily wastewater treatment technologies in recent years are reviewed from the perspectives of physical treatment, chemical treatment, biological treatment, and combined treatment, respectively. Principles and characteristics of all kinds of technologies were analyzed. In addition, this paper shows that multiple processing technologies used in combination for the purpose of high efficiency, environmental protection, economy, and energy conservation are the future development trend.

In this study, a catalytic persulfate oxidation process comprising sodium persulfate (PS) and modified sewage sludge-derived carbonaceous catalysts was tested for the degradation of phenol. Sludge-based biochar was modified by high-temperature treatment combined with hydrochloric acid oxidation. The surface properties of carbonaceous catalysts before and after modification were characterized by elemental analysis, N₂ isothermal adsorption-desorption, scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) spectroscopy. The effects of reaction parameters including catalyst dosage, PS/phenol molar ratio, initial pH and reaction temperature on the degradation rate of phenol were investigated. The kinetics of phenol transformation was explored and the reaction rate appeared pseudo first-order kinetics. In SS-600-HCl/PS system, 91% phenol could be efficiently degraded under certain reaction conditions ([phenol]₀ = 100 mg/L, catalyst dosage = 0.8 g/L, PS/phenol molar ratio = 3/1, pH = 7, 25 °C) in 180 min. Thus, the results showed that the modified sewage sludge-derived carbonaceous catalyst had a better ability to activate PS for phenol degradation.