Aerogels are exceptionally lightweight materials characterized by their high open porosity and remarkable specific surface area, currently used across a wide array of industrial sectors from construction to energy storage and have great potential for expanding their applicability and unlocking new market opportunities. Driven by global economic growth and an intensifying environmental crisis, there is a growing demand for engineering innovations that prioritize sustainability. Aerogels are well-positioned to support these sustainability efforts. Their unique properties make them ideal for energy-saving solutions, environmental remediation, and more efficient use of resources. As the demand for eco-conscious technologies rises, aerogels are poised to contribute significantly to the development of greener, more efficient products and processes across multiple industries. The sustainability of aerogel technology is crucial for the mid-to-long-term future, yet its current status has been scarcely reviewed in the literature. This Perspective explores and critically reviews significant advances on organic and hybrid aerogels in the current socioeconomic scenario, with selected case studies endorsing their contribution to the UN Sustainable Development Goals. It also identifies research gaps while proposing innovative strategies to enhance the sustainability of aerogel production through the application of circular economy principles. Key strategies discussed involve the fabrication of aerogels using eco-friendly sources, such as biopolymers derived from biorefinery processes or from waste materials. Additionally, this Perspective examines the development of methods for the reuse, recycling, and end-of-life management of aerogels, along with the implementation of more efficient processing routes. Ultimately, this work highlights the need for comprehensive assessments of aerogel sustainability through life cycle assessment (LCA) and evaluations of safety and toxicity. By addressing these critical aspects, the potential of aerogels to contribute to a more sustainable future appears highly favorable from both commercial and research perspectives, paving the way for a circular aerogel economy and providing a lasting impact to the society in which we live.
The spatial complexity of floodplains is a function of several processes: hydrodynamics, flow direction, sediment transportation, and land use. Sediments can bind toxic elements, and as there are several pollution sources, the risk of heavy metal accumulation on the floodplains is high. We aimed to determine whether fluvial forms have a role in metal accumulations. Topsoil samples were taken from point bars and swales in the floodplain of the Tisza River, North-East Hungary. Soil properties and metal concentrations were determined, and correlation and hypothesis testing were applied. The results showed that fluvial forms are important drivers of horizontal metal patterns: there were significant differences (p < 0.05) between point bars and swales regarding Fe, K, Mg, Mn, Cr, Cu, Ni, Pb, and Zn. Vertical distribution also differed significantly by fluvial forms: swales had higher metal concentrations in all layers. General Linear Models had different results for macro and micro elements: macro element concentrations were determined by the organic matter, while for micro elements the clay content and the forms were significant explanatory variables. These findings are important for land managers and farmers because heavy metal concentration has a direct impact on living organisms, and the risk of bioaccumulation can be high on floodplains.
Silica-gelatin hybrid aerogel of 24 wt% gelatin content is an advanced functional material suitable for the high performance selective adsorption of aqueous Hg(II). The remediation efficacy of this adsorbent was tested under realistic aquatic conditions by exposing cultures of Paramecium caudatum to Hg(II) and monitoring the model cultures by time-lapse video microscopy. The viability of Paramecium was quantified by analyzing the pixel differences of the sequential images caused by the persistent movement (motility) of the cells. The viability of Paramecium displays a clear exposure-response relationship with Hg(II) concentration. Viability decreases with increasing Hg(II) concentration when the latter is higher than 125 μg L-1. In the presence of 0.1 mg mL-1 aerogel adsorbent, the viability of the cells decreases only at Hg(II) concentrations higher than 500 μg L-1, and 220 min survival time was measured even at 1000 μg L-1 Hg(II). The effective toxicity of Hg(II) is lower in the presence of the aerogel, because the equilibrium concentration of aqueous Hg(II) is low due to adsorption, thus Paramecium cells do not uptake as much Hg(II) as in the un-remediated cultures. Video imaging of Paramecium cultures offers a simple, robust and flexible method for providing quantitative information on the effectiveness of advanced materials used in adsorption processes for water treatment.
Porous gold nanoparticles (PGNs) are usually prepared in an immobilized form on a solid substrate, which is not practical in many applications. In this work, a simple method is reported for the preparation and stabilization of mesoporous gold particles of a few hundred nanometers in size in aqueous suspension. Nanoparticles of Ag-Au alloy were fabricated on CaF and Si/SiO substrates by the solid-state dewetting method. Silver was selectively dissolved (dealloyed), and the resulting porous gold nanoparticles were chemically removed from the substrate either in a concerted step with dealloying, or in a subsequent step. Nitric acid was used for the one-step dealloying and detachment of the particles from CaF substrate. The consecutive use of HNO and HF resulted in the dealloying and the subsequent detachment of the particles from Si/SiO substrate. The PGNs were recovered from the aqueous suspensions by centrifugation. The Au content of the suspensions was monitored by using elemental analysis (ICP-OES), and recovery was optimized. The morphology and the optical characteristics of the support-free PGNs were analyzed by scanning electron microscopy (SEM), dynamic light scattering spectroscopy (DLS), and near-infrared spectrophotometry (NIR). The obtained PGNs are spherical disk-shaped with a mean particle size of 765 ± 149 nm. The suspended, support-free PGNs display an ideally narrow dipole plasmon peak at around 1450 nm in the NIR spectral region. Thus, the new colloidal PGNs are ideal candidates for biomedical applications, for instance photothermal therapy.