The major organic compositions from biomass burning emissions are monosaccharide derivatives from the breakdown of cellulose, generally accompanied by small amounts of straight-chain, aliphatic, oxygenated compounds, and terpenoids from vegetation waxes, resins/gums, and other biopolymers. Levoglucosan from cellulose can be utilized as a specific or general indicator for biomass combustion emissions in aerosol samples. There are other important compounds, such as dehydroabietic acid, syringaldehyde, syringic acid, vanillic acid, vanillin, homovanillic acid, 4-hydroxybenzoic acid, and p-coumaric acid, which are additional key indicators of biomass burning. In this review, we will address these tracers from different types of biomass burning and the methods used to identify the sources in ambient aerosols. First, the methods of inferring biomass burning types by the ratio method are summarized, including levoglucosan/mannose, syringic acid/vanillic acid, levolgucosan/K⁺, vanillic acid/4-hydroxybenzoic acid, levoglucosan/OC, and levoglucosan/EC to infer the sources of biomass burning, such as crop residual burning, wheat burning, leaf burning, peatland fire, and forest fire in Asia. Second, we present the source tracer ratio methods that determine the biomass combustion types and their contributions. Finally, we introduce the PCA (Principal component analysis) and PMF (Positive matrix factor) methods to identify the type of biomass burning and its contributions according to emission factors of different species in various plants such as softwood, hardwood, and grass.

In order to study the toxicity of fine particulate matter (PM_2.5) sourced from different seasons on human health, we collected PM_2.5 samples quarterly from March 2016 to February 2017 in Nanjing, China. The component analysis results showed that high proportions of water-soluble organic carbon (WSOC), SO₄²⁻, Ca²⁺ and Mg²⁺ were found in the summer samples, while high proportions of NO₃⁻, NH₄⁺ and heavy metals were observed in the spring and winter samples. Then human lung epithelial cells (A549) were exposed to the PM_2.5 samples. The toxicological results indicated that reactive oxygen species (ROS) production in the spring and winter samples was higher than that in the summer and fall samples, which was related to the contribution of some heavy metals and inorganic ions (e.g., Pb and NO₃⁻). However, the apoptosis rates of the cells showed the opposite seasonal changes as what the ROS did, which might be caused by the higher WSOC content in the summer. In addition, regression analysis also showed the importance of the PM_2.5 components in ROS production and apoptosis. Particularly, Zn had the strongest correlation with ROS production (R = 0.863) and cell apoptosis (R = 0.675); thus, the specific toxicity of Zn in PM_2.5 deserves further investigation. Our results could be beneficial for assessing the health risks and controlling the toxic components of PM_2.5 in Nanjing.

In recent years, the industrial emission of air pollution has been reduced via a series of measures. However, with the rapid development of modern agriculture, air pollution caused by agricultural activities is becoming more and more serious. Agricultural activities can generate a large amount of air pollutants, such as ammonia, methane, nitrogen oxides, volatile organic compounds, and persistent organic pollutants, the sources of which mainly include farmland fertilization, livestock breeding, pesticide use, agricultural residue burning, agricultural machinery, and agricultural irrigation. Greenhouse gases emitted by agricultural activities can affect regional climate change, while atmospheric particulates and persistent organic pollutants can even seriously harm the health of surrounding residents. With the increasing threat of agricultural air pollution, more and more relevant studies have been carried out, as well as some recommendations for reducing emissions. The emissions of ammonia and greenhouse gases can be significantly reduced by adopting reasonable fertilization methods, scientific soil management, and advanced manure treatment systems. Regarding pesticide use and agricultural residues burning, emission reduction are more dependent on the restriction and support of government regulations, such as banning certain pesticides, prohibiting open burning of straw, and supporting the recycling and reuse of residues. This review, summarizing the relevant research in the past decade, discusses the current situation, health effects, and emission reduction measures of agricultural air pollutants from different sources, in order to provide some help for follow-up research.

Ambient fine particles (PM_2.5) have been shown to have adverse health effects by inducing oxidative stress. Here, dithiothreitol (DTT)-based oxidative potential (OP) was used to assess the capacity of oxidative stress caused by PM_2.5. In this study, PM_2.5 samples were collected in the Nanjing area in 2016, and physicochemical properties and DTT activity were investigated. The annual mean PM_2.5 mass concentration was 73 μg m⁻³ and greatly varied among seasons (spring > winter > summer > autumn). Three fluorescent substances were identified by the excitation-emission matrix (EEM) spectrum. The annual mean mass-normalized DTT activity (DTT_m; 0.02 nmol min⁻¹ μg⁻¹) was similar to that documented for cities of some developed countries. The annual mean volume-normalized DTT activity (DTT_v) showed a relatively high value of 1.16 nmol min⁻¹ m⁻³, and the seasonal mean DTT_v was highest in winter, followed by spring, autumn, and summer, whose pattern is different from PM_2.5 mass concentration. Correlation and multiple linear regression analysis suggested that transition metals may have a greater effect on OP in autumn and winter, humic-like substances and UV absorbing aromatic substances may have a strong effect on OP in spring and summer. Generally, this study enhances our understanding of seasonal variation in health effects associated with PM_2.5.

Water-soluble organic nitrogen (WSON) is an important component of PM_2.5 which may affect air quality, climate and human health. Herein, one-year field samples of atmospheric PM_2.5 (June 2017–May 2018) were collected in northern Nanjing. Chemical characterization of PM_2.5 major components as well as WSON were conducted, and WSON composition and sources were further investigated via measurements by a Aerodyne soot particle aerosol mass spectrometer (SP-AMS) as well as positive matrix factorization (PMF). Inorganic ions, mainly consisting of ammonium, sulfate, and nitrate, were found to dominate PM_2.5 mass (58.7%), followed by organic matter (OM) (22.6%), and elemental carbon (EC) (2.1%). Water-soluble OM dominated OM (65.1%), and its temporal variation was closely correlated with that of secondary organic matter, while time series of water-insoluble OM concentrations correlated tightly with that of primary organic matter. Average WSON concentration was 2.15 μg/m³, which was highest in winter and lowest in summer. Correlation analysis of WSON with PM_2.5 components also indicated that WSON was mainly from secondary sources. SP-AMS revealed that WSON mass spectrum was composed of C_xH_yN_p⁺ (91.2%) and C_xH_yO_zN_p⁺ (8.8%), indicating dominance of amines and other oxygenated ON compounds. PMF analysis resolved two primary sources (traffic, biomass burning) and two secondary sources (less-oxidized and more-oxidized factors) of WSOM and WSON, and the secondary source dominated both WSOM and WSON. Contribution of the more-oxidized ON factor was very high in winter, and the less-oxidized factor was significant in summer, indicating a likely important role of aqueous-phase processing in winter as well as photochemical oxidation in summer to WSON.