This article presents the capabilities and selected measurement results from the newly developed low-cost air pollution measurement system mounted on an unmanned aerial vehicle (UAV). The system is designed and manufactured by the authors and is intended to facilitate, accelerate, and ensure the safety of operators when measuring air pollutants. It allows the creation of three-dimensional models and measurement visualizations, thanks to which it is possible to observe the location of leakage of substances and the direction of air pollution spread by various types of substances. Based on these models, it is possible to create area audits and strategies for the elimination of pollution sources. Thanks to the usage of a multi-socket microprocessor system, the combination of nine different air quality sensors can be installed in a very small device. The possibility of simultaneously measuring several different substances has been achieved at a very low cost for building the sensor unit: 70 EUR. The very small size of this device makes it easy and safe to mount it on a small drone (UAV). Because of this device, many harmful chemical compounds such as ammonia, hexane, benzene, carbon monoxide, and carbon dioxide, as well as flammable substances such as hydrogen and methane, can be detected. Additionally, a very important function is the ability to perform measurements of PM2.5 and PM10 suspended particulates. Thanks to the use of UAV, the measurement is carried out remotely by the operator, which allows us to avoid the direct exposure of humans to harmful factors. A big advantage is the quick measurement of large spaces, at different heights above the ground, in different weather conditions. Because of the three-dimensional positioning from GPS receiver, users can plot points and use colors reflecting a concentration of measured features to better visualize the air pollution. A human-friendly data output can be used to determine the mostly hazardous regions of the sampled area.
Due to the growing concerns about pharmaceutical contamination and its devastating impact on the economy and the health of humans and the environment, developing efficient approaches for removing such contaminants has become essential. Adsorption is a cost-effective technique for removing pollutants. Thus, in this work, banana peels as agro-industrial waste were utilized for synthesizing activated carbon for removing pharmaceuticals, namely amoxicillin and carbamazepine from different water matrices. The chemically activated carbon by phosphoric acid (H3PO4) was carbonized at temperatures 350 °C, 450 °C and 550 °C. The material was characterized by several techniques such as scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy (FTIR), Boehm titration, point of zero charge (pHPZC), BET surface area (SBET), the proximate and ultimate analyses, X-ray powder diffraction (XRD), and thermos-gravimetric analysis (TGA). The SEM of banana peel activated carbon (BPAC) depicted a semi-regular and heterogeneous morphology, characterized by an abundance of pores with diverse forms and sizes. Boehm titration revealed an increase in the amounts of acidic groups by 0.711 mmol/g due to activation by H3PO4. FTIR recorded different peaks suggesting significant modifications in the spectroscopic characteristics of the BPAC surface due to the successful activation and adsorption of the pollutant molecules. The pHpzc of BPAC was calculated to be 5.005. The SBET surface area dramatically increased to 911.59 m2/g after the activation. The optimum conditions were 25 °C, a materials dosage of 1.2 g/L, a saturation time of 120 min, a pollutants mixture of 25 mg/L, and a pH of 5. Langmuir exhibits a slightly better fit than Freundlich with a low value of the residual sum of squares (SSE) and the data were better fitted to the pseudo-second-order kinetic. Furthermore, the efficacy of BPAC in eliminating pharmaceuticals from Milli Q water, lake water, and wastewater was successfully investigated over the seven cycles. The results of the present work highlighted a potential usage of agro-industrial waste in eliminating organic micropollutants while exhibiting sustainable management of this waste.
1 February 2017 in Renewable and Sustainable Energy Reviews
Despite efforts to utilise bauxite residue, the amount of red mud stored in reservoirs is increasing. This paper aims to evaluate the potential of red mud and other sludge waste types as a soil substitute by monitoring plant development. Pot experiments were carried out testing two types of mixtures: dredging sludge from Lake Balaton mixed with garden soil and the sewage sludge and soil blend. These were then treated with red mud (15 and 30% w/w). The plants were under-, while the roots were more developed in the sewage sludge mix than the dredging sludge blend and the control soil. In the sewage amendment, the phosphorous content increased while the calcium content was lower than in the other soil types and the optimum. The metals uptake of the plants was a factor of the red mud quantity. Lead, nickel, titanium and silicon had elevated concentrations parallel to higher red mud content, but only the nickel exceeded the threshold of the Hungarian legislation. Silicon and titanium were beneficial for plant growth, compensating for the potentially toxic effects of lead and nickel. Results suggest that the red mud in a mixture with either sewage sludge or dredging sludge can act as catalysts for the growth rate of test plants, allowing their utilisation as secondary raw materials.