Streamflow data are of prime importance to water-resources planning and management, and the accuracy of their estimation is very important for decision making. The Soil and Water Assessment Tool (SWAT) and Artificial Neural Network (ANN) models have been evaluated and compared to find a method to improve streamflow estimation. For a more complete evaluation, the accuracy and ability of these streamflow estimation models was also established separately based on their performance during different periods of flows using regional flow duration curves (FDCs). Specifically, the FDCs were divided into five sectors: very low, low, medium, high and very high flow. This segmentation of flow allows analysis of the model performance for every important discharge event precisely. In this study, the models were applied in two catchments in Peninsular Spain with contrasting climatic conditions: Atlantic and Mediterranean climates. The results indicate that SWAT and ANNs were generally good tools in daily streamflow modelling. However, SWAT was found to be more successful in relation to better simulation of lower flows, while ANNs were superior at estimating higher flows in all cases.

Water availability is essential for the appropriate analysis of its sustainable management. We performed a comparative study of six hydrological balance models (Témez, ABCD, GR2M, AWBM, GUO-5p, and Thornthwaite-Mather) in several basins with different climatic conditions within Spain in the 1977–2010 period. We applied six statistical indices to compare the results of the models: the Akaike information criterion (AIC), the Bayesian information criterion (BIC), Nash–Sutcliffe model efficiency coefficient (NSE), coefficient of determination (R²), percent bias (PBIAS), and the relative error between observed and simulated run-off volumes (REV). Furthermore, we applied the FITEVAL software to determine the uncertainty of the model. The results show that when the catchments are more humid the obtained results are better. The GR2M model gave the best fit in peninsular Spain in a UNEP aridity index framework above 1, and NSE values above 0.75 in a 95% confidence interval classify GR2M as very good for humid watersheds. The use of REV is also a key index in the assessment of the margin of error. Flow duration curves show good performance in the probabilities of exceedance lower than 80% in wet watersheds and deviations in low streamflows account for less than 5% of the total streamflow.

The Mar Menor is a hypersaline coastal lagoon with high environmental value and a characteristic example of a highly anthropized hydro-ecosystem located in the southeast of Spain. An unprecedented eutrophication crisis in 2016 and 2019 with abrupt changes in the quality of its waters caused a great social alarm. Understanding and modeling the level of a eutrophication indicator, such as chlorophyll-a (Chl-a), benefits the management of this complex system. In this study, we investigate the potential machine learning (ML) methods to predict the level of Chl-a. Particularly, Multilayer Neural Networks (MLNNs) and Support Vector Regressions (SVRs) are evaluated using as a target dataset information of up to nine different water quality parameters. The most relevant input combinations were extracted using wrapper feature selection methods which simplified the structure of the model, resulting in a more accurate and efficient procedure. Although the performance in the validation phase showed that SVR models obtained better results than MLNNs, experimental results indicated that both ML algorithms provide satisfactory results in the prediction of Chl-a concentration, reaching up to 0.7 R²_CV (cross-validated coefficient of determination) for the best-fit models.

Assessing how climate change will affect hydrological ecosystem services (HES) provision is necessary for long-term planning and requires local comprehensive climate information. In this study, we used SWAT to evaluate the impacts on four HES, natural hazard protection, erosion control regulation and water supply and flow regulation for the Laguna del Sauce catchment in Uruguay. We used downscaled CMIP-5 global climate models for Representative Concentration Pathways (RCP) 2.6, 4.5 and 8.5 projections. We calibrated and validated our SWAT model for the periods 2005–2009 and 2010–2013 based on remote sensed ET data. Monthly NSE and R2 values for calibration and validation were 0.74, 0.64 and 0.79, 0.84, respectively. Our results suggest that climate change will likely negatively affect the water resources of the Laguna del Sauce catchment, especially in the RCP 8.5 scenario. In all RCP scenarios, the catchment is likely to experience a wetting trend, higher temperatures, seasonality shifts and an increase in extreme precipitation events, particularly in frequency and magnitude. This will likely affect water quality provision through runoff and sediment yield inputs, reducing the erosion control HES and likely aggravating eutrophication. Although the amount of water will increase, changes to the hydrological cycle might jeopardize the stability of freshwater supplies and HES on which many people in the south-eastern region of Uruguay depend. Despite streamflow monitoring capacities need to be enhanced to reduce the uncertainty of model results, our findings provide valuable insights for water resources planning in the study area. Hence, water management and monitoring capacities need to be enhanced to reduce the potential negative climate change impacts on HES. The methodological approach presented here, based on satellite ET data can be replicated and adapted to any other place in the world since we employed open-access software and remote sensing data for all the phases of hydrological modelling and HES provision assessment.