The magnetocaloriceffect is considered as an energy-efficient and environmentally friendly technique which can take cooling technology to the next level. Apart from its commercial application at room temperature, magnetic refrigeration is an up-and-coming solution for the cryogenic regime, especially as an alternative to He3 systems. Molecular magnets reveal advantageous features for ultra-low cooling which are competitive with intermetallic and lanthanide alloys. Here, we present a guide to the current status of magnetocaloric effect research of molecular magnets with a theoretical background focused on the inverse magnetocaloric effect and an overview of recent results and developments, including the rotating magnetocaloric effect.
Magnetic nanofibres have attracted more and more attention recently due to their possible applications e.g., in spintronics and neuromorphic computing. This work presents the synthesis and physicochemical characterization of the electrospun nanofibres of poly(ε-caprolactone) (PCL) doped by iron oxide nanoparticles with diameters of 5 nm. PCL is a semi-crystalline, hydrophilic polymer showing controllable biodegradation rates, biocompatibility, and flexible mechanical properties. In the composite material, two different concentrations of magnetic nanoparticles were used: 2 and 6 wt.%. PCL-based composites were investigated using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and thermogravimetry (TGA). Although in the literature one can find many studies on magnetic polymeric composites, the investigation of their magnetic properties is usually limited to measuring the magnetization curve. Detailed analysis of dynamic magnetic susceptibility is rather rare. In this report, special attention was paid to the detailed analysis of magnetic properties, where we followed the evolution of changes in the magnetic behavior of the material depending on the concentration of magnetic nanoparticles.
13 April 2023 in Journal of Magnetism and Magnetic Materials
The study of magnetocaloric effect in two related bimetallic cyanide-bridged molecular magnets: {[M (H2O)2]2[Nb (CN)8]·4H2O}n (M = Mn, Fe) is presented.
Materials exhibiting an exchange bias effect are a class of magnetic systems that have a wide range of possible technological applications e.g. in sensors, read heads, and spintronic devices. In this study, we demonstrate the effect of laser interference patterning on the magnetic properties of Pd/CoO/Co/Pd multilayers. Laser patterning creates arrays of well-ordered stripes, rectangles, and squares on the substrate surface. We found that the laser treatment caused magnetic softening of the structure edges while the centers of the objects remained unchanged and exhibited the exchange bias effect. In this study we focused on the shape and configurational magnetic anisotropies induced by patterning and showed that the magnetic properties varied depending on the angle at which the external magnetic field was applied with respect to the pattern geometry.