Thermal modification of wood causes chemical changes that significantly affect the physical, mechanical and biological properties of wood; thus, it is essential to investigate these changes for better utilization of products. Fourier transform infrared spectroscopy and size exclusion chromatography were used for evaluation of chemical changes at thermal treatment of oak wood. Thermal modification was applied according to Thermowood process at the temperatures of 160, 180 and 210 °C, respectively. The results showed that hemicelluloses are less thermally stable than cellulose. Chains of polysaccharides split to shorter ones leading to a decrease of the degree of polymerization and an increase of polydispersity. At the highest temperature of the treatment (210 °C), also crosslinking reactions take place. At lower temperatures degradation reactions of lignin predominate, higher temperatures cause mainly condensation reactions and a molecular weight increase. Chemical changes in main components of thermally modified wood mainly affect its mechanical properties, which should be considered into account especially when designing various timber constructions.

Selected and tested poplar clones are very suitable biomass resources for various applications such as biofuels, the pulp and paper industry as well as chemicals production. In this study, we determined the content of lignin, cellulose, holocellulose, and extractives, syringyl to guaiacyl (S/G) ratio in lignin, and also calculated higher heating values (HHV) among eight examined clones of Populus grown on three different experimental sites. The highest lignin content for all the examined sites was determined in ‘I-214’ and ‘Baka 5’ clones, whereas the highest content of extractives was found in ‘Villafranca’ and ‘Baka 5’ clones. The highest S/G ratio for all the examined sites was determined in ‘Villafranca’ and ‘Agathe F’ clones. The chemical profiles of main wood components, extractives, and the S/G ratio in lignin were also influenced by both the experimental site and the clone × site interaction. Higher heating values, derived from calculations based on the contents of lignin and extractives (or lignin only), were in close agreement with the previously published data. The highest heating values were found for ‘Baka 5’ and ‘I-214’ clones. The optimal method of poplar biomass utilization can be chosen on basis of the lignocellulosics chemical composition and the S/G ratio in lignin.

The growing complexity and risk profile of fire and emergency incidents necessitate advanced training methodologies that go beyond traditional approaches. Live-fire drills and classroom-based instruction, while foundational, often fall short in providing safe, repeatable, and scalable training environments that accurately reflect the dynamic nature of real-world emergencies. Recent advancements in immersive technologies, including virtual reality (VR), augmented reality (AR), mixed reality (MR), extended reality (XR), and simulation-based systems, offer promising alternatives to address these challenges. This review provides a comprehensive overview of the integration of VR, AR, MR, XR, and simulation technologies into firefighter and incident commander training. It examines current practices across fire services and emergency response agencies, highlighting the capabilities of immersive and interactive platforms to enhance operational readiness, decision-making, situational awareness, and team coordination. This paper analyzes the benefits of these technologies, such as increased safety, cost-efficiency, data-driven performance assessment, and personalized learning pathways, while also identifying persistent challenges, including technological limitations, realism gaps, and cultural barriers to adoption. Emerging trends, such as AI-enhanced scenario generation, biometric feedback integration, and cloud-based collaborative environments, are discussed as future directions that may further revolutionize fire service education. This review aims to support researchers, training developers, and emergency service stakeholders in understanding the evolving landscape of digital training solutions, with the goal of fostering more resilient, adaptive, and effective emergency response systems.

Black locust is a fast-growing deciduous tree species with multiple industrial purposes due to its valuable traits. However, the heterogeneity of colour distribution between sapwood and heartwood limits its application. Thermal modification is an environment-friendly technology for improving various wood properties, especially dimensional stability, decay resistance, and colour homogeneity. In this work, black locust (Robinia pseudoacacia L.) wood samples were thermally modified at temperatures of 160, 180, and 210 °C. Extractives and main wood components were analysed by wet chemical methods, colour was measured by spectrometry, and structural changes by Fourier transform infrared spectroscopy. The obtained results show that the darkening of black locust wood, unlike other wood species of the temperate zone, is mainly caused by changes in extractives. Their content decreases during thermal treatment, but new chromophores are formed, especially in quinones. Degradation of hemicelluloses and the partial degradation of cellulose also contribute to colour changes. At higher temperatures, condensation reactions can occur in lignin, leading to the formation of some chromophores. Statistical analysis confirmed that temperature can be considered a very significant factor affecting the colour of the wood surface.

Thermal modification is an environmentally friendly method to improve dimensional stability, durability, and aesthetic properties of wood. Changes in lignin as one of the main wood components markedly influence wood product properties and recycling possibilities of thermowood at the end of its life cycle. Teak and iroko wood samples were thermally treated at the temperatures of 160 °C, 180 °C and 210 °C following the Thermowood process. Dioxane lignin was isolated from treated and untreated wood and analysed by nitrobenzene oxidation (NBO), size exclusion chromatography (SEC) and Fourier transform infrared spectroscopy (FTIR). The yields of both acid-insoluble and dioxane lignins increased with an increasing treatment temperature. Dioxane lignins are GS-types containing more guaiacyl units compared to syringyl ones with S/G ratios of 0.91 and 0.84, respectively. In the process of thermal modification, several degradation and condensation reactions were observed. The cleavage of methoxyl groups and side chains, oxidation reactions, cleavage of the β-O-4 ether linkage and cross-linking radicals arising at higher temperatures were all confirmed. However, during the thermal treatment, teak lignin changed in a different way than iroko lignin, e.g., the molecular weight of iroko lignin decreased at all applied temperatures while it increased at 180 °C and 210 °C in teak lignin, and the change in S/G ratio and the cleavage of alkyl-aryl bonds are different in both wood species.

Traditional flame retardants often contain halogens and produce toxic gases when burned. Hence, in this study, low-cost, environmentally friendly compounds that act as fire retardants are investigated. These materials often contain nanoparticles, from which TiO₂ and SiO₂ are the most promising. In this work, pedunculate oak wood specimens were modified with sodium silicate (Na₂SiO₃, i.e., water glass) and TiO₂, SiO₂, and ZnO nanoparticles using the vacuum-pressure technique. Changes in the samples and fire characteristics of modified wood were studied via thermal analysis (TA), infrared spectroscopy (FTIR), and scanning electron microscopy, coupled with energy-dispersive X-ray spectroscopy (SEM-EDX). The results of TA showed the most significant wood decomposition at a temperature of 350 °C, with a non-significant influence of the nanoparticles. A dominant effect of sodium silicate was observed in the main weight-loss step, resulting in a drop in decomposition temperature within the temperature range of 36–44 °C. More intensive decomposition of wood treated with water glass and nanoparticles led to a faster release of non-combustible gases, which slowed down the combustion process. The results demonstrated that wood modifications using sodium silicate and nanoparticle systems have potentially enhanced flame retardant properties.