This review paper presents an overview of the state of the art on process-induced degradation of poly(lactic acid) (PLA) and the relative importance of different processing variables. The sensitivity of PLA to degradation, especially during melt processing, is considered a significant challenge as it may result in deterioration of its properties. The focus of this review is on degradation during melt processing techniques such as injection molding and extrusion, and therefore it does not deal with biodegradation. Firstly, the general processing and fundamental variables that determine the degradation are discussed. Secondly, the material properties (for example rheological, thermal, and mechanical) are presented that can be used to monitor and quantify the degradation. Thirdly, the effects of different processing variables on the extent of degradation are reviewed. Fourthly, additives are discussed for melt stabilization of PLA. Although current literature reports the degradation reactions and clearly indicates the effect of degradation on PLA’s properties, there are still knowledge gaps in how to select and predict the processing conditions that minimize process-induced degradation to save raw materials and time during production.
This article analyzes temperature fields and their variations in fused filament fabrication (FFF) from the filament entering the hot-end to the printed parts, aiming at a deeper understanding of the thermal process of this additive manufacturing technology. A standard E3D print head assembly was mounted on a robot arm for printing. A stable filament feeding region was determined with an upper limit in the volume flow rate at different nozzle temperatures. Within the limit, the steady-state temperature fields inside the hot-end were studied by a computational fluid dynamics model. Simulations indicated that the temperature became less homogeneous at higher flow rates, leading to a lower extrudate temperature at the nozzle outlet. These outlet temperatures were analyzed, validated, and used as input to simulate temperature variations in printed parts with a self-developed open-access numerical model. An interlayer time similarity rule was found in printing single-walled geometries, which specifies temperature similarities at the same interlayer time. The findings provide new insights into FFF processes, pointing out opportunities for improved production efficiency and scalability to large-scale manufacturing.
In an injection moulding process, the cooling step takes up to 50% or more of the total cycle time. Therefore, any reduction of the cooling time directly results into an increase of the production rate. Furthermore, products are often rejected because of defects such as warpage or sink marks. The cause of these defects is often an unevenly distributed cooling in the mould due to complex product or mould shapes. A solution for both problems is Conformal Cooling, a technique in which the cooling channels are designed to follow the contour of the mould cavity to obtain an optimal cooling. These often curved cooling channels are difficult or even impossible to produce with conventional techniques such as milling, drilling and EDM. The recent development of the Selective Laser Melting (SLM) 3D printing technology can be used to overcome these limitations. In a previous work [1] the cooling channels of an existing mould to produce sorting trays were assessed and redesigned to achieve a conformal cooled mould. A mould cavity and insert were provided with these cooling channels by means of the SLM technique. In this work the performance of the conformal cooled mould is compared with the original mould based on process characteristics and product measurements. In particular the start-up losses, mould temperature during the cycle, cycle time and product warpage are assessed.
One of the drawbacks of natural fibers and their composites is their inherent hydrophilic nature. The effect of moisture on the mechanical properties of composites is irrefutable. This study deals with the hygroscopic characteristics of enset–PLA composites and their effect on the mechanical properties of the composites. To do this, injection-molded composite specimens with different fiber volume fractions, plasticizer ratios, fiber lengths, and fiber ages were considered. The specimens were exposed to distilled water, and the moisture absorption was monitored on a daily basis. Subsequently, the specimens were subjected to mechanical loading to determine the effect of moisture on their strength, stiffness, and strain at break strength. Lastly, the individual and joint effects of the considered factors were scrutinized using an optimal experimental design. The results of the study show that the maximum and minimum moisture uptakes were recorded for 25% and 15% fiber ratios, respectively. Due to the effect of moisture, the tensile and bending strength decreased by 11% and 5%, respectively, for the 15% fiber volume fraction and decreased by 16% and 13%, respectively, for the 25% fiber volume fraction. Increasing the amount of plasticizer increases the moisture resistance. The results indicate that Enset–PLA composites have competitive properties and stability when exposed to moisture.