π-Helical push–pull dyes were prepared and their (chir)optical properties were investigated both experimentally and computationally. Specific fluorescent behaviour of bis-substituted system was observed with unprecedented solvent effect on the intensity of circularly polarized luminescence (CPL, dissymmetry factor decreasing from 10⁻² to 10⁻³ with an increase in solvent polarity) that was linked to a change in symmetry of chiral excited state and suppression of interbranched exciton coupling. The results highlight the potential of CPL spectroscopy to study and provide a deeper understanding of electronic photophysical processes in chiral π-conjugated molecules.

Sustainable building practices are a response to environmental issues. Businesses and industries are assessing how their activities affect the environment. The architecture, engineering and construction (AEC) industries have significant impacts on the environment and economy, while the industry is considered one of the largest contributors to greenhouse gas (GHG) emissions and has, therefore, been highlighted by researchers as a key area of intervention with a great potential to reduce environmental impacts. This paper critically reviews and evaluates the current state of sustainable building certification systems with the purpose of having a good understanding of the status quo and possibilities for future directions in Saudi Arabia. It reviews the academic literature on Saudi Arabia’s green/sustainable building codes, standards, certification systems, methods and tools. It starts by addressing sustainability in the broadest sense. Then, it investigates sustainability strategies and evaluates the building certification systems in Saudi Arabia, followed by an introduction to the new practice of sustainable healthcare building assessment. Life cycle assessment (LCA) and building information modelling (BIM) techniques have also been investigated. The paper introduces the updated Saudi Building Code (SBC) with further evaluation of the Saudi Green Building Code (SBC 1001-CR). Finally, the paper clearly highlights the key role of sustainable building practices and the need to develop a certification system that considers the new trends and the local context.

In this study, we investigated the potential of palladium tetrakis (imidazole) phthalocyanine (PdPc(Imz)₄) for use as an organic semiconductor for improving the photovoltaic performance. In order to get more information about the prevailing model of the conduction mechanism (correlated barrier hopping (CBH)) for PdPc(Imz)₄, electrical impedance measurements were performed at different temperatures and the obtained data were simulated by the Kohlraush Williams Watt (KWW) approach. Theoretical studies (density functional theory (DFT)) were performed and molecular electrostatic potential (MEP) maps were also extracted to understand the relationship between the molecular structures and the molecular electronic structure of PdPc(Imz)₄ and its semiconductor properties. Furthermore, studies on the AC electrical process as a function of temperature highlighted a hopping charge transport according to an equivalent electrical circuit composed of a parallel constant-phase element (CPE), capacitance in the grain boundary layer (C_g), and resistance of the grain boundary (R_g). To improve interpretation of the results, an in-depth analysis of the behavior of the electric transport was conducted. As a result, the correlated barrier hopping (CBH) conduction mechanism was shown to be the most suitable predominant conduction mechanism.

This study explores the novel use of mixed cultures of microalgae—Spirulina platensis, Micractinium, and Chlorella—for nutrient removal from dairy wastewater (DW). Microalgae were isolated from a local wastewater treatment plant and cultivated under various light conditions. The results showed significant biomass production, with mixed cultures achieving the highest biomass (2.51 g/L), followed by Spirulina (1.98 g/L) and Chlorella (1.92 g/L). Supplementing DW (75%) with BG medium (25%) significantly enhanced biomass and pH levels, improving pathogenic bacteria removal. Spirulina and mixed cultures exhibited high nitrogen removal efficiencies of 92.56% and 93.34%, respectively, while Chlorella achieved 86.85% nitrogen and 83.45% phosphorus removal. Although growth rates were lower under phosphorus-limited conditions, the microalgae adapted well to real DW, which is essential for effective algal harvesting. Phosphorus removal efficiencies ranged from 69.56% to 86.67%, with mixed cultures achieving the highest removal. Microbial and coliform removal efficiencies reached 97.81%, with elevated pH levels contributing to significant reductions in fecal E. coli and coliform levels. These findings suggest that integrating microalgae cultivation into DW treatment systems can significantly enhance nutrient and pathogen removal, providing a sustainable solution for wastewater management.

In this study, a series of new metal phthalocyanines with imidazole function MPc(Imz) (M: Cd, Hg, Zn and Pd) were synthesized to improve the photocatalyst performances. All physical properties such as total energy, HOMO, LUMO energies of MPc(Imz), as well as their vibrational frequencies have been determined by DFT method using B3LYP theory level at 6-311G (d, p) and sdd basis set. The gap of energy level between work function (WF) of ITO and LUMO of PdPc(Imdz) was 1.53 eV and represents the highest barrier beneficial to electron injection compared to WF of ZnPc(Imz), HgPc(Imz), and CdPc(Imz). Furthermore, the PdPc(Imdz) thin films on indium tin oxide (ITO) glass were prepared by spin coating and vacuum evaporation technique, and were characterized by X-ray diffraction (XRD), surface electron morphology (SEM), atomic force microscopy (AFM), and UV–Vis spectroscopy. The photocatalytic activity of the ITO/glass supported thin films and degradation rates of chlorinated phenols in synthetic seawater, under visible light irradiation were optimized to achieve conversions of 80–90%. Experiments on synthetic seawater samples showed that the chloride-specific increase in photodegradation could be attributed to photochemically generated chloride radicals rather than other photoproduced reactive intermediates [e.g., excited-state triplet PdPc(Imz) (³PdPc(Imz)*), reactive oxygen species]. The major 2,3,4,5-Tetrachlorophenol degradation intermediates identified by gas chromatography-mass spectrometry (GC/MS) were 2,3,5-Trichlorophenol, 3,5-dichlorophenol, dichlorodihydroxy-benzene and 3,4,5-trichlorocatechol.

In order to enhance the efficacy of organic solar cells, six new three-dimensional small donor molecules (IT-SM1 to IT-SM6) have been computationally designed by modifying the peripheral acceptors of the reference molecule (IT-SMR). The frontier molecular orbitals revealed that IT-SM2 to IT-SM5 had a smaller band gap (E_gap) than IT-SMR. They also had smaller excitation energies (E_x) and exhibited a bathochromic shift in their absorption maxima (λ_max) when compared to IT-SMR. In both the gas and chloroform phases, IT-SM2 had the largest dipole moment. IT-SM2 also had the best electron mobility, while IT-SM6 had the best hole mobility owing to their smallest reorganization energy for electron (0.1127 eV) and hole (0.0907 eV) mobility, respectively. The analyzed donor molecules' open-circuit voltage (V_OC) indicated that all of these proposed molecules had greater V_OC and fill factor (FF) values than the IT-SMR molecule. In accordance with the evidence of this work, the altered molecules can seem to be quite proficient for usage by experimentalists and have prospective use in future in the manufacture of organic solar cells with improved photovoltaic properties.