Newspapers have a limited lifespan, and therefore represent a focus of used and disposed paper. While these refuses have a considerable value and can be easily recycled, a considerable fraction ends in landfill. The authors show the possibility of adding value to used newspaper and enlarge its value chain. Old newspaper incorporates a high amount of wood fibers able to be used as reinforcement. On the other hand, this material also incorporates inks and other components inherent to newspaper production. In this work, the authors disintegrate old newspaper to recover and individualize wood fibers. A morphological analysis showed that the recovered fibers had aspect ratios higher than 10, revealing, a priori, their strengthening capabilities. Thereupon, these fibers were compounded with polypropylene at different contents, ranging from 20% to 50% w/w. It is well known that wood fibers are hydrophilic, while polyolefin are hydrophobic. This is a drawback to obtaining strong interfaces. Thus, two sets of composites were produced, with and without a coupling agent. The results showed that uncoupled composites increased the flexural strength of the matrix but reached an equilibrium point from which adding more reinforcement did not changer the flexural strength. On the other hand, the coupled composites showed a linear increase of the flexural strength against the reinforcement content. The flexural moduli of the coupled and uncoupled composites were very similar and evolved linearly with the reinforcement content.

The use of untreated natural fibers to reinforce cementitious composites improves their environmental friendliness, resulting in a more sustainable material. Moreover, the influence of the untreated natural fibers on the hydration process of Portland cement composites presents some uncertainties. According to the literature, the most usual tests to analyze the degree of hydration of cement composites are the differential thermal and thermogravimetric analyses (TGA/dTGA). Several authors propose to analyze data methods to establish the degree of hydration of cement composites. This paper presents the TGA/dTGA test carried out on mortar samples with and without fibers at age 2, 3, 7, 14, and 28 days. The degree of hydration was calculated according to Bhatty’s method. To characterize the raw materials, the quantitative chemical was determined using scanning electron microscopy and energy dispersive X-ray spectroscopy (SEM–EDX). The main findings of this study were that the presence of untreated natural hemp fibers in the OPC composites increased the hydration degree by 9%. The presence of fibers affected the formation of several components. Thus, their presence increased the formation of monosulphate, reduced portlandite, did not affect ettringite, and increased the formation of calcite, thereby improving the sustainable footprint due to the increased CO₂ fixation.

Dry-stone structures are traditional constructions that are present everywhere around the world, with their stability working mostly by gravity. Contrarily to their in-plane behavior, their out-of-plane response is very brittle and is fully controlled by the geometry, as well as the contact properties, between units (stones). Two main local failure modes of dry-joint contact are identified to lead to the global failure of the structure: (i) sliding and (ii) joint opening. Most of the existing studies investigated full structures to obtain the global response and/or couplet only, with the aim of only characterizing the contact. The present experimental work studies the effect of sliding and joint opening between stones at different scales: couplets, structures made of a few (up to five) blocks, and full walls, as well as varying the way the masonry units are assembled within a single structure. Different stones are employed to quantify potential differences. All the structures are loaded up to the collapse with a tilting table to induce out-of-plane actions. Repeatability tests are also conducted to better understand the effect of contact variability. This study unveils that the heterogeneity of the dry-joint contact, as well as the repartition of the blocks, affects the global response (both in terms of load capacity and failure mode). It also confirms that the most critical local failure mode is produced by the joint opening.

Aldolases are prodigious C-C bond forming enzymes, but their reactivity has only been extended past activated carbonyl electrophiles in special cases. We have used a pair of pyridoxal-phosphate-dependent aldolases to probe the mechanistic origins of this limitation. Our results reveal how aldolases are limited by thermodynamically favorable proton transfer with solvent, which undermines aldol addition into ketones. However, we show how a transaldolase can circumvent this limitation by protecting the enzyme-bound enolate from solvent protons and thereby enabling efficient addition into unactivated ketones. The resulting products are non-canonical amino acids with side chains that contain chiral tertiary alcohols. This study reveals the principles for extending aldolase catalysis beyond its previous limits and enables convergent, enantioselective C-C bond formation from simple starting materials.

The degradation of the natural fibers in the hydraulic binder alkaline matrix is widely known. This study investigates the effect of two fiber treatments, namely immersion in sodium hydroxide (NaOH) solution and hornification, in two types of alkaline environmental ordinary Portland cement (OPC) and a mixture of OPC and natural hydraulic lime (NHL). After curing for 28 days, the specimens were subjected to 25 and 50 dry–wet aging cycles to evaluate their degradation behavior. Subsequently, the specimens underwent flexural and compressive strength tests. This study reveals that the specimens with the mixed binder of ordinary Portland cement (OPC) and natural hydraulic lime (NHL), after 50 aging cycles, reached toughness values in the descending branch compared to the total toughness obtained in the flexural–displacement diagram, of 17% and 27% for the treatment with NaOH and hornification fiber, compared to 3% and 10% obtained for the matrix with an OPC binder. Therefore, the inclusion of NHL as a matrix binder provided better softening behavior than those with only the OPC binder, providing better protection of the fibers against environmental alkalinity due to matrix alkalinity. In addition, the hornification treatment better preserved the fibers throughout the aging process.