SERS AuNP EF dimer/EF monomer vs. gap, nm (y = e^−x) on Au, Ag, Al, Si, 1220+ nanoantennae.

An overview of the prospects for the development of nuclear technologies and the conclusion of the relevant requirements for advanced structural materials, their classification and features were performed. In order to obtain a bar with a modified radiation-resistant outer layer, an experiment of radial-shear rolling under the most stringent conditions was carried out. For the same conditions, a FEM-simulation of sequential rolling in eight passes with a total compression of 70.7% (from a diameter of 37 mm to 20 mm) was conducted. For adequate simulation results a new material database for Zr-1%Nb alloy using plastometry investigations was generated. An experimental obtaining of a gradient-modified structure with an ultrafine-grained (UFG) periphery and an elongated rolling texture in the center of the bar was performed.

Improving the quality of metal products by crushing of the microstructure of material is one of the promising areas of modern metallurgy. The basic idea consists in refinement the grain structure of the material to sizes less than a micron, i.e. the obtaining of ultrafine-grained (UFG) materials, offering higher strength properties of the material under preservation or a small loss of ductility. Stainless austenitic steel AISI 321 is widely used in all the above areas as well as in chemical, vacuum and nuclear technology. For the obtaining of UFG structure in this material the method of radial-shear rolling is used. For the purpose of identifying the influence of radial-shear rolling on microstructure and mechanical properties of stainless austenitic steel AISI-321, the experiment was conducted where at the radial-shear rolling mill SVP-08 at 800 °C in several passes of the workpieces with a diameter of 30 mm rolled till a diameter of 13 mm with following cooling in water. The analysis of the microstructure of deformed samples showed the presence of equiaxed ultrafine-grained structure in the peripheral areas of the workpiece and the presence of elongated fibrous texture in the axial zone. The strength characteristics of the workpiece has increased more than 2 times, with a slight decrease of plasticity.

In advancing special materials, seamless integration into existing production chains is paramount. Beyond creating improved alloy compositions, precision in processing methods is crucial to preserve desired properties without drawbacks. The synergy between alloy formulation and processing techniques is pivotal for maximizing the benefits of innovative materials. By focusing on advanced deep processing technology for small ingots of modified 12% Cr stainless steel, this paper delves into the transformation of cast ingot steel structures using radial shear rolling (RSR) processing. Through a series of nine passes, rolling ingots from a 32 mm to a 13 mm diameter with a total elongation factor of 6.02, a notable shift occurred. This single-operation process effectuated a substantial change in sample structure, transitioning from a coarse-grained cast structure (0.5–1.5 mm) to an equiaxed fine-grained structure with peripheral grain sizes of 1–4 μm and an elongated rolling texture in the axial part of the bar. The complete transformation of the initial cast dendritic structure validates the implementation of the RSR method for the deep processing of ingots.

In this article, we present research results on the closing conditions of internal metallurgical discontinuities during the hot elongation operation of a Zr-1%Nb alloy ingot using physical and numerical modeling. Research on the influence of thermal and deformation parameters of elongation operations on the rheological behavior of a Zr-1% Nb alloy was conducted using the Gleeble 3800 metallurgical process simulator. Modeling of the influence of thermal–mechanical parameters of hot elongation operations in combinations of rhombic and flat anvils on the closure of metallurgical discontinuities was performed with the help of the FORGE^®NxT 2.1 program. Based on the results of the research, recommendations were made regarding forging elongation technology and the geometry of working tools in order to ensure the closure of metallurgical discontinuities during hot elongation operations of Zr-1% Nb alloy ingots.

This paper investigates the behavior of transverse defects under significant total strain in conditions of complex vortex metal flow implemented through the radial shear rolling (RSR) method. The aim of this study is to assess the applicability of RSR processing for the in-depth transformation of small ingots of special steel into bars, particularly for the manufacturing of structural elements in specialized construction projects such as nuclear power plants. Although a substantial total strain is anticipated to enhance the steel structure and contribute to defect closure, the question of the development or closure of potential casting defects remains unclear. To address this issue, model tests were conducted to simulate the implementation of RSR processing. Defect behavior data under very complex vortex metal flow and high strain conditions were obtained for the first time and have scientific merit. A small steel ingot with a 32 mm diameter, containing a simulated artificial defect in the form of a transverse through-hole with a 5 mm diameter, was employed. During rolling, the workpiece diameter was progressively reduced by 2 mm with each subsequent pass, reaching a final diameter of 20 mm. Additionally, to provide a more detailed visualization of the defect evolution process, the same defect was modeled in an aluminum bar over six passes, and changes in defect volume and shape were analyzed after each pass. A highly detailed 3D visualization of the actual defect evolution was achieved based on cross-sections from experimental workpieces. These data corresponded to the total strain levels obtained by finite element method (FEM) simulation. Notably, a consistent similarity was observed between the test results for both metals, revealing a reduction in defect volume of up to 67.7%. The deformational welding of defects in the outer sections, encompassing one-third of the rod’s radius, occurred in the initial passes. However, defects in the axial zone of the rods remained unclosed, lengthening and gradually decreasing proportionally to the elongation of the rod, akin to conventional rolling. Consequently, the radial shear rolling (RSR) method is unsuitable for ingots with substantial discontinuities in the axial zone post-casting. Nevertheless, the method ensures the total welding of defects located in the outer zones of the ingots, even with minor applied deformations and a slight decrease in the diameter of the deformed ingot. Such data were obtained for the first time and should contribute to future investigations in this field.