Semi-rigid composites of polyurethane foams (SRPUF) modified with the addition of keratin flour from poultry feathers and flame retardant additives were manufactured. Ten percent by mass of keratin fibers was added to the foams as well as halogen-free flame retardant additives such as Fyrol PNX, expandable graphite, metal oxides, in amounts such that their total mass did not exceed 15%. Thermal and mechanical properties were tested. Water absorption, dimensional stability, apparent density and flammability of produced foams were determined. It was found that the use of keratin fibers and flame retardant additives changes the foam synthesis process, changes their structure and properties as well as their combustion process. The addition of the filler made of keratin fibers significantly limits the amount of smoke generated during foam burning. The most favorable reduction of heat and smoke release rate was observed for foams with the addition of 10% keratin fibers and 10% expandable graphite. Systems of reducing combustibility of polyurethane foams using keratin fillers are a new solution on a global scale.
In the present work, sustainable rigid polyurethane foams (RPUF) reinforced with chicken feathers (CF) were prepared and characterized. The bio-based polyol used to formulate the foams was obtained from castor oil. This investigation reports the influence of the chicken feathers fibers as reinforcement of RPUF, on water absorption, thermal, mechanical and morphological properties (field-emission scanning electron microscope—FESEM) and thermal conductivity on water-blown biofoams. It was found that the biofoams improved thermal insulating properties when CF was added. The addition of CF to foams provided lower heat flux density to the biofoams obtaining bio-based materials with better insulation properties. The results obtained in this study proved that the incorporation of CF to RPUF modified the cell structure of the foams affecting their physical and mechanical properties, as well as functional properties such as the heat transmission factor. These biofoams containing up to 45% of bio-based materials have shown the potential to replace fully petroleum-based foams in thermal insulation applications.
Feather waste is a major issue from an economic and environmental point of view. Even though there are already routes for the valorisation of feathers into fertilisers and feather meal, these are considered to have low added value. For more attractive applications, for example in agricultural biodegradable plastics, higher and faster degradability in soil is required. To face this challenge alternative approaches to accelerate biodegradation and disintegration processes are needed. In this context, steam explosion appears as an effective technology to modify the structure of feather and improve its soil degradability. In this work, chicken feathers were treated by steam explosion and the effect of treatment on their structure and physico-chemical and thermal properties were evaluated. Finally, the effect of the process conditions on the disintegration and biodegradation in soil of feathers was also investigated, finding an increased degradation in soil of steam explosion treated feathers. These results open up the possibilities of using feather waste as a component for environmentally friendly agricultural bioplastics that can be degraded in-situ in soil.
Viscoelastic polyurethane (VEPUR) foams with increased thermal resistance are presented in this article. VEPUR foams were manufactured with the use of various types of flame retardant additives and keratin fibers. The structure of the modified foams was determined by spectrophotometric-(FTIR), thermal-(DSC), and thermogravimetric (TGA) analyses as well as by scanning electron microscopy (SEM). We also assessed the fire resistance, hardness, and comfort coefficient (SAG factor). It was found that the use of keratin filler and flame retardant additives changed the foams’ structure and properties as well as their burning behavior. The highest fire resistance was achieved for foams containing keratin and expanding graphite, for which the reduction in heat release rate (HRR) compared to VEPUR foams reached 75%.
Geotextiles are widely used for separation, drainage, filtration, and erosion control, as well as for enhancing plant growth conditions. The objective of this study was to evaluate the impact of incorporating poultry feathers on the biodegradation rate of nonwoven geotextiles in arable soil. The research was conducted under laboratory conditions, with biodegradation assessed based on mass loss. The findings confirmed that the presence of keratin-rich waste positively influenced the biodegradation rate of the tested materials. Additionally, the potential ecotoxicological effects of biodegradation were examined, revealing no adverse impact on microbiological activity. Statistical analysis demonstrated a correlation between material composition and biodegradation time. This study represents a significant step toward the sustainable management of poultry feather waste in agricultural applications. The tested materials could serve as an environmentally viable alternative for long-term applications, aligning with ecological sustainability principles by simultaneously enriching soil with essential nutrients and promoting waste valorization.