Nicolas Candau

Dr. Nicolas Candau

Centre Català del Plàstic (CCP) - Universitat Politècnica de Catalunya Barcelona Tech (EEBE-UPC), Av. D’Eduard Maristany, 16, 08019, Spain
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Research Focus & Metrics

Academic Career Length

16Years (2011-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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4 August 2014 in Macromolecules
Verified
Journal Article
Closed access
Nicolas CandauNicolas Candau
Nicolas Candau
RLRabia Laghmach
Rabia Laghmach
Laurent ChazeauLaurent Chazeau
Laurent Chazeau
JCJean-Marc Chenal
Jean-Marc Chenal
CGCatherine Gauthier
Catherine Gauthier
EMEtienne Munch
Etienne Munch

1 March 2015 in European Polymer Journal
Verified
Journal Article
Closed access
Nicolas CandauNicolas Candau
Nicolas Candau
RLRabia Laghmach
Rabia Laghmach
Laurent ChazeauLaurent Chazeau
Laurent Chazeau
JCJean-Marc Chenal
Jean-Marc Chenal
CGCatherine Gauthier
Catherine Gauthier
EMEtienne Munch
Etienne Munch

1 June 2012 in Polymer
Verified
Journal Article
Closed access
Nicolas CandauNicolas Candau
Nicolas Candau
Laurent ChazeauLaurent Chazeau
Laurent Chazeau
JCJean-Marc Chenal
Jean-Marc Chenal
CGCatherine Gauthier
Catherine Gauthier
JFJosé Ferreira
José Ferreira
CRCyrille Rochas
Cyrille Rochas

22 December 2015 in Physical Chemistry Chemical Physics
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Journal Article
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Nicolas CandauNicolas Candau
Nicolas Candau
Laurent ChazeauLaurent Chazeau
Laurent Chazeau
JCJean-Marc Chenal
Jean-Marc Chenal
CGCatherine Gauthier
Catherine Gauthier
EMEtienne Munch
Etienne Munch
Strain induced crystallization (SIC) of a natural rubber (NR) and a synthetic rubber (IR) with a high amount of cis-1,4 units (98.6%) is studied, thanks to in situ wide angle X-ray (WAXS) experiments at room temperature performed in a large range of strain rates. During stretching at a low strain rate (4.2 × 10−3 s−1), SIC in IR occurs at a larger stretching ratio than in NR. As a result, the crystallinity index at a given stretching ratio is lower in IR than in NR, in spite of the similar crosslink densities of the chains involved in the crystallization in both materials. This lower ability for crystallization in IR is attributed to the presence of branching along its backbone and its lower stereoregularity. Conversely, dynamic experiments performed at high strain rates (101/102 s−1) show for both materials a similar ability to crystallize. This unexpected result is confirmed by monotonic tensile tests performed in a large range of strain rates. The reason is thermodynamic: the chain extension plays a predominant role compared to the role of the microstructure defects when the strain rate is high, i.e. when the kinetics of the crystallite nucleation forces the crystallization to occur at a large stretching ratio. A thermodynamic model enables qualitative reproduction of the experimental results.

1 November 2021 in Polymer
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Journal Article
Closed access
Nicolas CandauNicolas Candau
Nicolas Candau
EVEduard Vives
Eduard Vives
AFAna Inés Fernández
Ana Inés Fernández
MMMaria Lluïsa Maspoch
Maria Lluïsa Maspoch

1 May 2021 in Polymer
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Journal Article
Closed access
Nicolas CandauNicolas Candau
Nicolas Candau
GSGregory Stoclet
Gregory Stoclet
JTJean-François Tahon
Jean-François Tahon
ADAdrien Demongeot
Adrien Demongeot
EYEmel Yilgor
Emel Yilgor
OOOguzhan Oguz
Oguzhan Oguz