A graphene-based nanosensor was fabricated to selectively detect nitrotriazolone (NTO) molecules with a molecularly imprinted film via simple electrical measurements. Molecularly imprinted polymer comprising chitosan was used as sensitive layer. Gold electrodes for electrical measurements were lithographically fabricated on Si/SiO₂ substrate, followed by monolayer graphene transfer and polymeric film coating. Monolayer graphene and molecularly imprinted polymer were characterized by ATR-FTIR, UV-Vis, SEM and Raman spectroscopy. Transfer-length measurements (TLM) indicate that the sensor selectively and linearly responds against aqueous NTO solutions within a wide range of concentration of 0.01–0.1 mg mL⁻¹ that covers the lowest toxic level of NTO determined by USEPA. This nanosensor with embedded electrodes is re-usable and suitable for field applications, offering real-time electrical measurements unlike current techniques where complex analytics are required.

Superabsorbent polymers (SAPs) are useful polymers in a wide range of application fields ranging from the hygiene industry to construction and agriculture. As versatility and high water absorption capacity are their important merits, SAPs usually suffer from low water retention capacity (fast release) and weak mechanical properties. To address these drawbacks, a set of new superabsorbent polymer-Halloysite nanotube (HNT) nanocomposites was synthesized via free radical polymerization of acrylamide, 2-acrylamido-2-methylpropane-1-sulfonic acid, and acrylic acid in the presence of vinyltrimethoxysilane (VTMS) as the crosslinker. FTIR and TGA characterizations confirm the polymerization of SAP and successful incorporation of HNTs into the SAP polymer matrix. The effect of the HNT nanofiller amount in the nanocomposite polymer matrix was investigated with swelling-release performance tests, crosslink density calculations, and rheology measurements. It was found that equilibrium swelling ratios are correlated and therefore can be tuned via the crosslink densities of nanocomposites, while water retention capacities are governed by storage moduli. A maximum swelling of 537 g/g was observed when 5 wt % HNT was incorporated, in which the crosslink density is the lowest. Among the SAP nanocomposites prepared, the highest storage modulus was observed when 1 wt % of nanofiller was incorporated, which coincides with the nanocomposite with the longest water retention. The water release duration of SAPs was prolonged up to 27 days with 1% HNT addition in parallel with the achieved maximum storage modulus. Finally, three different incorporation mechanisms of the HNT nanofiller into the SAP nanocomposite structure were proposed and confirmed with rheology measurements. This study provides a rapid synthesis method for SAP nanocomposites with enhanced water retention capacities and explains the relationship between swelling and crosslink density and water retention and mechanical properties of SAP nanocomposites.