Global accessibility to clean water has stressed the need to develop advanced technologies for the removal of toxic organic and inorganic pollutants and pathogens from wastewater to meet stringent discharge water quality limits. Conventionally, the high separation efficiencies, relative low costs, small footprint, and ease of operation associated with integrated photocatalytic-membrane (IPM) technologies are gaining an all-inclusive attention. Conversely, photocatalysis and membrane technologies face some degree of setbacks, which limit their worldwide application in wastewater settings for the treatment of emerging contaminants. Therefore, this review elucidated titanium dioxide (TiO2), based on its unique properties (low cost, non-toxicity, biocompatibility, and high chemical stability), to have great potential in engineering photocatalytic-based membranes for reclamation of wastewater for re-use. The environmental pathway of TiO2 nanoparticles, membranes and configuration types, modification process, characteristics, and applications of IPMs in water settings are discussed. Future research and prospects of magnetized TiO2-based membrane technology is highlighted as a viable water purification technology to mitigate fouling in the membrane process and photocatalyst recoverability. In addition, exploring life cycle assessment research would also aid in utilizing the concept and pressing for large-scale application of this technology.
Increased affordability, smaller footprint, and high permeability quality that meets stringent water quality standards have accelerated the uptake of membranes in water treatment. Moreover, low pressure, gravity-based microfiltration (MF) and ultrafiltration (UF) membranes eliminate the use of electricity and pumps. However, MF and UF processes remove contaminants by size exclusion, based on membrane pore size. This limits their application in the removal of smaller matter or even harmful microorganisms. There is a need to enhance the membrane properties to meet needs such as adequate disinfection, flux amelioration, and reduced membrane fouling. To achieve these, the incorporation of nanoparticles with unique properties in membranes has potential. Herein, we review recent developments in the impregnation of polymeric and ceramic microfiltration and ultrafiltration membranes with silver nanoparticles that are applied in water treatment. We critically evaluated the potential of these membranes in enhanced antifouling, increased permeability quality and flux compared to uncoated membranes. Despite the intensive research in this area, most studies have been performed at laboratory scale for short periods of time. There is a need for studies that assess the long-term stability of the nanoparticles and the impact on disinfection and antifouling performance. These challenges are addressed in this study and future directions.
18 March 2019 in Environmental Engineering Research
This study was aimed at using the Central Composite Design (CCD) and Box-Behnken Design (BBD) to compare the efficiency and to elucidate the main interacting parameters in the upflow anaerobic sludge blanket (UASB) reactor, namely: Organic Loading Rate (OLR), Hydraulic Retention Times (HRT) and pH at a constant temperature of 35°C. Optimum HRT (15 h), OLR (3.5 kg.m-3 .d-1) and pH (7) resulted in biogas production of 5,800 mL/d and COD removal of 80.8%. BBD produced a higher desirability efficiency of 94% as compared to the CCD which was 92%. The regression quadratic models developed with high R 2 values of 0.961 and 0.978 for both CCD and BBD respectively, demonstrated that the interaction models could be used to pilot the design space. BBD model developed was more reliable with a higher prediction of biogas production (5,955.4 ± 225.3 mL/d) and COD removal (81.5 ± 1.014%), much close to the experimental results at a 95% confidence level. CCD model predictions was greater in terms of COD removal (82.6 ± 1.06% > 80.8%) and biogas production (4,636.31 mL/d ± 439.81 < 5,800 mL/d) which was less than the experimental results. Therefore, RSM can be adapted for optimizing various wastewater treatment process.
Access to safe, clean drinking water is a critical challenge across many resource-constrained settings, especially in developing economies. Large-scale water treatment technologies are often available in urban areas, whereas such centralized systems are unavailable in rural and remote areas due to high infrastructure costs, rugged terrains, and maintenance challenges. To address this challenge, point-of-use (PoU) water treatment systems can fill this critical gap. This study critically evaluates the role low-cost PoU water treatment solutions play as a promising alternative to address water access and quality aspects in remote rural areas. The study explores the present state of global water sources, the challenges of water scarcity and pollution, and the limitations of existing large-scale treatment technologies. It highlights the motivation behind PoU systems and provides an in-depth analysis of various low-cost technologies, including operational principles, performance efficiency, and economic viability. Embedded in this study is a concise evaluation of the sustainability of these solutions in addressing water access and quality challenges in resource-limited regions. Finally, the study proposes solutions and perspectives on improving PoU systems and scale-up of the systems for large-scale applications to facilitate increased access to clean and safe water.
The anthropogenic deployment of plastic waste, especially petroleum-based plastics with toxic hydrocarbons, presents a significant environmental and health threat in sub-Saharan Africa (SSA). Herein, the high demand and rapid plastic production, coupled with improper disposal and inadequate waste management, have led to widespread contamination of air, water, and soil. Conventionally, plastic waste management, such as incineration and recycling, provides limited long-term solutions to this growing crisis. This necessitates urgent, sustainable, and eco-friendly remediation techniques to mitigate its far-reaching environmental implications. This comprehensive review focused on sustainable and eco-friendly techniques by exploring strengths, weaknesses, opportunities, and threats (SWOT) analysis of plastic waste management. Bioremediation techniques were found as potential solutions for addressing plastic waste in SSA. This paper examines advancements in physiochemical methods, the challenges in managing various plastic types, and the role of enzymatic and microbial consortia in enhancing biodegradation. It also explores the potential of genomic technologies and engineered microbial systems to convert plastic waste into valuable products, including bioenergy via bio-upcycling. These bioremediation strategies align with the United Nations Sustainable Development Goals (UN SDGs), offering a promising path to reduce the environmental and health impacts of plastic pollution in the region. This paper also considers future directions of integrating AI-powered recycling systems to facilitate the development of a circular economy in SSA. Additionally, this paper provides progress and future perspectives on bioremediation as a sustainable solution for plastic waste management in SSA.
In this study, the principle of sustaining circular economy is presented as a way of recovering valuable resources from wastewater and utilizing its energy potential via anaerobic digestion (AD) of municipality wastewater. Biostimulation of the AD process was investigated to improve its treatability efficiency, biogas production, and kinetic stability. Addressing this together with agricultural waste such as eggshells (CE), banana peel (PB), and calcined banana peels (BI) were employed and compared to magnetite (Fe3O4) as biostimulation additives via 1 L biochemical methane potential tests. With a working volume of 0.8 L (charge with inoculum to substrate ratio of 3:5 v/v) and 1.5 g of the additives, each bioreactor was operated at a mesophilic temperature of 40 °C for 30 days while being compared to a control bioreactor. Scanning electron microscopy and energy dispersive X-ray (SEM/EDX) analysis was used to reveal the absorbent’s morphology at high magnification of 10 kx and surface pore size of 20.8 µm. The results showed over 70% biodegradation efficiency in removing the organic contaminants (chemical oxygen demand, color, and turbidity) as well as enhancing the biogas production. Among the setups, the bioreactor with Fe3O4 additives was found to be the most efficient, with an average daily biogas production of 40 mL/day and a cumulative yield of 1117 mL/day. The kinetic dynamics were evaluated with the cumulative biogas produced by each bioreactor via the first order modified Gompertz and Chen and Hashimoto kinetic models. The modified Gompertz model was found to be the most reliable, with good predictability.