Non-metallic pipe (NMP) materials are used as an internal lining and standalone pipes in the oil and gas industry, constituting an emerging corrosion strategy. The NMP materials are inherently susceptible to gradual damage due to creep, fatigue, permeation, processing defects, and installation blunder. In the presence of acid gases (CO₂, H₂S), and hydrocarbons under high pressure and temperature, the main damage is due to permeation. The monitoring of possible damage due to permeation is not well defined, which leads to uncertainty in asset integrity management. Assessment of permeation damage is currently performed through mechanical, thermal, chemical, and structural properties, employing Tensile Test, Differential Scanning Calorimetry (DSC), Fourier-transform Infrared Spectroscopy (FTIR), and Scanning Electron Microscopy (SEM)/Transmission Electron Microscopy (TEM), to evaluate the change in tensile strength, elongation, weight loss or gain, crystallinity, chemical properties, and molecular structure. Coupons are commonly used to analyze the degradation of polymers. They are point sensors and did not give real-time information. Polymers are dielectric materials, and this dielectric property can be studied using Impedance Analyzer and Dielectric Spectroscopy. This review presents a brief status report on the failure of polymer liners in pipelines due to the exposure of acid gases, hydrocarbons, and other contaminants. Permeation, liner failures, the importance of monitoring, and new exclusive (dielectric) property are briefly discussed. An inclusive perspective is provided, showing the challenges associated with the monitoring of the polymer liner material in the pipeline as it relates to the life-time prediction requirement.

Extensive damage due to saturated seawater and CO₂ exposure under high temperature and pressure in high-density polyethylene (HDPE) has been studied by Infrared Spectroscopy (FTIR), Differential Scanning Calorimetry (DSC), Thermogravimetric Analysis (TGA), Field Emission Scanning Electron Microscope (FESEM), and Electrochemical Impedance Spectroscopy (EIS). The degradation of square-shaped HDPE samples having 1 mm thickness was investigated at 70 bars with 60, 75, and 90 °C separately for three weeks in an autoclave chamber. A clear indication of aging was observed in terms of chain scission by the formation of the methyl group (1262 cm⁻¹), and the appearance of degradation products, including the alcohol and hydroxyl groups. The decline in glass transition temperature (T_g), melting point (T_m), and crystallinity (X_c) result from branching and formation of degradation products in the aged samples. TGA results reveal that the degradation shifts the characteristic temperatures (T_5% and T_10%) to lower values compared to virgin HDPE. FESEM images show clear surface cracks and rough patches after 3 weeks. The X_c value increased due to chain mobility at higher temperatures (90 °C). The impedance is relatively high 10¹¹ ohms.cm⁻² for a virgin sample, but it drops down to 10⁹ and 10⁶ after degradation. Impedance and dielectric loss were correlated, and the significance of dielectric loss was observed at lower frequencies. These characterizations will contribute to more efficient and detailed evaluation criteria for degradation monitoring.