A 1-D model based on DICTRA software was used to simulate Mn microsegregation in high-strength low-alloy steels during continuous casting. The experimentally determined (using a cumulative profiling method) segregation results were in good agreement with the modelling results. Steels undergoing solidification via a peritectic reaction had a larger segregation range than non-peritectic steels ascribed to trapping of the alloying atoms in liquid by austenite acting as a diffusion barrier. Subsequent, post-solidification cooling through the single phase austenite field decreased the microsegregation level, although the last γ→α phase transformation did affect the segregation profile in the solute-depleted dendrite centre. Simulation indicates that segregation levels could be reduced by decreasing either secondary dendrite arm spacing or adopting faster cooling rates through solidification.
This study evaluates the feasibility of producing high-strength low-alloy (HSLA) steel using advanced wire-fed laser additive manufacturing (LAM-W) and wire arc additive manufacturing (WAAM) technologies. Optimized parameters were independently developed for each heat source, utilizing a self-designed HSLA steel wire as the feedstock. Microstructural features and mechanical properties of the fabricated steels were characterized and compared, taking into account differences in heat input and cooling rates. LAM-W samples exhibited a finer columnar grain microstructure, while both LAM-W- and WAAM-produced steels predominantly showed lower bainite and granular bainite microstructures. LAM-W demonstrated higher strength and hardness, lower ductility, and comparable low-temperature toughness compared to WAAM. Both processes demonstrated an excellent balance between strength and ductility, with absorbed energy exceeding 100 J at −40 °C. The study confirms the feasibility of producing high-strength and tough HSLA steel parts using LAM-W and WAAM technologies, and compares the advantages and disadvantages of each method. These findings assist in selecting the most suitable wire-fed AM process for HSLA steel fabrication at high deposition rates.
To enhance the corrosion resistance of underground pipelines made of low carbon steel, nano-TiO2-modified polyurea was applied to their surface. The anti-corrosion performance of these nano-TiO2-modified coatings was tested by immersing them in a NACE (5 wt.% NaCl + 0.5 wt.% CH3COOH) solution under high temperatures and high CO2 pressures. The mass variation, SEM morphology, and open-circuit potential were determined. EIS tests, neutral salt spray tests, and contact angle measurements were carried out to analyze the effect of nanoparticles on corrosion resistance. Within the same pressure range, the polyurea coating shows the highest corrosion resistance when 5% TiO2 nanoparticles were added compared to that of polyurea coatings with 0%, 10%, and 15% TiO2 added. Coatings with 5% TiO2 nanoparticles showed rapid diffusion after being immersed for 96 h, indicating that the anti-corrosion performance of the coating weakened.
To improve the service life of continuous casting crystallizer, the NiCo-ZrB2 coating was prepared using nanocomposite plating technology. Uniformly dispersed nano-ZrB2 particles significantly enhanced the hardness and wear resistance of the coating. Upon testing, the hardness of the coating exceeded 700 HV, with a friction coefficient below 0.2, which was superior to those of pure NiCo or other nanocomposite NiCo coatings reported previously. Microscopic analysis revealed that the addition of dispersants and ultrasonic vibration treatment had facilitated the homogeneous distribution of nano-ZrB2 within the matrix, thereby promoting the formation of numerous nano-twins. Due to dispersion strengthening, fine grain strengthening, and twinning strengthening, the wear behavior of the coating changed from fatigue wear to abrasive wear, and the wear volume was significantly reduced by 82%. The above findings could potentially extend the service life of the coating, reduce the cost of steel loss per ton, and have broad application prospects in other surface protection fields.