This paper presents details of a study that deals with determination of engineering properties, identification of phases of major hydration products, and microstructural characteristics of a zinc-contaminated (referred to as Zn-contaminated in this paper) kaolin clay when it is stabilized by a cement additive. Investigations were carried out with respect to the effect of the level of zinc (Zn) concentration on the overall soil properties including Atterberg limits, water content, pH, stress–strain characteristics, unconfined compressive strength, and secant modulus. In addition, X-ray diffraction, scanning electron microscopy, and mercury intrusion porosimetry studies were conducted to understand the mechanisms controlling the changes in engineering properties of the stabilized kaolin clay. The study reveals that the level of Zn concentration has a considerable influence on the engineering properties, phases of hydration products formed, and microstructural characteristics of the stabilized kaolin clay. These changes are attributed to the retardant effect of Zn on the hydration and pozzolanic reactions, which in turn alters the phases of hydration products and cementation structure – bonding of the soils. Theoretical simulation of the pore-size distribution curves demonstrates that the cement-stabilized kaolin exhibits bimodal type when the Zn concentration is less than 2%, whereas it displays unimodal type when the Zn concentration is 2%. With an increase in the Zn concentration, the characteristics of the interaggregate pores in terms of volume and mean diameter change considerably, whereas those of intra-aggregate pores remain nearly unchanged.

Seepage-induced internal erosion in earth-filled embankment dams has been attracting the attention of civil engineering researchers and practitioners for decades. Microbially induced carbonate precipitation (MICP), owing to its proved performance in soil enhancement and permeability control, can potentially be used for internal erosion control. This paper examines the applicability of MICP for internal erosion control in gravel–sand mixtures using a large one-dimensional column test apparatus which incorporates the implementation of MICP. Visual observations, erosion characteristics and hydro-mechanical behaviours of non-MICP and MICP treated gravel–sand mixtures were investigated through a series of constant-pressure erosion tests. Test results confirm that MICP treatment can reduce the cumulative erosion weight, erosion rate and axial strain relative to non-MICP soil. The magnitudes of hydraulic conductivity for all tested samples before the erosion process fall into a range from 5·5 × 10⁻⁵to 8·0 × 10⁻³ m/s. After the erosion process, non-MICP soils and MICP treated soils with low cementation concentrations experience a significant increase in hydraulic conductivity. Furthermore, a hydro-mechanical coupling analysis was conducted and different erosion modes were identified for low and high concentrations of cementation solution. Fundamentally, the efficiency of internal erosion reduction is controlled by the calcium carbonate precipitation content within the tested soils. Higher precipitation content can facilitate the formation of larger clusters of cemented sand particles, thus reducing the likelihood of erosion.

Earth embankment dams are one of the most commonly constructed hydraulic infrastructures worldwide. One mode of dam failure is piping through the embankment, which is initiated by internal erosion of soil particles inside dams. In this study, the applicability of microbially induced carbonate precipitation (MICP) for internal erosion control is examined in the laboratory using sand-kaolin mixtures of different particle sizes. A series of internal erosion tests are conducted using a newly designed rigid-wall column erosion test apparatus, which allows independent control of MICP treatment. Erosion rate/coefficient, volumetric change, and permeability are characterized during the internal erosion process. It is found that MICP treatment facilitates the reduction of erosion and volumetric contraction of sand-clay mixtures investigated in the current study. Carbonate precipitation increases the erosion resistance of sand-clay mixtures by absorbing/coating fine particles directly and bridging the conta...

Calcium carbide residue (CCR) is an industrial by-product, stockpiles of which are rapidly accumulating worldwide. Highway embankment construction has been identified as an avenue to consume huge quantities of CCR as an economical, less energy intensive, and environmentally friendly chemical additive for soil stabilization. Previous studies have investigated the mechanical behavior of soils stabilized by CCR or blends of CCR with other additives; however, interpretation of the macroscale geomechanical behavior of CCR-stabilized soft soils from a systematically microstructural observation and analysis is relatively unknown. This paper presents a multi-scale laboratory investigation on the physical, mechanical, and microstructural properties of CCR-stabilized clayey soils with comparison to quicklime-stabilized soils. Several series of tests were conducted to examine the Atterberg limits, particle-size distribution, compaction characteristics, unconfined compressive strength, California Bearing Ratio, and resilient modulus of the CCR-stabilized clayey soils. The influences of binder content, curing time, and initial compaction state on the physical and mechanical properties of treated soils are interpreted with the aids of physicochemical and microstructural observations including soil pH, soil mineralogy obtained from X-ray diffraction and thermogravimetric analysis, and pore-size distribution obtained from mercury intrusion porosimetry. Soil particle flocculation and agglomeration at the early stage and pozzolanic reactions during the entire curing time, which originate from the finer particle size, greater specific surface area, and higher pH value of CCR, are the controlling mechanisms for the superior mechanical performance of CCR-stabilized soils. The outcomes of this research will contribute to the usage of CCR as a sustainable and alternative stabilizer to quicklime in highway embankment applications.