The problems arising from the limited availability of natural resources and the impact of certain anthropogenic activities on the environment must be addressed as soon as possible. To meet this challenge, it is necessary, among other things, to reconsider and redesign agricultural systems to find more sustainable and environmentally friendly solutions, paying specific attention to waste from agriculture. Indeed, the transition to a more sustainable and circular economy should also involve the effective valorization of agricultural waste, which should be seen as an excellent opportunity to obtain valuable materials. For the reasons mentioned above, this review reports and discusses updated studies dealing with the valorization of agricultural waste, through its conversion into materials to be applied to crops and soil. In particular, this review highlights the opportunity to obtain plant biostimulants, biofertilizers, and biopolymers from agricultural waste. This approach can decrease the impact of waste on the environment, allow the replacement and reduction in the use of synthetic compounds in agriculture, and facilitate the transition to a sustainable circular economy.

Microalgae anaerobic digestion produces biogas along with a digestate that may be reused in agriculture. However, the properties of this digestate for agricultural reuse have yet to be determined. The aim of this study was to characterise digestates from different microalgae anaerobic digestion processes (i.e. digestion of untreated microalgae, thermally pretreated microalgae and thermally pretreated microalgae in co-digestion with primary sludge). The main parameters evaluated were organic matter, macronutrients and heavy metals content, hygenisation, potential phytotoxicity and organic matter stabilisation. According to the results, all microalgae digestates presented suitable organic matter and macronutrients, especially organic and ammonium nitrogen, for agricultural soils amendment. However, the thermally pretreated microalgae digestate was the least stabilised digestate in comparison with untreated microalgae and co-digestion digestates. In vivo bioassays demonstrated that the digestates did not show residual phytotoxicity when properly diluted, being the co-digestion digestate the one which presented less phytotoxicity. Heavy metals contents resulted far below the threshold established by the European legislation on sludge spreading. Moreover, low presence of E. coli was observed in all digestates. Therefore, agricultural reuse of thermally pretreated microalgae and primary sludge co-digestate through irrigation emerges a suitable strategy to recycle nutrients from wastewater.