In this study, polypropylene (PP) was recycled in a non-stirred batch reactor by slow pyrolysis at low temperature. Virgin PP and waste PP as well as mixed material of equal amounts of virgin PP plus virgin PP pyrolysis oil (ratio 1:1 w/w) were used as raw material. The highest yields of liquid product were obtained at 350°C and 400°C (82.0 and 82.3 w/w%, respectively). The density, viscosity and calorific value of the gasoline and diesel fractions of the obtained pyrolysis oils comply with EN228 and EN590 standards, respectively. The flash point corresponded to the standard only for some of the oils, but the cold filter clogging point, the pour point and especially the oxidation stability were far above the stated reference values of the standards. The pyrolysis oils as products of thermal decomposition were determined by the methods of ¹H and ¹³C and two-dimensional-heteronuclear single quantum coherence nuclear magnetic resonance (2D-HSQC NMR) spectra. Spectral analysis showed that only very little aromatic compounds were present in the oils, but they contained many unsaturated compounds, which is presumably consistent with the measured oxidation stability and limits their use in the production of alternative fuels. The research octane number (RON) calculated from the NMR analyses corresponds to the lower limit of gasoline.

Background: With every oil tanker comes the risk of an accident and oil spill. Sorbents are the most suitable means to remove oil spills. Aerogels as sorbents have high porosity and can be made from cellulose from paper waste. The literature does not distinguish between paper and cardboard as sources of cellulose aerogels and little is known about composites of cellulose aerogels consisting of cellulose fibres and chemically untreated, unprocessed fibres or particles of straw, wool, macroalgae or cellulose acetate from cigarette butts. In this study, the sorption properties for marine diesel oil and biodiesel of such aerogels and their regenerative capacity with bioethanol were investigated. Methods: Cellulose aerogels were prepared from office paper and cardboard waste without and with chemically untreated algae, straw, wool and cellulose acetate as a composite by freeze drying. All samples were hydrophobised with methylsilane. The density to calculate the porosity and the contact angle were determined. Then the sorption capacity was determined over five cycles of sorption of oil and regeneration with bioethanol. Results: The average contact angle of all samples was 125°, indicating hydrophobicity. Paper-based aerogels were found to consistently have higher sorption capacities for biodiesel, marine diesel oil and bioethanol than cardboard-based aerogels. In particular, the wool/cellulose aerogel composite was found to have better sorption capacity for biodiesel, marine diesel oil and bioethanol than all other samples. The cellulose acetate/cellulose aerogel composite showed significantly higher sorption capacities than the paper and cardboard control samples (highest value is 32.25 g g⁻¹) only when first used as a sorbent for biodiesel, but with a rapid decrease in the following cycles.

The ambitious new International Maritime Organization (IMO) strategy to reduce greenhouse gas emissions from ships will shape the future path towards the decarbonization of the fleet and will bring further ecological challenges. In order to replace the larger oil-based part of marine fuel with components from renewable sources, it is necessary to develop multi-component blends. In this work, biomethanol and biodiesel with two additives—dodecanol and 2-ethylhexyl nitrate—in 20 blends with marine diesel oil (MDO) were selected as alternative components to replace the pure marine diesel oil-based part of marine fuel. For this purpose, two base blends of diesel and biodiesel with and without additives were produced with biomethanol from 0 to 30% (volume basis). Of all the blends, the blends with 5% (volume basis) methanol had the best property profile in terms of density, kinematic viscosity, calorific value, cloud point, and cetane index according to the ISO 8217:2017 standard (DMB grade) in compliance with the IMO requirements for marine fuels. However, the flash point must be increased. The boiling behavior of the blends was also investigated. A cluster analysis was used to evaluate the similarity between the blends based on their different physical properties.

Natural gas plays a vital role in the economically and environmentally sustainable future of energy. Its reliable deliveries are required, especially nowadays, when the energy market is so volatile and unstable. The conversion of natural gas to its liquefied form (LNG) allows its transport in greater quantities. Affordability and reliability of clean energy is a key issue even for developed markets. Therefore, natural gas usage enables to implement green solutions into countries’ economies. However, the LNG-production process consumes a considerable amount of energy. This energy is stored in LNG as cold energy. After LNG unloading into storage tanks at receiving terminals, it is vaporised and compressed for transmission to a natural gas pipeline system. During the regasification process, the large part of the energy stored in LNG may be recovered and used for electricity generation, seawater desalination, cryogenic air separation, hydrogen liquefaction, material freezing, carbon dioxide capture, as well as for combined LNG cold energy utilization systems. Moreover, increased efficiency of LNG terminals may attract potential clients. In the presented paper, a mathematical model is performed to determine the influence of LNG composition and regasification process parameters on the quantity of released LNG cold energy in a large-scale floating storage and regasification units (FSRU)-type terminal “Independence” (Lithuania). Flow rate of LNG regasification, pressure, and boil-off gas recondensation have been considered. Possibilities to reduce the energy losses were investigated to find the ways to improve the regasification process efficiency for real FSRU. The results analysis revealed that potential of LNG cold energy at FSRU could vary from 20 to 25 MW. A utilisation of industrial and urban waste heat for the heat sink FSRU is recommended to increase the energy efficiency of the whole regasification process.